The characteristics of stimulated Brillouin scattering (SBS) in perfluorinated amine media and the experimental structure used in hundreds of picoseconds pulse compression at 532 nm are demonstrated. A two-stage SBS pulse compression structure is adopted for this work. The compact double-cell SBS compression structure and the scattering media FC-70 are chosen to compress the incident light from 9.5 to about 1 ns in the first stage. Then, the light is used as the pumping source for the second pulse compression. In the second stage, using a single-cell SBS structure in a pulse compression system, perfluorinated amine media with different phonon lifetimes, such as FC-3283, FC-40, FC-43, and FC-70, are chosen to run the comparative experimental study. The narrowest compressed pulse times obtained are 294, 274, 277, and 194 ps; they respectively correspond to the above listed media. The average width of the compressed pulse width is 320 ps for FC-3283, with a fluctuation range of 87 ps. For FC-40, the average pulse width is 320 ps, with a fluctuation range of 72 ps. And for FC-43, the average pulse width is 335 ps, with a fluctuation range of 88 ps. However, the average pulse width is only 280 ps for FC-70, with a fluctuation range of 57 ps. The highest energy reflectivity is more than 80% for all of the media. The experimental results show that a two-stage SBS pulse compression system has lower pump energy requirements, thus making it easier to achieve a compressed pulse waveform. The results also show that the shorter the phonon lifetime of the medium, the narrower the obtained compressed pulse width.