光学学报, 2012, 32 (1): 0123005, 网络出版: 2011-12-19   

高显色白光LED的制备及其变温特性

Preparation and Temperature-Variation Properties of High Color Rendering Index LED
作者单位
北京工业大学光电子技术省部共建教育部重点实验室, 北京 100124
摘要
分别用黄色、红色荧光粉和黄色、红色、绿色荧光粉制备了两种高显色指数白光发光二极管(LED),调整荧光粉的比例使显色指数达到最高。对两种样品进行光学测试,发现加绿粉的样品光通量比较大,这是因为加绿粉后绿光成分较多,而绿光的视效函数比红光的大得多。对两种样品进行10 ℃~90 ℃的变温测试,发现发光效率都降低,显色指数反而升高。发光效率降低一方面是由芯片的内量子效率降低引起的,另一方面是芯片的发射波长红移使其与荧光粉的激发波长不匹配,并且荧光粉在升温时激发效率会降低。显色指数升高是因为高温时芯片发出的蓝光光谱变宽,使得整个光谱相对于室温时的光谱更平滑,更接近太阳光谱。
Abstract
Two kinds of high color rendering index light emitting diode (LED) are made by yellow, red phosphor and yellow, red, green phosphor respectively. The light output of the sample with green phosphor is bigger due to more green light in spectrum after the addition of green phosphor and the larger vision function of green light than that of red light. The luminous efficiency decreases and color rendering index increases when the testing temperature varies from 10 ℃ to 90 ℃. This suggests that, besides the degradation of internal quantum efficiency, the mismatch of red shift of wavelength of the chip and the excitation wavelength of phosphor and the degradation of excitation efficiency of phosphor at high temperature are all the reasons of degradation of luminous efficiency. The color rendering index increases due to wider spectrum of blue light emitted by the chip at high temperature which makes the spectrum smoother and closer to the spectrum of the sun.
参考文献

[1] Naichia Yeh, Jenping Chung. High-brightness LEDs—energy efficient lighting sources and their potential in indoor plant cultivation[J]. Renew. Sust. Energ. Rev., 2009, 13(8): 2175~2180

[2] N. Pal, P. K. Sadhu, R. P. Gupta et al.. Review of LED based cap lamps for underground coalmines to improve energy efficiency as compared to other light sources[C]. International Conference on Computer and Automation Engineering, 2010, 5: 675~677

[3] Isamu Niki, Yukio Narukawa, Daisuke Morita et al.. White LEDs for solid state lighting[C]. SPIE, 2004, 5187: 1~9

[4] Daniel A. Steigerwald, Jermome C. Bhat, Dave Collins et al.. Illumination with solid-state lighting technology[J]. IEEE J. sel. Top. Quant., 2002, 8(2): 310~320

[5] 吴海彬, 王昌铃, 何素梅. 涂敷红、绿荧光粉的白光L ED显色性研究[J]. 光学学报, 2008, 28(9): 1777~1782

    Wu Haibin, Wang Changling, He Sumei. Research of color rendering of white LED based on red and green phosphors[J]. Acta Optica Sinica, 2008, 28(9): 1777~1782

[6] 廖金生, 邱报, 温和瑞 等. 单分散球形BaWO4Tb3+绿色荧光粉合成及光谱性能[J]. 光学学报, 2010, 30(3): 839~843

    Liao Jinsheng, Qiu Bao, Wen Herui et al.. Synthesis and luminescence properties of monodispersed spheres for BaWO4Tb3+ green phosphors[J]. Acta Optica Sinica, 2010, 30(3): 839~843

[7] 李雅丽, 王超男, 宋国华 等. 溶胶凝胶法和微波辐射法制备红色荧光粉及发光性质的研究[J]. 光学学报, 2011, 31(3): 0316001

    Li Yali, Wang Chaonan, Song Guohua et al.. Luminescent properties of red phosphors prepared by sol-gel and microwave radiation methods[J]. Acta Optica Sinica, 2011, 31(3): 0316001

[8] Regina Mueller-Mach, Gerd O. Mueller, Michael R. Krames et al.. High-power phosphor-converted light-emitting diodes based on III-nitrides[J]. IEEE J. Sel. Topics Quant., 2002, 8(2): 339~345

[9] Joung Kyu Park, Chang Hae Kim, Seung Hyok Park et al.. Application of strontium silicate yellow phosphor for white light-emitting diodes[J]. Appl. Phys. Lett., 2004, 84(10): 1647~1649

[10] 夏威, 雷明凯, 罗昔贤 等. 宽激发带稀土激活碱土金属硅酸盐发光材料特性研究[J]. 光谱学与光谱分析, 2008, 28(1): 41~46

    Xia Wei, Lei Mingkai, Luo Xixian et al.. Broad excitation band alkaline-earth silicate luminescent materials activated by rare earth and its applications[J]. Spectrosc. & Spectral Anal., 2008, 28(1): 41~46

[11] 钟传鹏. 大功率LED荧光胶封装工艺对其显色性能的影响[J]. 现代显示, 2009, 103: 56~61

    Zhong Chuanpeng. Influence of flourescent glue packaging technology on the color rendering index of high power LED[J]. Advanced Display, 2009, 103: 56~61

[12] Wonkeun Chung, Hong Jeong Yu, Sun Hee Park et al.. YAG and CdSe/ZnSe nanoparticles hybrid phosphor for white LED with high color rendering index[J]. Mater. Chem. & Phys., 2011, 126: 162~166

[13] Harumasa Yoshida, Masakazu Kuwabara, Yoji Yamashita et al.. Radiative and nonradiative recombination in an ultraviolet GaN/AlGaN multiple-quantum-well laser diode[J]. Appl. Phys. Lett., 2010, 96(21): 211122

[14] Patrick N. Grillot, Michael R. Krames, Hanmin Zhao et al.. Sixty thousand hour light output reliability of AlGaInP light emitting diodes[J]. IEEE T. Device Mat. Re., 2006, 6(4): 565~569

[15] 郝海涛, 周禾丰, 梁建 等. 白光LED蓝光转换材料的发光特性研究[J]. 光谱学与光谱分析, 2007, 27(2): 240~243

    Hao Haitao, Zhou Hefeng, Liang Jian et al.. Luminescence properties of white LED blue light conver sion materials[J]. Spectrosc. & Spectral Anal., 2007, 27(2): 240~243

[16] C. C. Lin, Y. S. Zheng, H. Y. Chen, et al.. Improving optical properties of white LED fabricated by a blue LED chip with yellow/red phosphors[J]. J. Electrochem. Soc., 2010, 157(9): H900~H903

崔德胜, 郭伟玲, 崔碧峰, 闫薇薇, 刘莹. 高显色白光LED的制备及其变温特性[J]. 光学学报, 2012, 32(1): 0123005. Cui Desheng, Guo Weiling, Cui Bifeng, Yan Weiwei, Liu Ying. Preparation and Temperature-Variation Properties of High Color Rendering Index LED[J]. Acta Optica Sinica, 2012, 32(1): 0123005.

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