Author Affiliations
Abstract
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
Indoor organic and perovskite photovoltaics (PVs) have been attracting great interest in recent years. The theoretical limit of indoor PVs has been calculated based on the detailed balance method developed by Shockley–Queisser. However, realistic losses of the organic and perovskite PVs under indoor illumination are to be understood for further efficiency improvement. In this work, the efficiency limit of indoor PVs is calculated to 55.33% under indoor illumination (2700 K, 1000 lux) when the bandgap (Eg) of the semiconductor is 1.77 eV. The efficiency limit was obtained on the basis of assuming 100% photovoltaic external quantum efficiency (EQEPV) when EEg, there was no nonradiative recombination, and there were no resistance losses. In reality, the maximum EQEPV reported in the literature is 0.80–0.90. The proportion of radiative recombination in realistic devices is only 10-5–10-2, which causes the open-circuit voltage loss (ΔVloss) of 0.12–0.3 V. The fill factor (FF) of the indoor PVs is sensitive to the shunt resistance (Rsh). The realistic losses of EQEPV, nonradiative recombination, and resistance cause the large efficiency gap between the realistic values (excellent perovskite indoor PV, 32.4%; superior organic indoor PV, 30.2%) and the theoretical limit of 55.33%. In reality, it is feasible to reach the efficiency of 47.4% at 1.77 eV for organic and perovskite photovoltaics under indoor light (1000 lux, 2700 K) with VOC = 1.299 V, JSC = 125.33 µA/cm2, and FF = 0.903 when EQEPV = 0.9, EQEEL = 10-1, Rs = 0.5 Ω cm2, and Rsh = 104 kΩ cm2.
theoretical efficiency limit realistic efficiency losses organic photovoltaics perovskite photovoltaics indoor photovoltaics 
Chinese Optics Letters
2023, 21(12): 120031
毕宴钢 1,2易方顺 1,2冯晶 1,2,*
作者单位
摘要
1 集成光电子学国家重点实验室吉林大学实验区, 吉林 长春 130012
2 吉林大学电子科学与工程学院, 吉林 长春 130012
在有机电致发光器件(OLEDs)中,由于存在多种光子束缚模式,其光提取效率很低。在有机太阳能电池(OPVs)中,有机材料的载流子迁移率较低,需要控制有源层厚度,导致光吸收不足,降低光电转换效率。利用金属等离子体微纳结构调控有机光电器件中的光场分布,是提高器件效率的有效方法之一。对基于金属等离子体微纳结构调控有机光电器件光场分布的最新研究进展进行总结,并详细讨论利用等离子体金属结构提高OLEDs的光提取效率和OPVs的光吸收效率的机理和方法。
表面光学 表面等离子体 光场调控 有机电致发光器件 有机太阳能电池 
激光与光电子学进展
2019, 56(20): 202406
作者单位
摘要
1 上海大学机电工程与自动化学院新型显示技术及应用集成教育部重点实验室, 上海 200072
2 山西大同大学炭材料研究所,山西 大同 037009
采用溶液旋涂法在铟锡氧化物(ITO)电极上制备氧化石墨烯(GO)薄膜作为有机太阳能电池(OPVs)的空穴传输层,通过调控旋涂转速优化了氧化石墨烯薄膜的厚度并研究了膜厚对于器件性能的影响规律。在此基础上,通过紫外臭氧(UVO)处理和热处理等方法进一步提升电池器件的性能。结果表明:在紫外臭氧处理和热处理温度为250 ℃时,所得电池器件的效率最优,达到3.16%,接近于使用经典聚(3,4-乙撑二氧噻吩):聚苯乙烯磺酸(PEDOT:PSS)材料的电池器件水平。这一结果表明具有低成本、可溶液加工以及优异的光透过性等特点的氧化石墨烯会成为一种未来非常有前景的有机太阳能电池的空穴传输层材料。
材料 氧化石墨烯 有机太阳能电池 空穴传输层 溶液加工 
光学学报
2017, 37(4): 0416001
作者单位
摘要
1 Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China
2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory of Clean Energy, Dalian 116023, China
4 7-dithien-2-yl-2 1 3-benzothiadiazole (DTBT) conjugated polymers low-bandgap organic photovoltaics 
Frontiers of Optoelectronics
2013, 6(4): 418

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