发光学报, 2017, 38 (10): 1332, 网络出版: 2017-10-17  

基于MoO3/Au/MoO3透明电极的有机太阳能电池

Organic Solar Cells Based on MoO3/Au/MoO3 Transparent Electrode
作者单位
重庆邮电大学 光电工程学院, 重庆 400065
摘要
以透明导电薄膜MoO3/Au/MoO3代替铟锡氧化物(ITO)作为有机太阳能电池(OSCs)的阳极, 研究了一系列结构为MoO3/Au/MoO3的透明电极和MoO3(y nm)/Au(x nm)/MoO3(y nm)/CuPc(25 nm)/C60(40 nm)/BCP(8 nm)/Al(100 nm)的有机太阳能电池。研究表明, MoO3/Au/MoO3电极的光电特性可通过改变各层薄膜厚度加以调控, 在MoO3薄膜厚度为40 nm、Au薄膜厚度为10 nm时性能最优, 且以该薄膜为电极的有机太阳能电池器件的性能接近于电极为ITO的有机太阳能电池器件。
Abstract
Transparent conductive film MoO3/Au/MoO3 was used as the anode of organic solar cells (OSCs) instead of indium tin oxide (ITO). A series of MoO3/Au/MoO3 transparent electrodes and OSCs with the structure of MoO3(y nm)/Au(x nm)/MoO3(y nm)/CuPc(25 nm)/C60(40 nm)/BCP(8 nm)/Al(100 nm) were fabricated. The results show that the photoelectric characteristics of MoO3/Au/MoO3 electrode can be controlled by changing the film thickness of each layer, the optimum performance of OSC is achieved when the thickness of MoO3 film is 40 nm and the thickness of Au film is 10 nm. Besides, the performance of the OSC with MoO3/Au/MoO3 electrode is close to that of OSC with ITO electrode.
参考文献

[1] ZHOU H, CHEN Q, LI G, et al.. Interface engineering of highly efficient perovskite solar cells [J]. Science, 2014, 345:542-546.

[2] KAMAT P V. Organometal halide perovskites for transformative photovoltaics [J]. J. Am. Chem. Soc., 2014, 136:3713-3714.

[3] YUSOFF A R, NAZEERUDDIN M K. Organohalide lead perovskites for photovoltaic applications [J]. Energy Environm. Sci., 2014, 7(8):2448-2463.

[4] SAPKOTA S B, SPIES A, ZIMMERMANN B, et al.. Promising long-term stability of encapsulated ITO-free bulk-heterojunction organic solar cells under different aging conditions [J]. Solar Energy Mater. Solar Cells, 2014, 130(130):144-150.

[5] GONDEK E, DJAOUED Y, PRIYA S, et al.. Organic hybrid solar cells-influence of ZnO nanoparticles on the photovoltaic efficiency [J]. Mater. Lett., 2014, 131(131):259-261.

[6] 张利忠, 吴明晓, 田金鹏, 等. TiO2阴极缓冲层对Rubrene/C70有机太阳能电池性能的改善 [J]. 发光学报, 2017, 38(3):359-364.

    ZHANG L Z, WU M X, TIAN J P, et al.. Improvement of TiO2 cathode buffer layer to the performance of rubrene/C70 organic solar cells [J]. Chin. J. Lumin., 2017, 38(3):359-364. (in Chinese)

[7] 李祥, 文尚胜, 贺前华, 等. 电极对CuPc/C60双层异质结有机太阳能电池光学性能的影响 [J]. 发光学报, 2012, 33(8):888-894.

    LI X, WEN S S, HE Q H, et al.. Effects of electrodes on the optical performance of CuPc/C60 bilayer heterojunction organic solar cells [J]. Chin. J. Lumin., 2012, 33(8):888-894. (in Chinese)

[8] 田苗苗, 李春杰, 贺小光, 等. 基于新型透明导电电极的有机光伏器件的制备与表征 [J]. 发光学报, 2013, 34(2):192-196.

    TIAN M M, LI C J, HE X G, et al.. Preparation and characteristics of organic solar cells based on novel transparent conducting oxides [J]. Chin. J. Lumin., 2013, 34(2):192-196. (in Chinese)

[9] LI H, LV Y, ZHANG X, et al.. High-performance ITO-free electrochromic films based on bi-functional stacked WO3/Ag/WO3 structures [J]. Solar Energy Mater. Solar Cells, 2015, 136:86-91.

