中国激光, 2020, 47 (10): 1003004, 网络出版: 2020-09-27
掺铥钬离子碲锗酸盐玻璃2 μm发光性能研究 下载: 1055次
2 μm Fluorescence Properties of Tm 3+ and Ho 3+ ions Doped Tellurite-Germanate Glass
图 & 表
图 1. 未掺杂稀土离子的碲锗酸盐玻璃的差热分析曲线和拉曼光谱图。(a)差热分析曲线和玻璃样品实物图; (b)拉曼光谱图
Fig. 1. Differential thermal analysis curve and Raman spectrum of tellurite-germanate glass undoped with rare earth ions. (a) Differential thermal analysis curve and picture of glass sample; (b) Raman spectrum
图 2. 稀土离子掺杂的碲锗酸盐玻璃的吸收光谱。(a)掺Tm2O3的玻璃样品的吸收光谱;(b)分别掺Ho3+/Yb3+、Yb3+、Ho3+离子的玻璃样品的吸收光谱
Fig. 2. Absorption spectra of rare earth ions doped tellurite-germanate glass. (a) Absorption spectra of Tm2O3 doped glass samples; (b) absorption spectra of glass samples doped with Ho3+/Yb3+, Yb3+, and Ho3+, respectively
图 3. 稀土离子掺杂的碲锗酸盐玻璃的荧光光谱和衰减寿命曲线。 (a)掺Tm2O3的玻璃样品的荧光光谱图;(b) Ho3+/Yb3+共掺的玻璃样品的荧光光谱图;(c)掺杂0.4% Tm3+的玻璃样品的衰减寿命曲线;(d)掺杂1% Ho3+/0.5% Yb3+的玻璃样品的衰减寿命曲线
Fig. 3. Fluorescence spectra and decay lifetime curves of rare earth ions doped tellurite-germanate glass. (a) Fluorescence spectra of Tm2O3 doped glass samples; (b) fluorescence spectra of Ho3+/Yb3+ co-doped glass samples; (c) decay life curve of glass sample doped with 0.4% Tm3+; (d) decay life curve of glass sample doped with 1% Ho3+ and 0.5% Yb3+
图 4. 铥钬离子的能级简化图。(a) Tm3+离子;(b) Ho3+/Yb3+离子
Fig. 4. Simplified energy level diagrams of Tm3+ and Ho3+ ions. (a) Tm3+ ion; (b) Ho3+/Yb3+ ions
图 5. 稀土离子掺杂的碲锗酸盐玻璃的吸收发射截面和增益图谱。(a)掺杂0.4% Tm3+的玻璃样品的吸收发射截面;(b)掺杂1% Ho3+/0.5% Yb3+的玻璃样品的吸收发射截面;(c)掺杂0.4% Tm3+的玻璃样品的增益图谱;(d)掺杂1% Ho3+/0.5% Yb3+的玻璃样品的增益图谱
Fig. 5. Absorption and emission cross sections and gain coefficient of rare earth ions doped tellurite-germanate glass. (a) Absorption and emission cross sections of glass sample doped with 0.4% Tm3+; (b) absorption and emission cross sections of glass sample doped with 1% Ho3+/0.5% Yb3+; (c) gain coefficient of glass sample doped with 0.4% Tm3+; (d) gain coefficient of glass sample doped with 1% Ho3+/0.5% Yb3+
表 1碲锗酸盐玻璃中掺杂的稀土离子含量
Table1. Molar content of rare earth ions doped in tellurite-germanate glass
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表 2Tm3+单掺和Ho3+/Yb3+共掺的碲锗酸盐玻璃的J-O参数
Table2. J-O parameters of Tm3+ doped and Ho3+/Yb3+ co-doped tellurite-germanate glass
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王震, 谢文青, 豆奥举, 华有杰, 叶仁广, 蔡沐之, 徐时清, 张军杰. 掺铥钬离子碲锗酸盐玻璃2 μm发光性能研究[J]. 中国激光, 2020, 47(10): 1003004. Wang Zhen, Xie Wenqing, Dou Aoju, Hua Youjie, Ye Renguang, Cai Muzhi, Xu Shiqing, Zhang Junjie. 2 μm Fluorescence Properties of Tm 3+ and Ho 3+ ions Doped Tellurite-Germanate Glass[J]. Chinese Journal of Lasers, 2020, 47(10): 1003004.