Frontiers of Optoelectronics, 2013, 6 (4): 373, 网络出版: 2014-03-03  

Recent developments in sensitizers for mesoporous sensitized solar cells

Recent developments in sensitizers for mesoporous sensitized solar cells
作者单位
Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
摘要
Abstract
Sensitizers have proven to be extremely important in determining the performance of dye-sensitized solar cells (DSCs). The design and understanding of sensitizers, especially D-π-A structured porphyrins, has become a recent focus of DSC research. In this perspective article, advances in the conception and performance of various sensitizers including ruthenium complexes, organic dyes and porphyrins are reviewed with respect to their structure and charge transfer dynamics at the dyesensitized mesopours heterojunction interface. In particular, the discussion focuses on the trends that perovskite would be the most effective and most likely to be used in DSCs combining with innovative hole transporting materials.
参考文献

[1] O’Regan B, Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353(6346): 737-740

[2] Bach U, Lupo D, Comte P, Moser J E, Weissortel F, Salbeck J, Spreitzer H, Gratzel M. Solid-state dye-sensitized mesoporous TiO2 solar cells with high photon-to-electron conversion efficiencies. Nature, 1998, 395: 583-585

[3] Han L Y, Islam A, Chen H, Malapaka C, Chiranjeevi B, Zhang S F, Yang X D, Yanagida M. High-efficiency -sensitized solar cell with a novel co-adsorbent. Energy & Environmental Sciences, 2012, 5(3): 6057-6060

[4] Kohle O, Gratzel M, Meyer A F, Meyer T B. The photovoltaic stability of, bis(isothiocyanato)rlutheniurn(II)-bis-2, 2′bipyridine-4, 4′-dicarboxylic acid and related sensitizers. Advanced Materials, 1997, 9(11): 904-906

[5] Wang P, Zakeeruddin S M, Moser J E, Nazeeruddin MK, Sekiguchi T, Gratzel M. A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nature Materials, 2003, 2: 402-407

[6] Wang P, Klein C, Humphry-Baker R, Zakeeruddin S M, Gratzel M. A high molar extinction coefficient sensitizer for stable dyesensitized solar cells. Journal of the American Chemical Society, 2005, 127(3): 808-809

[7] Kuang D, Klein C, Ito S, Moser J E, Humphrey-Baker R, Evans N, Duriaux F, Gratzel C, Zakeeruddin S M, Gratzel M. High-efficiency and stable mesoscopic dye-sensitized solar cells based on a high molar extinction coefficient ruthenium sensitizer and nonvolatile electrolyte. Advanced Materials, 2007, 19(8): 1133-1137

[8] Gao F F,Wang Y, Shi D, Zhang J, Wang M K, Jing X Y, Humphry-Baker R,Wang P, Zakeeruddin S M, Gratzel M. Enhance the optical absorptivity of nanocrystalline TiO2 film with high molar extinction coefficient ruthenium sensitizers for high performance dye-sensitized solar cells. Journal of the American Chemical Society, 2008, 130(32): 10720-10728

[9] Chen C Y, Wu S J, Wu C G, Chen J G, Ho K C. A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells. Angewandte Chemie International Edition, 2006, 45(35): 5822-5825

[10] Chen C Y, Wang M K, Li J Y, Pootrakulchote N, Alibabaei L, Ngoc-le C H, Decoppet J D, Tsai J H, Gratzel C, Wu C G, Zakeeruddin S M, Gratzel M. Highly efficient light-harvesting ruthenium sensitizer for thin-film dye-sensitized solar cells. ACS Nano, 2009, 3(10): 3103-3109

[11] Cao Y M, Bai Y, Yu Q J, Cheng Y M, Liu S, Shi D, Gao F F, Wang P. Dye-sensitized solar cells with a high absorptivity ruthenium sensitizer featuring a 2-(hexylthio)thiophene conjugated bipyridine. Journal of Physical Chemistry C, 2009, 113(15): 6290-6297

[12] Karthikeyan C S, Peter K, Wietasch H, Thelakkat M. Highly efficient solid-state dye-sensitized TiO2 solar cells via control of retardation of recombination using novel donor-antenna dyes. Solar Energy Materials and Solar Cells, 2007, 91(5): 432-439

