All-metallic wide-angle metasurfaces for multifunctional polarization manipulation
1 Introduction
As one of the most fundamental rules in classical optics, the Fresnel equations, accompanied with Snell's law, determine the reflection and transmission of light incident on an interface of two media with different refractive indices. One important consequence of the Fresnel equations is the Brewster effect, which means the reflectivity for the wave polarized in the plane of incidence (p-polarization) vanishes at a particular incidence angle (Brewster angle). The Brewster effect can be intuitively understood by investigating the elemental dipole radiation1, which provides many physical insights into this problem. In a more general sense, the modified Brewster effect has been widely utilized to realize extraordinary transmission and broadband angular filters2, 3. Since the Brewster effect is an interface phenomenon, any modification of the surface conditions would change the light behavior. When a metasurface consisting of periodic or quasi-periodic subwavelength inclusions is inserted at the interface4-12, the Fresnel equations can be generalized to change the reflection, refraction properties on demand13.
In the ideal case, the reflectivity of p-polarized wave at the Brewster angle would be zero. However, in general most materials used in optics and electromagnetics are lossy to some extent, thus the minimum reflectivity is not exactly zero. For strongly lossy materials such as metals, the minimal reflectivity is often larger than 10%, thus the corresponding angle is termed pseudo-Brewster angle14, 15. Note that metal is often treated as a good reflector in most electromagnetic spectrum, thus the reflection minimum seems to be an "abnormal" effect. The energy transmitting into metal would be totally absorbed since there is no way to let them transmit if the metal thickness is larger than the skin depth. This absorption is indeed very strong at the infrared and visible wavelengths, where metal could not be treated as perfect conductors as they were in the microwave range.
The control of the polarization-dependent absorption at pseudo-Brewster angle has great significance in infrared applications such as functional devices and infrared polarimetric detection. According to the Kirchhoff's law16, the thermal emission due to blackbody radiation would also be highly dependent on angle and polarization since the thermal emissivity at infrared region equals to the absorptivity. This also explains why the thermal radiation differs from that described by Lambert's cosine law17. As a result, polarimetric imaging could provide a new route for infrared surveillance with the ability to reveal the hidden metallic objects18.
Here we propose a concept for the design of structured surfaces with inhibited pseudo-Brewster effect. By eliminating the energy loss of surface electromagnetic wave propagating along a structured metallic surface, we show that both the polarimetric thermal emission and laser's reflection loss can be significantly reduced. Consequently, the proposed metasurfaces will serve as an efficient way to modify the polarization states, for either thermal infrared radiation or coherent laser beam.
2 Results and discussions
To characterize the physical principle of our design, we first consider the Fresnel's reflection at a lossy metal surface under variant angles of incidence. Since the metal is thick enough to absorb the transmitted light, the angle and polarization dependent absorptivity should be:
and
where
In a phenomenological view, the increased absorption at the pseudo-Brewster angle is associated with the large vertical electric fields
Fig. 1. (a) Electromagnetic reflection on a flat surface at the pseudo-Brewster angle. Note that the reflection minimum is related to the Zenneck surface wave that propagates along the interface between air and a lossy smooth metal. (b) Electric field distribution at the pseudo-Brewster angle for a posts array.
To prove the above hypothesis, a full-wave finite-element method (FEM) is adopted to solve the Maxwell's Equations in the structured surface rigorously26. The results have also been compared with theoretical model that approximate the structured surface to be an equivalent boundary condition. As depicted in
Fig. 2. Theoretical analysis of the metallic grating.(a ) Reflectance of s- and p-polarized light for a smooth gold plate. (b ) Reflectance of s- and p-polarized light for a gold plate decorated with subwavelength posts array. (c ) Energy flow in the xz-plane when p-polarized light is incident with a angle of 80°. (d ) Schematic of the wavevector mismatching at the air-posts interface. (e ) and (f ) Amplitudes of the electric fields for s- and p-polarization at θ =80°.
One fascinating property of the reflection spectra shown in
In our experiments, the posts array was fabricated by triple resist technology followed by laser direct writing and electron beam deposition (Fig. S2). The SEM image of a sample coated with gold is shown in
Fig. 3. Broadband reflectance and polarimetric imaging.(a ) Perspective view of the gold-sample. (b ) and (c ) FTIR spectra of the gold sample for incidence angles of 70° to 80°. The p- and s-polarizations are indicated in each panel. (d ) Perspective view of the chromium sample. (e ) and (f ) Polarized infrared images of the chromium-sample and a reference sample for p- and s- polarizations. The strong emission at the circumference of the sample is from the silicon dioxide substrate (the diameter of the substrate is 2.5 cm and the structured is fabricated in a square region with a width of 1.5 cm).
The metallic posts array can be used to suppress the p-polarized thermal radiation near the pseudo-Brewster angle. We note that this directive and polarized thermal radiation of flat metal surface have been observed by Arago in almost two hundred years ago30, in stark contrast to the Lambert's radiation law as well as the common sense about the spatial coherence of thermal radiation31. It was recently realized that the Lambert's cosine law is only valid for perfect black body, thus nearly all manmade objects would have directive and polarized emission to some extent16. For the thermal radiation of a metal surface, the physical process can be viewed in a different picture: the total thermal emission can be considered as the black-body radiation that transmitted from metal to air32. Different from the coherent thermal emission assisted by surface-phonon polaritons31, the directive and polarized thermal emission of flat metal surface can be ascribed to the excitation of Zenneck surface wave at the pseudo-Brewster angle33, 34.
To demonstrate the suppressed unusual thermal radiation, the infrared images of a posts array (
Although there are almost no difference between the reflectance and absorbance between the p- and s-polarizations for all incidence angles, some relative phase shift would occur between the two polarized components. This can be well characterized by our impedance model. As depicted in
Fig. 4. Metallic posts array acting as a reflective waveplate.(a ) Reflective phase retardation at different incidence angles for s- and ppolarizations at λ =10.6 μm. The distance between the reference plane and the top of the posts array is 10 μm. The theory is based on the effective impedance and transfer matrix method. (b ) Measured ellipticity of the reflected laser beam generated by a CO2 laser (λ =10.6 μm).
3 Conclusions
In summary, the most remarkable feature of the results shown in this paper is that the pseudo-Brewster effect can be nearly completely eliminated, leading to significantly reduced and non-polarized thermal emission and providing an important means to achieve polarimetric crypsis. This simple structure is also easy to fabricate in large volume for practical applications. Besides the camouflage applications, we showed that the same surface-relief structure can be used as a highly-efficient reflective mirror, which could generate circular polarization in a broadband spectrum. Different from the anisotropic metamirror37, 38, this phenomenon might be described by the extrinsic anisotropy and regarded as a generalization of the Brewster' law1.
4 Acknowledgements
We acknowledge the financial support by National Natural Science Foundation of China under contact Nos. 61622508, 61622509, and 61675208.
5 Competing interests
The authors declare no competing financial interests.
6 Supplementary information
[14] G Ohman. The pseudo-brewster angle. IEEE Trans Antennas Propag, 1977, 25: 903-904.
[20] K L Wang, D M Mittleman. Metal wires for terahertz wave guiding. Nature, 2004, 432: 376-379.
[25]
[26]
[30] O Sandus. A review of emission polarization. Appl Opt, 1965, 4: 1634-1642.
Article Outline
Xiaoliang Ma, Mingbo Pu, Xiong Li, Yinghui Guo, Xiangang Luo. All-metallic wide-angle metasurfaces for multifunctional polarization manipulation[J]. Opto-Electronic Advances, 2019, 2(3): 180023.