发光学报, 2012, 33 (10): 1074, 网络出版: 2012-10-12  

钛酸锶钡薄膜的室温光学性能研究

Optical Properties of (Ba0.75Sr0.25)TiO3 Film at Room Temperature
作者单位
西北大学 信息科学与技术学院, 陕西 西安 710127
摘要
采用溶胶-凝胶法制备了(Ba0.75Sr0.25)TiO3薄膜, 研究了不同退火温度下样品的物相结构、薄膜的光致发光性能和光学透过率。结果表明: 室温下非晶钛酸锶钡薄膜在蓝光激发下具有明显的发光现象, 发光波长范围是500~650 nm, 峰值在525 nm附近。延长非晶态薄膜的退火时间能够显著提高样品的发光强度, 且发光强度随薄膜厚度增加而增大。晶态薄膜有微弱的发光现象。透射谱测试结果表明, 钛酸锶钡薄膜在可见光范围内具有良好的光学透过率。
Abstract
(Ba0.75Sr0.25)TiO3 thin film was prepared by sol-gel process. The phase structure, photoluminescence properties and optical transmittance of the films annealed at different temperature were studied respectively. The results show that a strong photoluminescence phenomenon can be observed under blue light excited at room temperature. The emission band is from 500 nm to 650 nm, and the peak is about 525 nm. An enhanced intensity of photoluminescence property was measured by increasing the anneal time for amorphous films. Moreover, the photoluminescence intensity also increases with the film thickness. A weak photoluminescence peak was observed in crystalline film. In addition, both the crystalline and amorphous films have good optical transmittance in the visible light region.
参考文献

[1] Scott J F. Applications of modern ferroelectrics [J]. Science, 2007, 315(5814):954-959.

[2] Kong L B, Li S, Zhang T S, et al. Electrically tunable dielectric materials and strategies to improve their performances [J]. Progress in Materials Science, 2010, 55(8):840-893.

[3] Suhermann P H, Jackson T J, Koutsonas Y, et al. On-wafer microwave characterization of ferroelectric thin film phase shifters [C]// Microwave Symposium Digest, 2004 IEEE MTT-S International, Fort Worth, USA:IEEE, 2004, 1:265-268.

[4] Pizani P S, Leite E R, Pontes F M, et al. Photoluminescence of disordered ABO3 perovskites [J]. Appl. Phys. Lett., 2000, 77(6):824-826.

[5] Leite E R, Paris E C, Pontes F M, et al. The origin of photoluminescence in amorphous lead titanate [J]. Journal of Materials Science, 2003, 38(6):1175-1178.

[6] Orhan E, Pontes F M, Pinheiro C D, et al. Theoretical and experimental study of the relation between photoluminescence and structural disorder in barium and strontium titanate thin films [J]. Journal of the European Ceramic Society, 2005, 25(12):2337-2340.

[7] Sczancoski J C, Cavalcante L S, Badapanda T, et al. Structure and optical properties of [Ba1-xY2x/3](Zr0.25Ti0.75)O3 powders [J]. Solid State Sciences, 2010, 12(7):1160-1167.

[8] Mochizuki S, Fujishiro F, Minami S, et al. Photoluminescence and reversible photo-induced spectral change of SrTiO3 [J]. J. Phys.: Condens. Matter., 2005, 17(6):923-948.

[9] Kan D, Terashima T, Kanda R, et al. Blue-light emission at room temperature from Ar+-irradiated SrTiO3[J]. Nature Materials, 2005, 4:816-819.

[10] Peng J, Xu Z M, Wang S B, et al. Metal organic decomposition technique and optical properties of amorphous Ba0.7Sr0.3-TiO3 thin films [J]. Acta Phys.Sinica (物理学报), 2011, 60(5):057702-1-6 (in Chinese).

[11] Roy S C, Sharma G L, Bhatnagar M C. Large blue shift in the optical band-gap of sol-gel derived Ba0.5Sr0.5TiO3 thin films [J]. Solid State Communications, 2007, 141(5):243-247.

[12] Souza A E, Silva R A, Santos G T A, et al. Order-disorder degree of self-assembled clusters: Influence on photoluminescence emission and morphology of BaxSr1-xTiO3 nanocrystals [J]. Chem. Phys. Lett., 2011, 514(4-6):301-306.

[13] Peng J, Fu Y H, Xu Z M, et al. Room temperature photoluminescence properties of (Ba0.8Sr0.2)TiO3 thin films [J]. Journal of Huazhong University of Science and Technology (华中科技大学学报), 2009, 37(6):121-124 (in Chinese) .

[14] Pontes F M, Pinheiro C D, Longo E, et al. Theoretical and experimental study on the photoluminescence in BaTiO3 amorphous thin films prepared by the chemical route [J]. J. Lumin., 2003, 104(3):175-185.

[15] Gao S X, Chen Y B, Zeng R J. Preparation and characterization of agglomerate-free YAG∶Ce3+ phosphor by co-precipitating and spray drying [J]. Chin. J. Lumin.(发光学报), 2010, 31(6):806-811 (in Chinese).

[16] Zhao A P, Deng H, Liu F. Characterization of YAG∶Ce3+ phosphor synthesized via ultrasonic co-precipitation by different techniques [J]. Chin. J. Lumin.(发光学报), 2011, 32(11):1104-1108 (in Chinese).

高永进, 赵丽丽, 张智翔, 廖付友, 朱红丹. 钛酸锶钡薄膜的室温光学性能研究[J]. 发光学报, 2012, 33(10): 1074. GAO Yong-jin, ZHAO Li-li, ZHANG Zhi-xiang, LIAO Fu-you, ZHU Hong-dan. Optical Properties of (Ba0.75Sr0.25)TiO3 Film at Room Temperature[J]. Chinese Journal of Luminescence, 2012, 33(10): 1074.

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