[13] Yum J H, Jung I, Baik C, Ko J J, NazeeruddinMK, Gratzel M. High efficient donor-acceptor ruthenium complex for dye -sensitized solar cell applications. Energy & Environmental Sciences, 2009, 2(1): 100-102

[14] Yum J H, Moon S J, Karthikeyan C S, Wietasch H, Thelakkat M, Zakeeruddin S M, Nazeeruddin M K, Gratzel M. Heteroleptic ruthenium complex containing substituted triphenylamine holetransport unit as sensitizer for stable dye-sensitized solar cell. Nano Energy, 2012, 1(1): 6-12

[15] Bessho T, Yoneda E, Yum J H, Guglielmi M, Tavernelli I, Imai H, Rothlisberger U, Nazeeruddin M K, Gratzel M. New paradigm in molecular engineering of sensitizers for solar cell applications. Journal of the American Chemical Society, 2009, 131(16): 5930-5934

[16] Wang S W,Wu K L, Ghadiri E, LobelloMG, Ho S T, Chi Y, Moser J E, Angelis F D, Gratzel M, Nazeeruddin M K. Engineering of thiocyanate-free Ru(II) sensitizers for high efficiency dye-sensitized solar cells. Chemical Science, 2013, 4(6): 2423-2433

[17] Yeh H H, Ho S T, Chi Y, Clifford J N, Palomares E, Liun S H, Chou P T. Ru(II) sensitizers bearing dianionic biazolate ancillaries: ligand synergy for high performance dye sensitized solar cells. Journal of Materials Chemistry A, 2013, 1: 7681-7689

[18] Bessho T, Zakeeruddin S M, Yeh C Y, Diau E W G, Gratzel M. Highly efficient mesoscopic dye-sensitized solar cells based on donor-acceptor-substituted porphyrins. Angewandte Chemie International Edition, 2010, 49(37): 6646-6649

[19] Wang C L, Chang Y C, Lan C M, Lo C F, Diau E W G, Lin C Y. Enhanced light harvesting with π-conjugated cyclic aromatic hydrocarbons for porphyrin-sensitized solar cells. Energy & Environmental Sciences, 2011, 4(5): 1788-1795

[20] Wang C L, Lan C M, Hong S H, Wang Y F, Pan T Y, Chang C W, Kuo H H, Kuo M Y, Diau E W G, Lin C Y. Enveloping porphyrins for efficient dye-sensitized solar cells. Energy & Environmental Sciences, 2012, 5(5): 6933-6940

[21] Chang Y C,Wang C L, Pan T Y, Hong S H, Lan C M, Kuo H H, Lo C F, Hsu H Y, Lin C Y, Diau E W G. A strategy to design highly efficient porphyrin sensitizers for dye-sensitized solar cells. Chemical Communications (Cambridge), 2011, 47(31): 8910-8912

[22] Yella A, Lee H W, Tsao H N, Yi C, Chandiran A K, Nazeeruddin M K, Diau E W G, Yeh C Y, Zakeeruddin S M, Gratzel M. Porphyrinsensitized solar cells with cobalt (II/III)-based redox electrolyte exceed 12 percent efficiency. Science, 2011, 334(6056): 629-634

[23] He J X, Guo F L, Li X,WuWJ, Yang J B, Hua J L. New bithiazolebased sensitizers for efficient and stable dye-sensitized solar cells. Chemistry, a European Journal (Weinheim an der Bergstrasse, Germany), 2012, 18(25): 7903-7915

[24] ZengWD, Cao Y M, Bai Y,Wang Y H, Shi Y S, Zhang M,Wang F F, Pan C Y, Wang P. Efficient dye-sensitized solar cells with an organic photosensitizer featuring orderly conjugated ethylenedioxythiophene and dithienosilole blocks. Chemistry of Materials, 2010, 22(5): 1915-1925

