中国激光, 2013, 40 (8): 0803003, 网络出版: 2013-07-09   

镍包石墨对激光熔覆镍基合金涂层组织和性能的影响

Influence of Graphite/Ni on Microstructure and Properties of Laser Clad Ni-Based Alloy Coatings
作者单位
大连理工大学三束材料改性教育部重点实验室, 辽宁 大连 116024
摘要
采用激光熔覆技术在40CrNi2Si2MoV钢表面制备了不同含量的镍包石墨镍基复合涂层。利用X射线衍射仪(XRD)、扫描电镜、能谱分析仪(EDX)、显微硬度计和摩擦磨损试验机,对不同镍包石墨含量镍基复合涂层的相组成、微观组织形貌、成分、硬度及摩擦磨损性能进行了分析。研究结果表明,不同镍包石墨含量的复合涂层均主要由γ-Ni、Ni3B、M23C6和M7C3相所组成,但有所不同的是,随着镍包石墨含量的增加,复合涂层凝固组织逐渐细化,共晶组织数量逐渐增多,且在镍包石墨添加量超过10.0%(体积分数)时,组织中开始有明显的石墨相出现。受上述组织变化的影响,复合涂层的平均硬度值和耐磨性随着镍包石墨含量的增加而逐渐提高,而减摩性能则呈现出先降后增的变化趋势,当镍包石墨添加量为6.0%(体积分数)时,复合涂层具有最低的减摩性能。
Abstract
Ni-based composite coatings with different graphite/Ni contents are prepared by laser cladding on the 40CrNi2Si2MoV steel. The microstructure and properties of the composite coatings are investigated by means of X-ray diffraction (XRD), scanning electron microscopy, energy dispersive X-ray (EDX) spectroscopy, Vickers hardness tester, and friction wear testing machine. The results show that the composite coatings mainly consist of γ-Ni, Ni3B, M23C6, and M7C3 phases. But with the graphite/Ni addition increasing, the contents of the eutectic increase. The graphite is observed as the graphite/Ni addition is beyond 10.0% (volume fraction). The changes in the microstructure improve the hardness and the wear resistance of the coatings while the anti-friction property presents a trend of first decreasing and then increasing, and the lowest anti-friction property is obtained as the graphite/Ni addition is 6.0%.
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马超, 王存山. 镍包石墨对激光熔覆镍基合金涂层组织和性能的影响[J]. 中国激光, 2013, 40(8): 0803003. Ma Chao, Wang Cunshan. Influence of Graphite/Ni on Microstructure and Properties of Laser Clad Ni-Based Alloy Coatings[J]. Chinese Journal of Lasers, 2013, 40(8): 0803003.

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