Author Affiliations
Abstract
Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 2018002 Physical Chemistry of Luminescent Materials, University of Lyon, UMR CNRS 5620, Villeurbanne 69622, France
Yb-Er codoped Na2O-Al2O3-P2O5-xSiO2 glasses containing 0-20 mol% SiO2 were prepared successfully. The addition of SiO2 to the phosphate glass not only lengthens the bond between P^{5+} and non-bridging oxygen but also reduces the number of P=O bond. In contrast with silicate glass in which there is only four-fold coordinated Si^{4+}, most probably there coexist [SiO4 tetrahedron and [SiO6] octahedron in our glasses. Within the range of 0-20 mol% SiO2 addition, the stimulated emission cross-section of Er^{3+} ion only decreases no more than 10%. The Judd-Ofelt intensity parameters of Er^{3+}, \Omega_{2} does not change greatly, but \Omega_{4} and \Omega_{6} decrease obviously with increasing SiO2 addition, because the bond between Er^{3+} and O^{2-} is more strongly covalently bonded.
镱铒共掺磷酸盐玻璃 氧化硅 拉曼光谱 Judd-Ofelt参数 160.2750 Glass and other amorphous materials 160.5690 Rare-earth-doped materials 300.6450 Spectroscopy, Raman 300.6170 Spectra 
Chinese Optics Letters
2009, 7(1): 0156
作者单位
摘要
中国科学院上海光学精密机械研究所, 上海 201800
研究了氙灯抽运脉宽、输出耦合镜的反射率、铒玻璃工作温度以及工作重复频率对铬镱铒共掺磷酸盐玻璃激光输出能量的影响。结果表明, 对于输出能量, 抽运脉宽为2.3 ms(10%最大幅度间)时较好; 综合考虑激光阈值和斜率效率, 输出耦合镜的反射率为85%时较好。此外, 如同大多数激光介质那样, 铬镱铒共掺磷酸盐玻璃的激光输出能量随铒玻璃工作温度的升高和工作重复频率的增加而降低。
材料 激光性质 镱铒共掺磷酸盐玻璃 输出能量 
中国激光
2007, 34(2): 272

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