[25] Choi H, Raabe I, Kim D, Teocoli F, Kim C, Song K, Yum J H, Ko J, Nazeeruddin M K, Gratzel M. High molar extinction coefficient organic sensitizers for efficient dye-sensitized solar cells. Chemistry, a European Journal (Weinheim an der Bergstrasse, Germany), 2010, 16(4): 1193-1201

[26] Ito S, Miura H, Uchida S, Takata M, Sumioka K, Liska P, Comte P, Pechy P, Gratzel M. High-conversion-efficiency organic dyesensitized solar cells with a novel indoline dye. Chemical Communications (Cambridge), 2008, 41: 5194-5196

[27] Wu Y Z, Marszalek M, Zakeeruddin S M, Zhang Q, Tian H, Gratzel M, Zhu W. High-conversion-efficiency organic dye-sensitized solar cells: molecular engineering on D-A-π-A featured organic indoline dyes. Energy & Environmental Sciences, 2012, 5(8): 8261-8272

[28] Zhang M, Liu J G, Wang Y H, Zhou D F, Wang P. Redox couple related influences of π-conjugation extension in organic dyesensitized mesoscopic solar cells. Chemical Science, 2011, 2(7): 1401-1406

[29] Cao Y M, Cai N, Wang Y L, Li R Z, Yuan Y, Wang P. Modulating the assembly of organic dye molecules on titania nanocrystals via alkyl chain elongation for efficient mesoscopic cobalt solar cells. Physical Chemistry Chemical Physics, 2012, 14(23): 8282-8286

[30] Kim H S, Lee C R, Im J H, Lee K B, Moehl T, Marchioro A, Moon S J, Humphry-Baker R, Yum J H, Moser J E, Gratzel M, Park N G. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Scientific Reports, 2012, 2: 591

[31] Li J Y, Chen C Y, Chen J G, Tan C J, Lee K M, Wu S J, Tung Y L, Tsai H H, Ho K C,Wu C G. Heteroleptic ruthenium antenna-dye for high-voltage dye-sensitized solar cells. Journal of Materials Chemistry, 2010, 20(34): 7158-7164

[32] Chen C Y,Wu S J, Li J Y,Wu C G, Chen J G, Ho K C. A new route to enhance the light-harvesting capability of ruthenium complexes for dye-sensitized solar cells. Advanced Materials, 2007, 19(22): 3888-3891

[33] Chen C Y, Pootrakulchote N, Wu S J, Wang M K, Li J Y, Tsai J H, Wu C G, Zakeeruddin S M, Gratzel M. New ruthenium sensitizer with carbazole antennas for efficient and stable thin-film dyesensitized solar cells. Journal of Physical Chemistry C, 2009, 113(48): 20752-20757

[34] Zhu S S, Kingsborough R P, Swager T M. Conducting redox polymers: investigations of polythiophene-Ru(bpy)3n+ hybrid materials. Journal of Materials Chemistry, 1999, 9(9): 2123-2131

[35] Nazeeruddin M K, Baranoff E, Gratzel M. Dye-sensitized solar cells: a brief overview. Solar Energy, 2011, 85(6): 1172-1178

[36] Wadman S H, Kroon J M, Bakker K, Lutz M, Spek A L, Klin G P M, Koten G. Cyclometalated ruthenium complexes for sensitizing nanocrystalline TiO2 solar cells. Chemical Communications (Cambridge), 2007, 19(19): 1907-1909

[37] Wu K L, Ku W P, Wang S W, Yella A, Chi Y, Liu S H, Chou P T, Nazeeruddin M K, Gratzel M. Thiocyanate-free Ru(II) sensitizers with a 4,4′-dicarboxyvinyl-2,2′-bipyridine anchor for dye-sensitized solar cells. Advanced Functional Materials, 2013, 23(18): 2285-2294

[38] Wu K L, Ku W P, Clifford J N, Palomares E, Ho S T, Chi Y, Liu S H, Chou P T, Nazeeruddin M K, Gratzel M. Harnessing the opencircuit voltage via a new series of Ru(II) sensitizers bearing (iso-) quinolinyl pyrazolate ancillarie. Energy & Environmental Sciences, 2013, 6: 859-870

