硅酸盐通报, 2023, 42 (1): 287, 网络出版: 2023-03-16
钨添加对Si3N4陶瓷力学性能的影响及强韧化机理研究
Effect and Toughening Mechanism of Tungsten Addition on Mechanical Properties of Si3N4 Ceramics
Si3N4陶瓷 钨 气压烧结 微观结构 致密性 弯曲强度 断裂韧性 Si3N4 ceramics tungsten pneumatic sintering microstructure compactness bending strength fracture toughness
摘要
为了增韧Si3N4基陶瓷材料, 以钨(W)作为第二相材料, Y2O3-Al2O3作为烧结助剂, 采用气压烧结法制备了W/Si3N4复合陶瓷材料。研究了W含量对W/Si3N4复合陶瓷材料致密性、力学性能以及结构的影响。结果表明: 在W含量小于5%(质量分数)时, 样品致密度均达97%以上; 在W含量为5%(质量分数)时, 获得的W/Si3N4复合陶瓷材料综合性能最佳, 弯曲强度、硬度和断裂韧性分别为(670.28±40.00) MPa、(16.42±0.22) GPa和(8.04±0.16) MPa·m1/2, 相比于未添加金属W的Si3N4陶瓷材料分别提高了38.08%、13.08%和44.34%; 通过分析W/Si3N4复合陶瓷材料样品抛光面和压痕裂纹的微观结构, 发现W的引入能促使裂纹在扩展路径上更易发生偏转、分叉等增韧机制, 消耗裂纹扩展能量, 从而改善Si3N4陶瓷的断裂韧性。
Abstract
To toughen Si3N4-based ceramic materials, W/Si3N4 composite ceramic materials were prepared in this article by the pneumatic sintering method with tungsten (W) as the second phase material and Y2O3-Al2O3 as sintering additive. Then the effect of W content on the compactness, mechanical properties, and microstructure of W/Si3N4 composite ceramic materials was investigated. The results indicate that the densities of samples all reach more than 97% when the W content is less than 5% (mass fraction). The most outstanding overall performance of W/Si3N4 composite ceramic materials is obtained when W content is 5% (mass fraction), and the bending strength, hardness, and fracture toughness are (670.28±40.00) MPa, (16.42±0.22) GPa, and (8.04±0.16) MPa·m1/2, respectively, which are 3808%, 13.08%, and 44.34% higher than Si3N4 ceramic materials without the addition of metal W. By analyzing the microstructure of the polished surface and indentation cracks of W/Si3N4 composite ceramic material samples, it is found that the introduction of W can trigger toughening mechanisms such as deflection and bifurcation of cracks in the propagation path, and consume crack expansion energy, thus improving the fracture toughness of Si3N4 ceramics.
杨超, 周存龙, 王强, 杨元清, 郝瑞杰. 钨添加对Si3N4陶瓷力学性能的影响及强韧化机理研究[J]. 硅酸盐通报, 2023, 42(1): 287. YANG Chao, ZHOU Cunlong, WANG Qiang, YANG Yuanqing, HAO Ruijie. Effect and Toughening Mechanism of Tungsten Addition on Mechanical Properties of Si3N4 Ceramics[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(1): 287.