Author Affiliations
Abstract
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
Two-dimensional Dion–Jacobson (D-J) phase perovskites are prospective photovoltaic and optoelectronic materials. To study their mechanical properties and carrier-lattice interactions, we conduct femtosecond spectroscopic experiments on the films of a D-J perovskite. After optical excitation, a meV bandgap oscillation is observed in the film by transient absorption spectroscopy. With the help of transient reflection methods, we reveal that the oscillation originates from the transport of coherent longitudinal acoustic phonons through the film. Large bandgap oscillation indicates a strong coupling between carriers and lattice, and significant bandgap modulation by strains in D-J perovskites.
transient absorption coherent longitudinal acoustic phonons bandgap oscillation 2D Dion–Jacobson phase perovskites Chinese Optics Letters
2022, 20(10): 100010
1 中国科学院物理研究所光物理开放实验室,北京,100080
2 香港城市大学,物理及材料科学系,香港,九龙
我们选用x=0,0.14,0.36,0.54,和0.92的Y3-xBixFe5O12系列单晶,开展了比早期实验更为深入的布里渊散射研究.实验发现对于Bi-YIG晶体,照射在样品上小于5 mW的激光功率为最佳激发功率.布里渊散射结果表明Y3-xBixFe5O12晶体中的磁性能和机械性质与Bi含量密切有关.此实验观测到了两种体波性质的磁振子,一个是热激发的自旋波,另一个被确认为静磁模.实验还发现声学声子的散射强度和声速随Bi含量的增加而减少.
布里渊散射 磁振子 声学声子 Brillouin light scattering magnons acoustic phonons