[39] Bomben P G, Robson K C D, Koivisto B D, Berlinguette C P. Cyclometalated ruthenium chromophores for the dye-sensitized solar cell. Coordination Chemistry Reviews, 2012, 256(15-16): 1438-1450

[40] Hsu C W, Ho S T, Wu K L, Chi Y, Liu S H, Chou P T.Ru(II) sensitizers with a tridentate heterocyclic cyclometalate for dyesensitized solar cells. Energy& Environmental Sciences, 2012, 5(6): 7549-7554

[41] Wu K L, Li C H, Chi Y, Clifford J N, Cabau L, Palomares E, Cheng Y M, Pan H A, Chou P T. Dye molecular structure device opencircuit voltage correlation in Ru(II) sensitizers with heteroleptic tridentate chelates for dye-sensitized solar cells. Journal of the American Chemical Society, 2012, 134(17): 7488-7496

[42] Imahori H, Umeyama T, Ito S. Large pi-aromatic molecules as potential sensitizers for highly efficient dye-sensitized solar cells. Accounts of Chemical Research, 2009, 42(11): 1809-1818

[43] Panda M K, Ladomenou K, Coutsolelos A G. Porphyrins in bioinspired transformations: light-harvesting to solar cell. Coordination Chemistry Reviews, 2012, 256(21-22): 2601-2627

[44] CampbellWM, Burrell A K, Officer D L, Jolley K W. Porphyrins as light harvesters in the dye-sensitised TiO2 solar cell. Coordination Chemistry Reviews, 2004, 248(13-14): 1363-1379

[45] He H, Gurung A, Si L P. 8-hydroxylquinoline as a strong alternative anchoring group for porphyrin-sensitized solar cells. Chemical Communications (Cambridge), 2012, 48(47): 5910-5912

[46] Lammi R K, Wagner R W, Ambroise A, Diers J R, Bocian D F, Holten D, Lindsey J S. Mechanisms of excited-state energy-transfer gating in linear versus branched multiporphyrin arrays. Journal of Physical Chemistry B, 2001, 105(22): 5341-5352

[47] Lee C W, Lu H P, Lan C M, Huang Y L, Liang Y R, YenWN, Liu Y C, Lin Y S, Diau E W G, Yeh C Y. Novel zinc porphyrin sensitizers for dye-sensitized solar cells: synthesis and spectral, electrochemical, and photovoltaic properties. Chemistry, a European Journal (Weinheim an der Bergstrasse, Germany), 2009, 15(6): 1403-1412

[48] Lu H P, Tsai C Y, Yen W N, Hsieh C P, Lee C W, Yeh C Y, Diau E W G. Control of dye aggregation and electron injection for highly efficient porphyrin sensitizers adsorbed on semiconductor films with varying ratios of coadsorbate. Journal of Physical Chemistry C, 2009, 113(49): 20990-20997

[49] Li L L, Diau E W G. Porphyrin-sensitized solar cells. Chemical Society Reviews, 2013, 42(1): 291-304

[50] Tanaka M, Hayashi S, Eu S, Umeyama T, Matano Y, Imahori H. Novel unsymmetrically π-elongated porphyrin for dye-sensitized TiO2 cells. Chemical Communications (Cambridge), 2007, 20: 2069-2071

[51] Liu Y Z, Lin H, Dy J T, Tamaki K, Nakazaki J, Nakayama D, Uchida S, Kubo T, Segawa H. N-fused carbazole-zinc porphyrin-free-base porphyrin triad for efficient near-IR dye-sensitized solar cells. Chemical Communications (Cambridge), 2011, 47(13): 4010-4012

[52] Mai C L, HuangWK, Lu H P, Lee C W, Chiu C L, Liang Y R, Diau E W G, Yeh C Y. Synthesis and characterization of diporphyrin sensitizers for dye-sensitized solar cells. Chemical Communications (Cambridge), 2010, 46(5): 809-811

[53] Mozer A J, Wagner P, Officer D L, Wallace G G, Campbell W M, Miyashita M, Sunahara K, Mori S. The origin of open circuit voltage of porphyrin-sensitised TiO2 solar cells. Chemical Communications (Cambridge), 2008, 39: 4741-4743

