钾盐的添加对水热法合成铌酸钾晶体的影响 | 中国激光 -- 中国光学期刊网

中国激光, 2013, 40 (8): 0806005, 网络出版: 2013-08-01

钾盐的添加对水热法合成铌酸钾晶体的影响

Effect of Added Potassium Salt on Preparation of Potassium Niobate by Hydrothermal Processing

论文大纲

曹博 ^1,*于杰 ¹于斌 ¹张欣鹏 ²游诚 ²陈珺文 ²曹慧群 ^2,3

作者单位

¹ 深圳大学光电工程学院光电子器件与系统(教育部/广东省）重点实验室, 广东深圳 518060

² 深圳大学化学与化工学院深圳市新型锂离子电池与介孔材料重点实验室, 广东深圳 518060

³ 浙江大学硅材料国家重点实验室, 浙江杭州 310027

材料铌酸钾水热法荧光性 materials potassium niobate hydrothermal method fluorescence

摘要

采用水热法，以KOH和Nb2O5为主要原料，分别加入KCl、K2SO4、K2CO3和KBr制备了铌酸钾(KNbO3)晶体。采用X射线衍射(XRD)、拉曼光谱、扫描电镜（SEM）、红外光谱（FTIR）、荧光光谱（PL）等方法研究了不同钾盐对合成的KNbO3晶体结构、微观形貌、产量及荧光性的影响。结果表明在水热合成过程中添加钾盐可以明显提高KNbO3晶体的产率，钾盐的种类对KNbO3的晶型和形貌有较大影响，当钾盐分别为KCl和KBr时，产物为0.5～1 μm宽、1～10 μm长,表面光滑的棒，分别为斜方六面体和正交晶型的KNbO3。当钾盐分别为K2CO3和 K2SO4时，产物为不规则块状结构，分别为斜方六面体和正交晶型的KNbO3。FTIR分析表明样品在1383，1087，1050，879,614 cm－1处出现了Nb＝O和Nb－O－Nb的振动峰。荧光光谱分析表明样品在396,450,467,481,491 nm附近出现特征峰。

Abstract

The potassium niobate (KNbO3) is prepared with niobium oxide (Nb2O5) and potassium hydroxide (KOH) as source material by hydrothermal method, which adds different kinds of potassium salt, for example, KCL, K2SO4, K2CO3, KBr. The influence of different potassiums on crystal texture, microstructure, output and fluorescence of the complex KNbO3 is studied by X-ray diffraction (XRD), Raman spectrum, scanning electron microscope (SEM), infrared spectroscopy (FTIR) and fluorescence spectra (PL). Results show that the productivity is improved greatly by the adding of potassium salt. The kind of potassium salt is a critical factor for the structure and morphological profile of the KNbO3. When the added potassium salt is KCl or KBr, the well crystallized KNbO3 rods whose structures are rhombohedral and ortho rhombic form respectively are formed with the width of 0.5～1 μm and the length of 1～10 μm. Using K2CO3 or K2SO4 as the added potassium salt, the formed KNbO3 crystals whose structure are rhombohedral and ortho rhombic form respectively are irregular granular structures instead of rod-like structures. FTIR results indicate that the crystal show Nb＝O and Nb－O－Nb vibration peaks at 1383, 1087, 1050, 879, 614 cm-1. The fluorescence emissions of the KNbO3 samples are detected to appear the characteristic peaks at the wavelengths of 396, 450, 467,481, 491 nm.

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曹博, 于杰, 于斌, 张欣鹏, 游诚, 陈珺文, 曹慧群. 钾盐的添加对水热法合成铌酸钾晶体的影响[J]. 中国激光, 2013, 40(8): 0806005. Cao Bo, Yu Jie, Yu Bin, Zhang Xinpeng, You Cheng, Chen Junwen, Cao Huiqun. Effect of Added Potassium Salt on Preparation of Potassium Niobate by Hydrothermal Processing[J]. Chinese Journal of Lasers, 2013, 40(8): 0806005.

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