应用激光, 2017, 37 (4): 497, 网络出版: 2017-10-12  

激光熔覆Ni/Ti-Al2O3涂层组织研究

Microstructure of Laser Clad Ni/Ti-Al2O3 Coatings
作者单位
上海工程技术大学材料工程学院, 上海 201620
摘要
采用激光熔覆技术在钛合金基体表面制备了Ni/Ti涂层和Ni/Ti-Al2O3涂层。利用扫描电镜、能谱分析仪和X射线衍射仪对涂层的显微组织、成分和相组成进行了分析。结果表明, 涂层与基体的结合区域有明显的光亮线, 涂层与基体呈现出良好的冶金结合,涂层的显微组织由白色光亮带组织和黑色组织构成, Ni/Ti涂层中主要的物相有NiTi2和NiTi两相, Ni/Ti-Al2O3涂层主要的物相则为NiTi2、Ti和Al2O3相。
Abstract
Ni/Ti coating and Ni/Ti-Al2O3 coating were fabricated on titanium alloy substrate by laser cladding. The microstructure and phase composition of the coatings were investigated by XRD, SEM, EDAX, respectively. The microhardness and wear resistance of the coatings were also researched and analyzed used by microhardness tester and multifunction tribometer, respectively. The results show that the microstructure of the coating consisted of bright zone and black zone. The binding region between coating and substrate has obvious bright line, which exhibit substantially good metallurgical bonding. The main phase of Ni/Ti coating was NiTi2 and NiTi, while Ni/Ti-Al2O3 coating was NiTi2, Ti and Al2O3.
参考文献

[1] 李昂, 李安, 张凌云.激光熔化沉积NiTi/Ni3Ti金属间化合物合金的显微组织和耐磨性[J].中国有色金属学报, 2006, 16(5): 867-873.

[2] FENG SHURONG, TANG HAIBO, ZHANG SHUQUAN, et al.Microstructure and wear resistance of laser clad TiB-TiC/TiNi-Ti2Ni intermetallic coating on titanium alloy[J].Transactions of Nonferrous Metals Society of China, 2012(22): 1667-1673.

[3] YE H.Z, LIU R, LI D Y, et al.Wear and friction of a new wear-resistant material: TiNi-based composites[J].Composites Science and Technology, 2001, 61(7): 987-994.

[4] JAVIER FERNANDEZ, ANTONIO ISALGUE, NURIA CINCA, et al.Comparison of mechanical and tribological properties of TiC- NiTi and TiC-TiB2- NiTi coatings[J].Physics Procedia, 2010(10): 65-68.

[5] 赵连城, 郑玉峰.形状记忆与超弹性镍钛合金的发展和应用[J].中国有色金属学报, 2004, 14(专辑1): 323-327.

[6] 裴新军, 黄继华.反应钎涂钛镍金属间化合物涂层研究[J].有色金属(冶炼部分): 2005(3): 1007- 7545.

[7] 周勇, 杨冠军, 吴限, 李长久.层叠Ni/Ti热扩散形成金属间化合物的规律[J].焊接学报, 2010, 31(9): 41-44.

[8] MASATAKA MIZUNO, HIDEKI ARAKI, YASUHARU SHIRAI.Compositional dependence of structures of NiTi martensite from first principles[J].Acta Materialia, 2015(95); 184-191.

[9] HITOSHI HIRAGA, TAKASHI INOUE, HIROFUMI SHIMURA, et al.Cavitation erosion mechanism of NiTi coatings made by laser plasma hybrid spraying[J].Wear, 1999, 231(2): 272-278.

[10] HITOSHI HIRAGA, TAKASHI INOUE, SHIGEHARU KAMADO, et al.Fabrication of NiTi intermetallic compound coating made by laser plasma hybrid spraying of mechanically alloyed powders[J].Surface and Coatings Technology, 2001, 139(1):93-100.

[11] STELLA J, SCHULLER E, HEBING C, et al.Cavitation erosion of plasma-sprayed NiTi coatings[J].Wear, 2006, 260(9-10): 1020-1027.

[12] SERKAN OZEL, BULENT KURT, ILYAS SOMUNKIRAN, et al.Microstructural characteristic of NiTi coating on stainless steel by plasma transferred arc process[J].Surface & Coatings Technology, 2008, 202(15): 3633-3637.

张群森, 陈永香, 董丰波, 刁磊, 周维, 高鸿鹏, 雷宇江, 李崇桂. 激光熔覆Ni/Ti-Al2O3涂层组织研究[J]. 应用激光, 2017, 37(4): 497. Zhang Qunsen, Chen Yongxiang, Dong Fengbo, Diao Lei, Zhou Wei, Gao Hongpeng, Lei Yujiang, Li Chonggui. Microstructure of Laser Clad Ni/Ti-Al2O3 Coatings[J]. APPLIED LASER, 2017, 37(4): 497.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!