[54] Tsao H N, Yi C Y, Moehl T, Yum J H, Zakeeruddin S M, Nazeeruddin M K, Gratzel M. Cyclopentadithiophene bridged donor-acceptor dyes achieve high power conversion efficiencies in dye-sensitized solar cells based on the tris-cobalt bipyridine redox couple. ChemSusChem, 2011, 4(5): 591-594

[55] Lu J F, Xu X B, Li Z H, Cao K, Cui J, Zhang Y B, Shen Y, Li Y, Zhu J, Dai S Y, Chen W, Cheng Y B,Wang MK. Zinc porphyrins with a pyridine-ring-anchoring group for dye-sensitized solar cells. Chemistry, an Asian Journal, 2013, 8(5): 956-962

[56] Mishra A, Fischer M K R, Bruerle P. Metallfreie organische farbstoffe für farbstoffsensibilisierte solarzellen-von struktureigenschafts-beziehungen zu designregeln. Angewandte Chemie, 2009, 121(14): 2510-2536

[57] Wang X F, Tamiaki H. based molecules for Cyclic tetrapyrroledyesensitized solar cells. Energy& Environmental Sciences, 2010, 3(1): 94-106

[58] Ning Z J, Fu Y, Tian H. Improvement of dye -sensitized solar cells : what we know and what we need to know. Energy & Environmental Sciences, 2010, 3(9): 1170-1181

[59] Fang Z, Eshbaugh A A, Schanze K S. Low-bandgap donor-acceptor conjugated polymer sensitizers for dye-sensitized solar cells. Journal of the American Chemical Society, 2011, 133(9): 3063-3069

[60] He J X, Wu W J, Hua J L, Jiang Y H, Qu S Y, Li J, Long Y T, Tian H. Bithiazole-bridged dyes for dye-sensitized solar cells with high open circuit voltage performance. Journal of Materials Chemistry, 2011, 21(16): 6054-6062

[61] Xu W, Peng B, Chen J, Liang M, Cai F S. New triphenylaminebased dyes for dye-sensitized solar cells. Journal of Physical Chemistry C, 2008, 112(3): 874-880

[62] Zhang G L, Bai Y, Li R Z, Shi D, Wenger S, Zakeeruddin S M, Gratzel M,Wang P. Employ a bisthienothiophene linker to construct an organic chromophore for efficient and stable dye-sensitized solar cells. Energy & Environmental Sciences, 2009, 2(1): 92-95

[63] Liu J Y, Zhou D F, Xu M F, Jing X Y, Wang P. The structure-property relationship of organic dyes in mesoscopic titania solar cells : only one double-bond difference. Energy & Environmental Sciences, 2011, 4(9): 3545-3551

[64] Zhu X Z, Tsuji H, Yella A, Chauvin A S, Gratzel M, Nakamura E. New sensitizers for dye-sensitized solar cells featuring a carbonbridged phenylenevinylene. Chemical Communications (Cambridge), 2013, 49(6): 582-584

[65] Choi H, Baik C, Kang S O, Ko J, Kang M S, Nazeeruddin M K, Gratzel M. Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells. Angewandte Chemie International Edition, 2008, 47(2): 327-330

[66] Lim K, Kim C, Song J, Yu T, Lim W, Song K, Wang P, Zu N, Ko J. Enhancing the performance of organic dye-sensitized solar cells via a slight structure modification. Journal of Physical Chemistry C, 2011, 115(45): 22640-22646

[67] Kim S, Lee J K, Kang S O, Ko J, Yum J H, Frantacci S, Angelis F D, Censo D D, Nazeeruddin MK, Gratzel M. Molecular engineering of organic sensitizers for solar cell applications. Journal of the American Chemical Society, 2006, 128(51): 16701-16707

[68] ZhuWH,Wu Y Z,Wang S T, LiWQ, Li X, Chen J,Wang Z S, Tian H. Organic D-A-π-A solar cell sensitizers with improved stability and spectral response. Advanced Functional Materials, 2011, 21(4): 756-763

