光学学报, 2008, 28 (12): 2383, 网络出版: 2008-12-17   

碱金属氟化物对掺Yb3+氟磷酸盐玻璃析晶稳定性和光谱性质的影响

Crystalization Stability and Spectral Properties of Yb3+-Doped Alkaline Metal Modified Fluorophosphates Glasses
作者单位
中国科学院上海光学精密机械研究所, 上海 201800
摘要
研究了碱金属氟化物对掺Yb3+氟磷玻璃的光谱性质和析晶稳定性能的影响。运用倒易法计算了Yb3+的发射截面。结果显示, LiF的引入对吸收和发射截面的提高作用较大并出现最佳引入量极值, 其次为KF。碱金属氟化物的引入可提高二元体系的析晶稳定性能,使玻璃网络结构得到改善; 拉曼光谱显示二元体系中引入YbF3后玻璃网络结构得到增强, 而在引入碱金属氟化物的三元体系中掺杂YbF3后破坏了网络完整性,降低系统析晶稳定性能。
Abstract
The influence of alkaline fluorides on spectroscopic properties and crystalization stability of Yb3+-doped fluorophosphate glasses was studied. Emission cross section of Yb3+ is calculated based on reciprocity method. Results show that LiF increases the absorption and emission cross section and has optimal introduction amount, and the second is KF. Alkaline fluorides improve the crystalization stability of binary system and strengthen the glass network. Raman spectra show that YbF3 strengthens the glass network of binary system, but destroys that of the ternary system with alkaline fluorides and reduces the crystalization stability.
参考文献

[1] . Yamada, H. Ono, Y. Ohishi. Low-noise, broadband Er3+ doped silica fiber amplifiers[J]. Electron. Lett., 1998, 34(13): 1490-1491.

[2] . Honninger, R. Paschotta. Ultrafast ytterbium-doped bulk lasers and laser amplifiers[J]. Appl. Phys. B, 1999, 69: 3-17.

[3] 廖梅松, 房永征, 孙洪涛 等. 掺铥氟磷玻璃的结构、热学性质和光谱性质[J]. 光学学报, 2006, 26(5): 713~719

    Liao Meisong, Fang Yongzhen, Sun Hongtao et al.. Structure, thermal properties and spectral properties of Tm3+-doped fluorophosphate glasses[J]. Acta Optica Sinica, 2006, 26(5): 713~719

[4] . Honninger, Morier, H. F-Genoud et al.. Efficient and tunable diode-pumped femtosecond Yb:glass lasers[J]. Opt. Lett., 1998, 23(2): 126-128.

[5] Ehrt D. On non-oxide glass and new optical glass[C]. 2002 Ⅷ International Symp, Pardubice, Czech Republic, 2002. 662~664

[6] . F. Massicott, J. R. Armitage, R. Wyatt et al.. High gain, broadband, 1.6 μm Er3+ doped silica fiber amplifier[J]. Electron. Lett., 1990, 26(20): 1645-1646.

[7] 陆龙君, 聂秋华, 徐铁峰 等. Er3+/Yb3+共掺Bi2O3-GeO2-Na2O玻璃的上转换发光[J]. 中国激光, 2006, 33(8): 1117~1121

    Lu longjun, Nie Qiuhua, Xu Tiefeng et al.. Upconversion emission of Er3+/Yb3+-codoped Bi2O3-GeO2-Na2O glasses[J]. Chin. J. Lasers, 2006, 33(8): 1117~1121

[8] . Nilsson, R. Paschotta, J. E. Caplen et al.. Yb3+-ring-doped fiber for high-energy pulse amplification[J]. Opt. Lett., 1997, 22(14): 1092-1094.

[9] . L. Zou, K. Itoh, H. Toratani. Transmission loss characteristics of fluorophosphate optical fiber in the ultraviolet to visible wavelength region[J]. J. Non-Crys. Solids, 1997, 215: 11-20.

[10] M. J. Weber, J. E. Lynch, D. H. Blackburn et al.. Dependence of the stimilated emission cross section of Yb3+ on host glasses composition[J]. IEEE J. Quant. Electron., 1983, QE-19(10): 1600~1608

[11] . Takebe, T. Murata, K. Morinaga. Compositional dependence of absorption and fluorescence of Yb3+ in oxide glasses[J]. J. Am. Ceram. Soc., 1996, 79: 681-687.

[12] . Dellach, S. Payne, L. Chase et al.. Evaluation of absorption and emission properties of Yb3+ doepd crystals for laser applications[J]. IEEE J. Quant. Electron., 1993, 29(4): 1179-1191.

[13] F. X. Gan. Optical and Spectroscopic Properties of Glasses[M]. Berlin Heidelberg: Springer-Verlag, 1992. 27~49

[14] . . Special effects of YbF3 on the structural changes for fluorophosphates glass[J]. Physica B, 2005, 367: 1-5.

[15] 汪国年, 戴世勋, 张军杰 等. Yb3+掺杂锌锗碲酸盐玻璃的热分析、光谱和激光性质[J]. 中国激光, 2005, 32(3): 365~369

    Wang Guonian, Dai Shixun, Zhang Junjie et al.. Thermal, spectra and laser properties of Yb:zinc-germanium-tellurite glasses for laser[J]. Chin. J. Lasers, 2005, 32(3): 365~369

董擎雷, 张丽艳, 胡丽丽. 碱金属氟化物对掺Yb3+氟磷酸盐玻璃析晶稳定性和光谱性质的影响[J]. 光学学报, 2008, 28(12): 2383. Dong Qinglei, Zhang Liyan, Hu Lili. Crystalization Stability and Spectral Properties of Yb3+-Doped Alkaline Metal Modified Fluorophosphates Glasses[J]. Acta Optica Sinica, 2008, 28(12): 2383.

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