光学学报, 2013, 33 (6): 0612004, 网络出版: 2013-05-22   

基于调频光谱原理的在线式表面等离子体共振光纤传感器

Investigation on On-Line Optical Fiber Surface Plasma Resonance Sensors Based on Frequency Modulation Spectroscopy
作者单位
1 南京农业大学工学院 江苏省智能化农业装备重点实验室, 江苏 南京 210031
2 淮阴工学院电子与电气工程学院, 江苏 淮安 223003
摘要
基于调频光谱原理,提出一种可用于在线测量的表面等离子体共振光纤传感器结构。理论分析、数值仿真和实测结果表明,基于表面等离子体共振效应的光纤传感头,相当于具有中心对称吸收谱的吸收介质,且吸收峰中心波长随待测折射率的增加而红移;基于此吸收谱函数,以微分光谱替代直接光谱测量,可有效克服吸收峰处一阶微分谱为零对测量灵敏度的消极影响;参考光路及闭环负反馈结构的引入,可有效抑制源于光源和光路中光强波动等的影响。以镀有50 nm厚金薄膜的多模石英光纤组成传感头,搭建相应的闭环系统,对折射率为1.33000~1.43000范围内不同液体进行折射率测量,并与阿贝折射率仪、光纤光谱仪及理论仿真结果进行比较。结果表明, 在1.33200~1.37580 RIU(RIU表示单位折射率)范围内,测量精度可达0.00016 RIU,与波长分辨率为0.4 nm的光谱仪测量结果精度相当;在1.37500~1.42640 RIU范围内,测量精度可达0.00071 RIU,优于0.00090 RIU的光谱仪测量结果,较好地验证了该方案用于在线测量的可行性和检测结果的可靠性。
Abstract
An optimal structure of on-line optical fiber surface plasma resonance (SPR) sensors is proposed based on principle of frequency modulation. On the basis of theoretical analysis, numerical simulation and measured results, the optical fiber SPR sensing probes can be regarded as an absorbing medium with a centro symmetric absorption spectrum function, whose central wavelength at absorbing peak has a red-shift as increasing the refractive index of measured medium. The features of this centro symmetric absorption spectrum function make it possible to overcome the negative effect on measurement sensitivity originating from zero-value point of differential spectra at absorbing peak in directly measuring spectral method by the application of frequency modulation principle. And the adverse effects, rising from the intensity fluctuation of light source and in light propagating paths, can be suppressed by introduction of reference light path and negative feedback closed-loop system structure. The probes, which are made up of 15-mm long silica multi-mode optical fiber plated with 50-nm thick gold film, are applied in the proposed model, the corresponding experiments are arranged to measuring different liquid mediums with the index range of 1.33000~1.43000 refractive index unit (RIU).Then, discussion and analysis are carried out based on the data, which are got from the proposed method and other methods, such as Abbe refractometer, optical fiber spectrometer and numerical emulation. The results indicate that the precision of the proposed model is 0.00016 RIU at the range of 1.33200~1.37580 RIU, which is the same as measured results by applying optical fiber spectrometer with 0.4 nm wavelength resolution, and the precision is 0.000710 RIU at the range which is better than measured results by using optical fiber spectrometer with 0.0009 RIU. Therefore, the feasibility and reliability of the proposed method and the application for on-line measurement can be confirmed.
参考文献

[1] 李海波, 徐抒平, 刘钰 等. 波长型SPR检测仪的灵敏度探讨[J]. 高等学校化学学报, 2010, 31(11): 2157~2161

    Li Haibo, Xu Shuping, Liu Yu et al.. Studies on the sensitivity of a wavelength-dependent PR sensor [J]. Chemical J. Chinese Universities, 2010, 31(11): 2157~2161

[2] 张美, 代吉祥, 杨明红 等. 基于表面等离子体共振的钯膜氢气传感器[J]. 中国激光, 2011, 38(12): 1205005

    Zhang Mei, Dai Jixiang, Yang Minghong et al.. Fiber-optic surface plasmon resonance hydrogen sensor based on palladium coating [J]. Chinese J. Lasers, 2011, 38(12): 1205005