[69] Wu Y Z, Zhang X, Li W Q, Wang Z S, Tian H, Zhu W H. Hexylthiophene-featured D-A-π-A structural indoline chromophores for coadsorbent-free and panchromatic dye-sensitized solar cells. Advanced Energy Materials, 2012, 2(1): 149-156

[70] Liang M, Chen J. Arylamine organic dyes for dye-sensitized solar cells. Chemical Society Reviews, 2013, 42(8): 3453-3488

[71] Boschloo G, Hagfeldt A. Characteristics of the iodide/triiodide redox mediator in dye-sensitized solar cells. Accounts of Chemical Research, 2009, 42(11): 1819-1826

[72] O’Regan B C, Lopez-Duarte I, Martínez-Díaz M V, Forneli A, Albero J, Morandeira A, Palomares E, Torres T, Durrant J R. Catalysis of recombination and its limitation on open circuit voltage for dye sensitized photovoltaic cells using phthalocyanine dyes. Journal of the American Chemical Society, 2008, 130(10): 2906-2907

[73] Hagfeldt A, Gratzel M. Light-induced redox reactions in nanocrystalline systems. Chemical Reviews, 1995, 95(1): 49-68

[74] Mitzi D B. Organic-inorganic perovskites containing trivalent metal halide layers: the templating influence of the organic cation layer. Inorganic Chemistry, 2000, 39(26): 6107-6113

[75] Gratzel C, Zakeeruddin S M. Recent trends in mesoscopic solar cells based on molecular and nanopigment light harvesters. Materials Today, 2013, 6(1-2): 11-18

[76] Poglitsch A, Weber D. Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy. Journal of Chemical Physics, 1987, 87(11): 6373-6378

[77] Mitzi D B, Field C A, Schlesinger Z, Laibowitz R B. Transport, optical, and magnetic properties of the conducting halide perovskite CH3NH3SnI3. Journal of Solid State Chemistry, 1995, 114(1): 159-163

[78] Yamada K, Kuranaga Y, Ueda K, Goto S, Okuda T, Furukawa Y. Phase transition and electric conductivity of ASnCl3 (A = Cs and CH3NH3). Bulletin of the Chemical Society of Japan, 1998, 71(1): 127-134

[79] Mitzi D B, Feild C A, Harrison W T A, Guloy A M. Conducting tin halides with a layered organic-based perovskite structure. Nature, 1994, 369(6480): 467-469

[80] Billing D G, Llemmerer A. Synthesis and crystal structures of inorganic-organic hybrids incorporating an aromatic amine with a chiral functional group. CrystEngComm, 2006, 8(9): 686-695

[81] Zhang S J, Lanty G, Lauret J S, Deleporte E, Audebert P, Galmiche L. Synthesis and optical properties of novel organic-inorganic hybrid nanolayer structure semiconductors. Acta Materialia, 2009, 57(11): 3301-3309

[82] Kojima A, Teshima K, Shirai Y, Miyasaka T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. Journal of the American Chemical Society, 2009, 131(17): 6050-6051

[83] Im J H, Lee C R, Lee J W, Park S W, Park N G. 6.5% efficient perovskite quantum-dot-sensitized solar cell. Nanoscale, 2011, 3(10): 4088-4093

[84] Chung I, Lee B, He J Q, Chang R P H, Kanatzidis M G. All-solidstate dye-sensitized solar cells with high efficiency. Nature, 2012, 485(7399): 486-489

[85] Lee M M, Teuscher J, Miyasaka T, Murakami T N, Snaith H J. Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science, 2012, 338(6107): 643-647

[86] Etgar L, Gao P, Xue Z S, Peng Q, Chandiran A K, Liu B, Nazeeruddin M K, Gratzel M. Mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cells. Journal of the American Chemical Society, 2012, 134(42): 17396-17399

Kun CAO, Mingkui WANG. Recent developments in sensitizers for mesoporous sensitized solar cells[J]. Frontiers of Optoelectronics, 2013, 6(4): 373. Kun CAO, Mingkui WANG. Recent developments in sensitizers for mesoporous sensitized solar cells[J]. Frontiers of Optoelectronics, 2013, 6(4): 373.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!