[10] QI Z, CAO J, DING L, et al.. Transparent and transferrable organic optoelectronic devices based on WO3/Ag/WO3 electrodes [J]. Appl. Phys. Lett., 2015, 106(5):053304.

[11] 胡俊涛, 邓亚飞, 梅文娟, 等. 透明叠层结构Ag/MoO3/Ag阳极对绿光OLED器件性能的影响 [J]. 液晶与显示, 2016, 31(1):74-79.

    HU J T, DENG Y F, MEI W J, et al.. Effects of transparent Ag/MoO3/Ag stack as anode on the performance of green organic light-Emitting diodes [J]. Chin. J. Liq. Cryst. Disp., 2016, 31(1):74-79. (in Chinese)

[12] KINOSHITA Y, TAKENAKA R, MURATA H. Independent control of open-circuit voltage of organic solar cells by changing lm thickness of MoO3 buffer layer [J]. Appl. Phys. Lett., 2008, 92(24):243301-1-3.

[13] PANG H, ZHOU Y, YUAN Y, et al.. ZnS Ag ZnS coating as transparent anode for organic light emitting diodes [J]. J.Lumin., 2007, 122-123:587-589.

[14] LEWIS J, GREGO S, CHALAMALA B. Highly flexible transparent electrodes for organic light-emitting diode-based displays [J]. Appl. Phys. Lett., 2004, 85:3450-3452.

[15] CHOI K H, NAM H J, JEONG J A, et al.. Highly flexible and transparent InZnSnOxAgInZnSnOx multilayer electrode for flexible organic light emitting diodes [J]. Appl. Phys. Lett., 2008, 92(22):223302.

[16] PARK Y, PARK H, JEONG J. Comparative investigation of transparent ITO/Ag/ITO and ITO/Cu/ITO electrodes grown by dual-target DC sputtering for organic photovoltaics [J]. J. Electrochem. Soc., 2009, 7(156):588-594.

[17] PARK H, JEONG J, PARK Y. Room-temperature indium-free Ga∶ZnO/Ag/Ga∶ZnO multilayer electrode for organic solar cell applications [J]. Electrochem. Solid-State Lett., 2009, 8(12):309-311.

[18] JEONG J, PARK Y. Comparison of electrical, optical, structural, and interface properties of IZO-Ag-IZO and IZO-Au-IZO multilayer electrodes for organic photovoltaics [J]. Appl. Phys. Lett., 2010, 107(23):23111.

[19] PARK J, CHIO Y, KIM H, et al.. The effects of rapid thermal annealing on the electrical, optical, and structural properties of Nb∶TiO2 multilayer electrodes with an inserted nanoscale Ag layer for organic solar cells [J]. Appl. Phys. Lett., 2010, 108(8):83501-83509.

[20] TAO C, XIE G, LIU C, et al.. Semitransparent inverted polymer solar cells with MoO3/Ag/MoO3 as transparent electrode [J]. Appl. Phys. Lett., 2009(95):53301-53303.

[21] 宋春燕. 新型无铟透明导电薄膜的设计研制及其应用 [D]. 长春: 中国科学院研究生院, 2011.

    SONG C Y. Design, Fabrication and Application of Novel Indium Free Transparent Conductive Films [D]. Changchun: Graduate University of The Chinese Academy of Sciences, 2011. (in Chinese)

[22] SHOCKLEY W, QUEISSER H J. Detailed balance limit of efficiency of p-n junction solar cells [J]. J. Appl. Phys., 1961, 32(3):510-519.

王振, 柳菲, 郑新, 王培, 甘林, 汪静静. 基于MoO3/Au/MoO3透明电极的有机太阳能电池[J]. 发光学报, 2017, 38(10): 1332. WANG Zhen, LIU Fei, ZHENG Xin, WANG Pei, GAN Lin, WANG Jing-jing. Organic Solar Cells Based on MoO3/Au/MoO3 Transparent Electrode[J]. Chinese Journal of Luminescence, 2017, 38(10): 1332.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!