Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料的Rietveld精修及高温热电性能研究

李欢; 李翠芹; 江祥红; 王雪; 支伟; 杨阳; 卢飞凡; 杨旭

人工晶体学报, 2020, 49 (2): 312, 网络出版: 2020-06-15

Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料的Rietveld精修及高温热电性能研究

Study on Rietveld Refinement and High-temperature Thermoelectric Properties of Dy Doped Ca1-x Dyx MnO3 (x=0, 0.02, 0.03, 0.05, 0.10)Thermoelectric Materials

论文大纲

李欢李翠芹 ^*江祥红王雪支伟杨阳卢飞凡杨旭

作者单位

贵州大学化学与化工学院，贵阳 550025

CaMnO3热电材料共沉淀法 Dy掺杂 Rietveld精修 CaMnO3 thermoelectric material coprecipitation Dy doping Rietveld refinement

摘要

本文采用共沉淀法制备Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料，通过X射线衍射对热电材料进行物相结构表征，利用Rietveld粉末衍射全谱拟合方法对X射线衍射数据进行精修得到Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料的精细结构，利用标准四探针法测试高温热电性能。Rietveld精修结果表明，随着Dy掺杂量的增加，CaMnO3样品的晶胞参数及晶胞体积逐渐变大。对应的电阻率测量结果表明，掺杂样品的电阻率随着Dy 掺杂量的增加而减小。其中Ca0.9Dy0.1MnO3的室温电阻率最低，为6.7×10-5 Ω?m，是未掺杂CaMnO3的1/6倍。

Abstract

Dy doped Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10) thermoelectric materials were prepared by coprecipitation. The phase structure was determined by X-ray diffraction. Fine structure of Dy doped Ca1-xDyxMnO3(x=0,0.02, 0.03, 0.05, 0.10) thermoelectric materials were obtained by refining data with Rietveld powder diffraction full spectrum fitting method. And the high-temperature thermoelectric properties were determined by four probe electrodes. Rietveld refinement results show that the cell parameters and cell volume of CaMnO3 samples gradually increase with the increase of Dy doping. The corresponding resistivity results show that the resistivity of the doped samples decreases with the increase of Dy doping. The room temperature resistivity of Ca0.9Dy0.1MnO3 is the lowest, which is 6.7×10-5 Ω ?m, 1/6 times of that of undoped CaMnO3.

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李欢, 李翠芹, 江祥红, 王雪, 支伟, 杨阳, 卢飞凡, 杨旭. Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料的Rietveld精修及高温热电性能研究[J]. 人工晶体学报, 2020, 49(2): 312. LI Huan, LI Cuiqin, JIANG Xianghong, WANG Xue, ZHI Wei, YANG Yang, LU Feifan, YANG Xu. Study on Rietveld Refinement and High-temperature Thermoelectric Properties of Dy Doped Ca1-x Dyx MnO3 (x=0, 0.02, 0.03, 0.05, 0.10)Thermoelectric Materials[J]. Journal of Synthetic Crystals, 2020, 49(2): 312.

Dy掺杂Ca1-xDyxMnO3(x=0, 0.02, 0.03, 0.05, 0.10)热电材料的Rietveld精修及高温热电性能研究

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