大气与环境光学学报, 2017, 12 (1): 66, 网络出版: 2017-02-09  

利用单光子电离飞行时间质谱仪对塑料企业中VOCs的监测

Monitoring VOCs of Plastic Company by Single Photon Ionization Time-of-Flight Mass Spectrometry
作者单位
1 暨南大学质谱仪器与大气环境研究所, 广东 广州 510632
2 广州禾信仪器股份有限公司, 广东 广州 510530
3 广东省大气污染在线源解析系统工程技术研究中心, 广东 广州 510632
摘要
采用自主研发的单光子电离飞行时间质谱仪对珠三角某塑料生产企业生产区域的挥发性有机物(volatile organic compounds, VOCs) 进行现场在线监测,初步获取了该企业各生产车间以及污水处 理站等地点的VOCs排放源谱,结果显示该企业所有车间均未发现VOCs浓度超标情况。另外还通过对企业内部道路的污染情况与各车间的源谱进行了对 比分析,定量评价了各个污染源对道路VOCs的贡献率。这套在线挥发性有机物质谱仪在化工园区VOCs实时在线监测、应急检测、污染模式识别、偷排漏排 监控等方面具有广阔的市场。
Abstract
A single photon ionization time-of-flight mass spectrometry(SPI-TOFMS) was applied to the online monitoring of the volatile organic compounds (VOCs) emitted from a plastic company in Pearl River Delta. The source profiles of workshops and sewage treatment station were attained successfully. Over-standard concentration of VOCs has not been found during the monitoring. In addition, the contribution of every pollution source to the internal roads was also evaluated by comparing the source profiles of workshops. This online VOCs mass spectrometry has wide markets in aspects of online VOCs monitoring, emergency detecting, pollution mode recognition and underlying discharge monitoring.
参考文献

[1] 张少梅, 沈晋明.室内挥发性有机化合物(VOC)污染的研究[J]. 洁净与空调技术, 2003(3): 1-4.

    Zhang Shaomei, ShenJinming. Research on the volatile organic compound (VOC) pollution [J].Contamination Control & Air-conditioning Technology, 2003(3): 1-4(in Chinese).

[2] Buszewski B, Ulanowska A, Kowalkowski T,et al. Determination of volatile organic compounds in human breath for Helicobacter pylori detection by SPMEGC/MS [J]. Biomed. Chromatogr., 2011, 25(3): 391-397.

[3] Stoppacher N, Kluger B, Zeilinger S,et al. Identification and profiling of volatile metabolites of the biocontrol fungus Trichoderma atroviride by HS-SPME-GC-MS [J]. J. Microbiol. Meth., 2010, 81(2): 187-193.

[4] 空气质量甲苯、二甲苯、苯乙烯的测定气相色谱法: GB/T 14677-1993 [S].中华人民共和国国家标准.

    Air quality-determination of toluene,dimethyl benzene and styrene-gas chromatography: GB/T 14677-1993 [S]. National Standards of the People’s Republic of China(in Chinese).

[5] 居住区大气中苯、甲苯和二甲苯卫生检验标准方法气相色谱法: GB/T 11737-1989 [S].中华人民共和国国家标准.

    Standard method for hygienic examination of benzene, toluene and xylene in air of residential areas- gas chromatography: GB/T 11737-1989 [S].National Standards of the People’s Republic of China(in Chinese).

[6] 谭国斌,高 伟,黄正旭,等.真空紫外灯单光子电离源飞行时间质谱仪的研制 [J]. 分析化学, 2011, 39(10): 1470-1475.

    Tan Guobin, Gao Wei, Huang Zhengxu,et al.Vacuum ultraviolet single photon ionization time-of-flight mass spectrometer [J]. Analytical Chemistry, 2011, 39(10): 1470-1475(in Chinese).

[7] 谭国斌,高 伟,洪 义,等.高灵敏度膜进样VOCs在线检测质谱仪的研制[J]. 现代科学仪器, 2011, 10(5): 59-62.

    Tan Guobin, Gao Wei, Hong Yi,et al.Development of high sensitivity membrane introduction mass spectrometer for on-line detecting VOCs [J]. Modern Scientific Instruments, 2011, 10(5): 59-62(in Chinese).

陈彦锐, 谭国斌, 麦泽彬, 周达荣, 钟应铨, 李雪, 高伟, 黄正旭. 利用单光子电离飞行时间质谱仪对塑料企业中VOCs的监测[J]. 大气与环境光学学报, 2017, 12(1): 66. CHEN Yanrui, TAN Guobin, MAI Zebin, ZHOU Darong, ZHONG Yingquan, LI Xue, GAO Wei, HUANG Zhengxu. Monitoring VOCs of Plastic Company by Single Photon Ionization Time-of-Flight Mass Spectrometry[J]. Journal of Atmospheric and Environmental Optics, 2017, 12(1): 66.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!