[3] 刘琨, 刘铁根, 江俊峰 等. 基于波长调制技术的内腔式气体传感研究[J]. 中国激光, 2011, 38(1) 0105008

    Liu Kun, Liu Tiegen, Jiang Junfeng et al.. Investigation of intra-cavity gas sensing technology based on wavelength modulation [J]. Chinese J. Lasers, 2011, 38(1): 0105008

[4] 王林, 何俊, 李芳 等. 用于探测极低频信号的光纤传感器相位生成载波解调方法[J]. 中国激光, 2011, 38(4): 0405001

    Wang Lin, He Jun, Li Fang et al.. Ultra low-frequency phase generated carrier demodulation technique for fiber sensors [J]. Chinese J. Lasers, 2011, 38(4): 0405001

[5] 余贶琭, 吴重庆, 郭旋 等. 基于波分复用的多点光纤乙炔传感系统[J]. 光学学报, 2011, 31(5): 0506003

    Yu Kuanglu, Wu Chongqing, Guo Xuan et al.. A novel multi-point fiber optics acetylene sensing system based on dense wavelength division multiplexers [J]. Acta Optica Sinica, 2011, 31(5): 0506003

[6] 谢作生, 李伟文, 林伟鹏 等. 利用扫频光纤激光器实现低频周期振动传感[J]. 中国激光, 2011, 38(12): 1205006

    Xie Zuosheng, Li Weiwen, Lin Weipeng et al.. Implementation of low-frequency periodic vibration sensor based on frequency-swept fiber laser [J]. Chinese J. Lasers, 2011, 38(12): 1205006

[7] 罗彬彬, 赵明富, 周晓军 等. 基于结构化光纤Bragg光栅的折射率梯度传感器研究[J]. 光学学报, 2012, 32(3): 0306004

    Luo Binbin, Zhao Mingfu, Zhou Xiaojun et al.. Research on the refractive-index gradient sensor based on the structured fiber Bragg grating [J]. Acta Optica Sinica, 2012, 32(3): 0306004

[8] 赵华新, 蒋永翔, 罗天穹 等. 基于表面等离子体共振原理的空心光纤传感器[J]. 光学学报, 2012, 32(6): 0628001

    Zhao Huaxin, Jiang Yongxiang, Luo Tianqiong et al.. Hollow optical fiber sensor based on surface plasmon resonace [J]. Acta Optica Sinica, 2012, 32(6): 0628001

[9] 曾捷, 梁大开, 曾振武 等. 基于SPR光谱分析的液体折射率测量研究[J]. 光谱学与光谱分析, 2006, 26(4): 723~727

    Zeng Jie, Liang Dakai, Zeng Zhenwu et al.. Study on measurement of liquid refractive index by analyzing SPR spectrum character [J]. Spectroscopy and Spectral Analysis, 2006, 26(4): 723~727

[10] 黄昌春, 李云梅, 孙德勇 等. 太湖水体散射光谱特性及其形成机理研究[J]. 光学学报, 2011, 31(5): 0501003

    Huang Changchun, Li Yunmei, Sun Deyong et al.. Research of scattering spectrum characteristic and formative mechanism of Taihu lake waters [J]. Acta Optica Sinica, 2011, 31(5): 0501003

[11] 施坤, 李云梅, 王桥 等. 内陆湖泊富营养化水体散射系数模型研究[J]. 光学学报, 2010, 30(9): 2478~2485

    Shi Kun, Li Yunmei, Wang Qiao et al.. Study of scattering coefficients model in inland eutrophic lake [J]. Acta Optica Sinica, 2010, 30(9): 2478~2485

[12] Y. Huot, A. Morel, M. S. Twardowski et al.. Particle optical backscattering along a chlorophyll gradient in the upper layer of the eastern South Pacific Ocean [J]. Biogeosciences, 2008, 5(2): 495~507

[13] 周雯, 曹文熙, 李彩 等. 由吸收系数与粒度分布计算浮游植物的散射光谱特征[J]. 光学学报, 2008, 28(8): 1429~1432

    Zhou Wen, Cao Wenxi, Li Cai et al.. Spectral scattering property of phytoplankton calculated by absorption cooefficient and size distribution [J]. Acta Optica Sinica, 2008, 28(8): 1429~1432

