Author Affiliations
Abstract
1 Laboratory of Infrared Materials and Devices, Research Institute of Advanced Technologies, Ningbo University, Ningbo 315211, China
2 Engineering Research Center for Advanced Infrared Photoelectric Materials and Devices of Zhejiang Province, Ningbo University, Ningbo 315211, China
3 Department of Quantum Science and Technology, Research School of Physics, Australian National University, Canberra ACT 2601, Australia
4 School of Physics and Optoelectronics Engineering, Xidian University, Xi’an 710071, China
Three-dimensional (3D) nonlinear photonic crystals have received intensive interest as an ideal platform to study nonlinear wave interactions and explore their applications. Periodic fork-shaped gratings are extremely important in this context because they are capable of generating second-harmonic vortex beams from a fundamental Gaussian wave, which has versatile applications in optical trapping and materials engineering. However, previous studies mainly focused on the normal incidence of the fundamental Gaussian beam, resulting in symmetric emissions of the second-harmonic vortices. Here we present an experimental study on second-harmonic vortex generation in periodic fork-shaped gratings at oblique incidence, in comparison with the case of normal incidence. More quasi-phase-matching resonant wavelengths have been observed at oblique incidence, and the second-harmonic emissions become asymmetric against the incident beam. These results agree well with theoretic explanations. The oblique incidence of the fundamental wave is also used for the generation of second-harmonic Bessel beams with uniform azimuthal intensity distributions. Our study is important for a deeper understanding of nonlinear interactions in a 3D periodic medium. It also paves the way toward achieving high-quality structured beams at new frequencies, which is important for manipulation of the orbital angular momentum of light.
second-harmonic generation nonlinear photonic crystal periodically poled ferroelectric crystal quasi-phase matching nonlinear wavefront shaping 
Chinese Optics Letters
2024, 22(4): 041902
作者单位
摘要
1 临沂大学材料科学与工程学院, 临沂 276000
2 中材人工晶体研究院有限公司, 北京 100018
3 山东大学晶体材料国家重点实验室, 济南 250100
本文采用固相反应法探索了Aurivillius结构Bi2MoxW1-xO6体系的合成条件以及能够形成固溶体的成分范围, 探索了Bi2MoxW1-xO6晶体的助熔剂法生长体系, 并对晶体的结构、变温介电性质和电阻率进行了测定和分析。Bi2MoxW1-xO6体系中Mo的占比x可以在0~1的范围内连续变化, 采用固相反应法可以在500~870 ℃范围内的不同温度合成纯的Bi2MoxW1-xO6铁电相。采用Li2B4O7-Bi2O3(摩尔比2∶1)作为助熔剂生长得到了厘米级Bi2WO6单畴晶体, 厚度不小于2 mm, 最大尺寸则达到了约40 mm。在n(Bi2O3)∶n(MoO3)∶n(WO3)∶n(Li2B4O7)=1∶1∶1∶1(摩尔比)体系中生长得到了厚度约1 mm的Bi2Mo0.15W0.85O6厘米量级单畴晶体, 结构解析表明Bi2Mo0.15W0.85O6属于正交晶系, Aba2(No.41)空间群。变温介电性质测试表明, Bi2Mo0.15W0.85O6晶体的介电常数ε33由Bi2WO6晶体的70提高到了102, 介电弛豫现象发生的温度由Bi2WO6晶体的430 ℃降到了330 ℃附近。变温电阻率测试表明, Bi2WO6与Bi2Mo0.15W0.85O6晶体的电阻率均随温度升高而降低, 在100 ℃以下, Bi2WO6的电阻率高于Bi2Mo0.15W0.85O6晶体, 且随温度升高, 二者电阻率的差距在逐渐缩小。
Aurivillius结构 助熔剂法 晶体结构 介电性质 铁电晶体 电阻率 Bi2MoxW1-xO6 Bi2MoxW1-xO6 Aurivillius structure flux method crystal structure dielectric property ferroelectric crystal resistivity 
人工晶体学报
2022, 51(11): 1858
作者单位
摘要
中国科学院上海硅酸盐研究所(嘉定园区), 上海 201800
主要阐述了当前热释电红外探测器的发展状况,并重点介绍了我国尤其是我们在新型热释电材料以及 红外探测器方面的主要进展和成果。弛豫铁电单晶是一类具有优异压电性能的新型材料,同时我们发现该类晶体还具有 优异的热释电性能。我们所生长的PMNT单晶的热释电系数超过15.3×10-4 cm-2 · K-1,Mn-PMNT的介电损耗降至0.0005, 探测优值达到40.2×10-5 Pa-1/2,高居里温度点单晶PIMNT的居里温度达到180℃以上。与合作单位一起利用该类晶体 研制的红外探测器的性能远优于利用传统热释电材料(如LiTaO3 )制作的探测器,其比探测率达到1.07×109 cm · Hz1/2 · W-1,说明利用该新型弛豫 铁电单晶制作的红外探测器具有广阔的应用前景。
热释电红外探测器 弛豫铁电单晶 比探测率 pyroelectric infrared detector relaxation ferroelectric crystal PMNT PMNT detectivity 
红外
2013, 34(1): 12
作者单位
摘要
1 School of Material Sciences and Engineering, Seoul National University, Korea
2 浙江省嘉兴学院,浙江 嘉兴 314000
3 云南昆明物理研究,云南,昆明,650223
4 云南昆明物理研究所,云南 昆明 650223
5 中国科学院上海技术物理研究所,上海 200083
6 KangSchool of Material Sciences and Engineering, Seoul National University, Korea
测量了一批不同组分的铌酸钾锂晶体Raman光谱,发现晶体中位于C格位的Li离子浓度对晶体Raman光谱产生了强烈的影响:低Li含量晶体中[NbO6]7-八面体所对应的3个Raman特征光谱线没有发生峰分裂,在100~400cm-1范围出现的小峰与C格位Li离子浓度相关;当晶体中Li离子浓度增加时,与v5所对应的Raman峰在散射几何为X(ZY)Z对应的光谱中加宽,v2振动模式在两种散射几何中均出现分裂峰,并在100~400cm-1范围出现小峰数量增多;当Li离子浓度接近晶体化学组分时,微扰进一步加强,v5所对应峰分裂成3个峰,v1和v2振动模式发生部分分裂,在100~400cm-1范围小峰更为突出.
铁电晶体 铌酸钾锂 振动模式 红外Raman振动光谱 ferroelectric crystal potassium lithium niobate vibration mode infrared Raman vibration spectra 
红外与毫米波学报
2005, 24(5): 331

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