应用激光, 2023, 43 (6): 0078, 网络出版: 2024-02-02  

10网终首发类金刚石网络结构石墨/环氧树脂导电复合材料的制备及性能研究

Research on the Preparation and Performance of Diamond-Like Network Structure Graphite/Epoxy Resin Conductive Composites
作者单位
1 三峡大学石墨增材制造技术与装备湖北省工程研究中心,湖北 宜昌 443002
2 三峡大学机械与动力学院,湖北 宜昌 443002
摘要
传统成型工艺制备的导电复合材料内部导电通路分布不可控,且难以实现复合材料的电学与力学性能的匹配。利用选择性激光烧结技术快速制备了类金刚石结构石墨骨架素坯,并经过二次固化、真空压力浸渍酚醛树脂溶液以及高温碳化等后处理工艺改善石墨骨架电学以及力学性能,并将环氧树脂与之“复合”,制备了石墨/环氧树脂复合导电材料。通过正交试验,研究了石墨骨架结构特征参数对导电复合材料的电导率和抗弯强度的影响。研究结果表明:键半径R为决定复合材料电导率的主要因素,但对于其抗弯强度为较次要因素;键长L对复合材料的电导率和抗弯强度皆为较主要因素;当键长为6 mm、键半径为1.4 mm、键角为120°时,可获得力学性能和导电性能相协同的新型导电复合材料。
Abstract
The internal conductive pathway distribution of conductive composites prepared for traditional molding processes is uncontrollable, and it is difficult to match the electrical and mechanical properties of composites. In this paper, the selective laser sintering technology was used to rapidly prepare the diamond-like graphite skeleton blank, and the electrical and mechanical properties of the graphite skeleton were improved by secondary curing, vacuum pressure impregnation of phenolic resin solution and high temperature carbonization. The epoxy resin was "composited" with it, and graphite-epoxy composite conductive materials were prepared. Through orthogonal experiments, the effects of structural parameters of graphite skeleton on the conductivity and bending strength of conductive composites were studied. Results show that the bond radius R is the main factor determining the conductivity of the composite material, but it is a secondary factor for its bending strength. Bond length L is the main factor for the conductivity and bending strength of composite materials. When the bond length is 6 mm, the bond radius is 1.4 mm, and the bond angles is 120°, a new type of conductive composite material with mechanical properties and conductivity synergistic properties is obtained.

叶喜葱, 潘文, 杨鹏, 陈俊超, 吴海华. 10网终首发类金刚石网络结构石墨/环氧树脂导电复合材料的制备及性能研究[J]. 应用激光, 2023, 43(6): 0078. Ye Xicong, Pan Wen, Yang Peng, Chen Junchao, Wu Haihua. Research on the Preparation and Performance of Diamond-Like Network Structure Graphite/Epoxy Resin Conductive Composites[J]. APPLIED LASER, 2023, 43(6): 0078.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!