[14] 刘畅, 邹正峰, 陈淑芬 等. 基于光盘光栅的表面等离子体共振传感器[J]. 中国激光, 2012, 39(3): 0314001

    Liu Chang, Zou Zhengfeng, Chen Shufeng et al.. Surface plasmon resonance sensor based on compact disk grating [J]. Chinese J. Lasers, 2012, 39(3): 0314001

[15] 耿俊清, 余兴龙, 章恩耀 等. 基于相位解算的SPR传感方法及其应用[J]. 仪器仪表学报, 2012, 33(10): 2168~2174

    Geng Junqing, Yu Xinglong, Zhang Enyao et al.. SPR biosensing method based on phase shift algorithm and its application [J]. Chinese J. Scientific Instrument, 2012, 33(10): 2168~2174

[16] 沈云, 范定寰, 傅继武 等. 加入增益介质的表面等离子体激元耦合共振波导传输特性理论研究[J]. 物理学报, 2011, 60(11): 117302

    Shen Yun, Fan Dinghuan, Fu Jiwu et al.. Theoretical research on optical properties of gain-assisted plasmonic coupled resonator optical waveguides [J]. Acta Physica Sinica, 2011, 60(11): 117302

[17] 吴英才, 顾铮. 激励表面等离子共振的金属薄膜最佳厚度分析[J]. 物理学报, 2008, 57(4): 2295~2298

    Wu Yingcai, Gu Zhentian. Research on the optimum thickness of metallic thin films utilized to excited surface plasmon resonance [J]. Acta Physica Sinica, 2008, 57(4): 2295~2298

[18] 卢启景, 吴根柱, 陈达如 等. 表面等离子体激元微盘的优化设计及应用[J]. 光学学报, 2012, 32(7): 0714002

    Lu Qijing, Wu Genzhu, Cheng Daru et al.. Optimal design and application of surface plasmon polaritons microdisk [J]. Acta Optica Sinica, 2012, 32(7): 0714002

[19] 马伟涛, 周骏, 黄水平 等. 金属膜衬底上亚波长介质光栅结构的特性及传感应用[J]. 中国激光, 2011, 38(9): 0905008

    Ma Weitao, Zhou Jun, Huang Shuiping et al.. Characteristic of subwavelength dielectric grating with metal layer and its sensing application [J]. Chinese J. Lasers, 2011, 38(9): 0905008

[20] 马慧莲, 金仲和, 丁纯 等. 谐振腔光纤陀螺中信号检测方法的研究[J]. 中国激光, 2004, 31(8): 1001~1005

    Ma Huilian, Jin Zhonghe, Ding Chun et al.. Research on signal detection method of resonator fiber optic gyro [J]. Chinese J. Lasers, 2004, 31(8): 1001~1005

[21] Y. Ohtsuka. Analysis of a fiber-optic passive loop resonator gyroscope: dependence on resonator parameters and light source coherence [J]. J. Lightwave Technol., 1985, LT-3(2): 378~383

[22] 王马华, 崔一平, 张彤. 聚合物集成光学陀螺耦合比优化的研究[J]. 光学学报, 2007, 27(10): 1793~1796

    Wang Mahua, Cui Yiping, Zhang Tong. Investigation on the optimization for the coupling coefficient of polymer integrated optic gyros [J]. Acta Optica Sinica, 2007, 27(10): 1793~1796

[23] Manfred Gehrtz, Gary C. Bjorklund. Quantum-limited laser frequency modulation spectroscopy [J]. J. Opt. Soc. Am. B, 1985, 2(9): 1510~1525

付丽辉, 尹文庆. 基于调频光谱原理的在线式表面等离子体共振光纤传感器[J]. 光学学报, 2013, 33(6): 0612004. Fu Lihui, Yin Wenqing. Investigation on On-Line Optical Fiber Surface Plasma Resonance Sensors Based on Frequency Modulation Spectroscopy[J]. Acta Optica Sinica, 2013, 33(6): 0612004.

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