掺镱铋酸盐玻璃近红外发光的温度特性

程继萌; 李韦韦; 赵国营; 李顺光; 陈伟; 胡丽丽; Georges Boulon

doi:doi:10.3788/cjl201340.1015001

中国激光, 2013, 40 (10): 1015001, 网络出版: 2013-09-17

掺镱铋酸盐玻璃近红外发光的温度特性

Temperature Characteristics of Near-Infrared Luminescence of Yb-Doped Bismuth-Based Glasses

论文大纲

程继萌 ^1,*李韦韦 ¹赵国营 ¹李顺光 ¹陈伟 ¹胡丽丽 ¹Georges Boulon ²

作者单位

¹ 中国科学院上海光学精密机械研究所, 上海 201800

² Institute Light Matter, UMR5306 University of Lyon1-CNRS, University of Lyon, Bat. Kastler, 69622 Villeurbanne cedex, France

摘要

研究了组分为55Bi2O3-25B2O3-10SiO2-(10-x)Ga2O3-xYb2O3（x=0.5,2.0,5.0）掺镱铋酸盐玻璃在1 μm近红外波段发光的温度特性。测定了9 K低温到350 K高温条件下975 nm和1003 nm主次荧光峰，它们的半峰全宽基本没有大的变化，表明铋酸盐玻璃基质对镱离子的非均匀加宽是谱线加宽的主要原因。另外，电子声子耦合对镱离子荧光光谱和荧光寿命也有一定程度的影响。对于荧光寿命的温度特性，本身具有较大荧光俘获效应的镱离子的寿命受到明显影响，其中在高温区的影响比在低温区的更强。

Abstract

The temperature dependence of near-infrared around 1 μm emission properties of Yb-doped 55Bi2O3-25B2O3-10SiO2-(10-x)Ga2O3-xYb2O3（x=0.5, 2.0, 5.0) glasses is investigated. Emission spectra, covering a major 975 nm fluorescence peak with a minor 1003 nm weaker peak, are determined within the temperature range of 9 K~350 K. The full width at half-maximum of them does not change a lot. An important cause for the width of fluorescence line is inhomogeneous broadening from this bismuth-based glass host. On the other hand, the electron-phonon coupling will have some influence on the emission spectrum and emission lifetime. For the temperature dependence of lifetime, a longer emission lifetime of Yb at higher temperature region indicates a more significant influence of radiation trapping effect.

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程继萌, 李韦韦, 赵国营, 李顺光, 陈伟, 胡丽丽, . 掺镱铋酸盐玻璃近红外发光的温度特性[J]. 中国激光, 2013, 40(10): 1015001. Cheng Jimeng, Li Weiwei, Zhao Guoying, Li Shunguang, Chen Wei, Hu Lili, Georges Boulon. Temperature Characteristics of Near-Infrared Luminescence of Yb-Doped Bismuth-Based Glasses[J]. Chinese Journal of Lasers, 2013, 40(10): 1015001.

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