光学学报, 2001, 21 (4): 417, 网络出版: 2006-08-10   

差分浓度调制激光光谱技术

A Novel Differential Concentration Modulation Spectroscopy
作者单位
1 中国科学院武汉物理与数学研究所波谱与原子分子物理国家重点实验室,武汉 430071
2 武汉大学物理与电子信息学院,武汉 430072
3 华东师范大学物理系,上海 200062
摘要
报道了在近红外波段的差分浓度调制激光光谱技术的研究工作。以N+2的浓度调制光谱为例,研究了浓度调制激光光谱技术的特性。将浓度调制光谱与速度调制光谱相结合得到了速度调制光谱调制度与各因素的关系。同时展示的Ar激发态的差分浓度调制光谱表明,差分浓度调制光谱技术在探测中性自由基分子和分子离子方面具有很大的应用潜力。
Abstract
A novel differential concentration modulation spectroscopic technique was demonstrated with the spectrum of N+2 in the near infrared region. Its properties have been studied. Combining the concentration modulation spectroscopy with velocity modulation spectroscopy, the dependence of the signal to noise ratio on the modulation depth and various other factors are obtained. The high signal to noise ratio concentration modulation spectrum of Ar suggests that this spectroscopic technique will be a very sensitive and convenient method for detecting neutral free radicals and molecular ions.
参考文献

[1] Wilkening L. Comets. Tucson: University of Arizona Press, 1982

[2] Gudeman C S, Begemanm M S, Saykally R J. Velocity-modulated infrared laser spectroscopy of molecular ions: The ν1 band of HCO+. Phys. Rev. Lett., 1983, 50(10):727~731

[3] Gudeman C S, Saykally R J. Velocity modulation infrared laser spectroscopy of molecular ions. Ann. Rev. Phys. Chem., 1984, 35(2):387~418

[4] Hirota E. Microwave and infrared spectra of free radicals and molecular ions. Chem. Rev., 1992, 92(1):141~173

[5] Bawendi M G, Rehfuss B D, Oka T. Laboratory observation of hot bands of H+3. J. Chem. Phys., 1990, 93(9):6200~6209

[6] Zhuan Liu. Infrared diode laser absorption spectroscopy of gas phase molecular ions. Ph. D. Dissertation. University of Cambridge, 1998

[7] Farley J W. Theory of the resonance line shape in velocity-modulation spectroscopy. J. Chem. Phys., 1991, 95(8):5590~5602

高晖, 刘红平, 段传喜, 刘煜炎. 差分浓度调制激光光谱技术[J]. 光学学报, 2001, 21(4): 417. 高晖, 刘红平, 段传喜, 刘煜炎. A Novel Differential Concentration Modulation Spectroscopy[J]. Acta Optica Sinica, 2001, 21(4): 417.

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