发光学报, 2019, 40 (2): 204, 网络出版: 2019-03-11   

铜铟镓硒薄膜太阳能电池新型图形化透明前电极研究

Improved Performance of CuInGaSe2 Solar Cells with Patterned Front Contact
郭凯 1,2张传升 1,2,3
作者单位
1 重庆神华薄膜太阳能科技有限公司, 重庆 400700
2 中国节能减排有限公司, 北京 100011
3 北京低碳清洁能源研究所, 北京 102208
摘要
为了优化铜铟镓硒薄膜太阳能电池的前电极, 提高铜铟镓硒薄膜太阳能电池的效率, 提出了一种可应用于铜铟镓硒薄膜太阳能电池的AZO/图案化Ag薄膜/AZO结构的前电极, 中间层的Ag薄膜与电池顶层的金属栅线具有完全相同的图案和尺寸, 并且位于金属栅线的正下方, 这种新型结构可以提高电池前电极的电学性能, 但对电池来说不会带来额外的光学损失。对比了新型前电极结构与几种传统前电极的电学和光学性能, 并且制备了相应的电池进行了性能对比。实验结果表明, 新型的前电极结构可以提高铜铟镓硒薄膜太阳能电池的短路电流, 相对传统AZO电极,电池效率从13.83%提高到14.53%。本结构可以明显提高电池效率。
Abstract
In order to improve the efficiency of CIGS thin film solar cell, a novel AZO/patterned Ag/AZO multilayer front contact was investigated. In this architecture, middle Ag thin film is patterned, which has the identical shape and size with the metal grid of solar cell and under the metal grid. This architecture can increase the electrical properties when the transmittance is constant. The transmittance and sheet resistance of new architecture were compared with that of traditional front contact. In comparison with the solar cell with AZO and AZO/Ag/AZO front contact, the CIGS solar cell with new architecture shows the higher short circuit current and improves efficiency from 13.83% to 14.53%. The noval architecture can improve the efficiency of CIGS solar cell.
参考文献

[1] JACKSON P,WUERZ R, HARISKOSD,et al.. Effects of heavy alkali elements in Cu(I,Ga)Se2 solar cells with efficiency up to 22.6% [J]. Phys. Status Solidi-Rapid Res. Lett., 2016,10(8): 583.

[2] MENNER R,HARISKOS D,LINSS V,et al.. Low-cost ZnO∶Al transparent contact by reactive rotatable magnetron sputtering for Cu(In,Ga)Se2 solar modules [J]. Thin Solid Films, 2011,519: 7541.

[3] JEONG S H,BOO J H. Influence of target-to-substrate distance on the properties of AZO films grown by RF magnetron sputtering [J]. Thin Solid Films, 2004,448: 105.

[4] 焦杨,徐旭,周晨露,等. 纳米结构ZnO薄膜的制备及其疏水特性 [J]. 发光学报, 2014, 35(6): 654-659.

    JIAO Y,XU X,ZHOU C L,et al.. Preparation of diverse nanostructured ZnO films and their hydrophobic properties [J]. Chin. J. Lumin., 2014, 35(6): 654-659. (in Chinese)

[5] CHIRIL A,REINHARD P, PIANEZZI F,et al.. Potassium-induced surface modification of Cu(In,Ga)Se2 thin films for high-efficiency solar cells [J]. Nat. Mater., 2013, 12(12): 1107.

[6] CHANG J C,GUO J W,HSIEHT P. Effects of substrate temperature on the properties of transparent conducting AZO thin films and CIGS solar cells [J]. Surf. Coat. Technol., 2013,231(9): 573-577.

[7] FAHLAND M,KARLSSON P,CHARTON C. Low resisitivity transparent electrodes for displays on polymer substrates [J]. Thin Solid Films, 2001,392(2): 334-337.

[8] OU S L,WU D S,LIU S P,et al.. Pulsed laser deposition of ITO/AZO transparent contact layers for GaN LED applications [J]. Opt. Express, 2011, 19(17): 16244-16251.

[9] 伍嘉城,林伯融,陈采宁,等. 用于氮化镓发光二极管窗口层的铝掺杂氧化锌的生长 [J]. 发光学报, 2008,29(3): 508-512.

    WU J C,LIN B R,CHEN C N,et al.. Growth of Al-doped ZnO window layer for GaN LED application [J]. Chin. J. Lumin., 2008,29(3): 508-512. (in Chinese)

[10] AOSHIMA Y,MIYAZAKI M,SATO K,et al.. Development of silver-based multilayer coating electrodes with low resistance for use in flat panel displays [J]. Japan J. Appl. Phys., 2000, 39(8): 4884-4889.

[11] MIAO D G,LI A S,JIANG S X,et al.. Fabrication of Ag and AZO/Ag/AZO ceramic films on cotton fabrics for solar control [J]. Ceram. Int., 2014, 40(8): 12847-12853.

[12] 杨田林,张之圣,宋淑梅,等. 衬底温度对AZO/Cu/AZO多层薄膜结构及光电的影响 [J]. 太阳能学报, 2009,30(9): 1209-1215.

    YANG T L,ZHANG Z S,SONG S M,et al.. Influence of substrate tempreture on the structural,optical and electrical properties for AZO/Cu/AZO multilayer films [J]. Acta Energiae Solaris Sinica, 2009,30(9): 1209-1215. (in Chinese)

[13] MIAO D G,JIANG S X,SHANG S M. Fabrication of high infrared reflective AZO/Ag/AZO films on polyester fabrics [J]. J. Mater. Sci.: Mater. Electron., 2014,25: 5248-5254.

[14] WU H W,CHU C H. Structural and optoelectronic properties of AZO/Mo/AZO thin films prepared by RF magnetron sputtering [J]. Mater. Lett., 2013,105(16): 65-67.

[15] CHU C H,WU H W,HUANG J L. AZO/Au/AZO tri-layer thin films for the very low resistivity transparent electrode applications [J]. Mater. Sci. Eng. B, 2014, 186(1): 117-121.

郭凯, 张传升. 铜铟镓硒薄膜太阳能电池新型图形化透明前电极研究[J]. 发光学报, 2019, 40(2): 204. GUO Kai, ZHANG Chuan-sheng. Improved Performance of CuInGaSe2 Solar Cells with Patterned Front Contact[J]. Chinese Journal of Luminescence, 2019, 40(2): 204.

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