中国激光, 2024, 51 (3): 0307302, 网络出版: 2024-01-24  

生物材料消光特性研究进展

Progress on Extinction Properties of Biomaterials
顾有林 1,2,3,*张熙 1,3胡以华 1,2,3孟凡昊 1,3陈国龙 1,3丁婉莹 1,3王思雨 1,3
作者单位
1 国防科技大学脉冲功率激光技术国家重点实验室,安徽 合肥 230037
2 先进激光技术安徽省实验室,安徽 合肥 230037
3 国防科技大学,安徽 合肥 230037
摘要
生物材料作为一种有别于传统无机消光材料的新型烟幕介质,悬浮于空气中,以烟幕的形式存在,通过对光的吸收和散射作用改变光波的传输特性。本文根据生物材料的复折射率特点,介绍了生物材料的吸收和散射特性,概括了生物材料单粒子、单分散凝聚粒子和多分散凝聚粒子的消光特性的表征方式,分析了影响生物材料消光特性的因素,总结了生物材料消光性能的测试方法。最后,本文提出了生物材料在复杂空间结构模拟精确化、消光特性影响因素分析多元性、消光特性测试标准化方面的发展趋势,以期为新型消光材料的制备和改进等提供有益参考。
Abstract
Significance

In recent years, laser and infrared detection technology has been rapidly developed. The material preparation, generation method, extinction performance test, and effect evaluation of multi-band smoke screens have garnered widespread attention. Traditional inorganic extinction materials, such as metal powder, red phosphorus, and expanded graphite, often possess drawbacks such as a narrow extinction band, high costs, combustibility, difficulty in degradation, a single release method, and environmental harm. Consequently, environmentally friendly extinction materials characterized by a broad extinction band, long duration, low preparation cost, pollution-free, and non-combustibility emerge as research hotspots both domestically and internationally.

Artificially controlled biomaterials, such as spores or hyphae, represent a new type of smoke screens medium, distinct from traditional inorganic extinction materials. Once released into the air, these biomaterials form smoke screens, altering light transmission properties through absorption and scattering. Hence, biomaterials can diminish the detection capabilities of visible, laser, and infrared detection systems and equipment, making them suitable for the photoelectric protection of critical targets or facilities. Biomaterials aggregated particles systems formed from tiny biological particles due to static electricity, collision, or adhesion, possess complex spatial structures and random orientations.

There is a significant progress in researching the extinction properties of biomaterials. Biomaterials can be prepared with attributes such as controllable morphology, cost-efficiency, ease of batch preparation, high impedance, environmental friendliness, and non-toxicity. Researchers have constructed structure models of spherical particles, typical non-spherical particles, monodisperse aggregated particles, and polydisperse aggregated particles and have analyzed their static extinction properties. Additionally, the dynamic extinction properties of biomaterials have been examined under varying wind speeds, surface roughnesses, and relative humidities. Regarding the differential extinction properties of viable and dead biomaterials, the activity ratio of biomaterials can be qualitatively determined. Although many advances have occurred, challenges persist in the simulation, testing, and enhancement of biomaterials' extinction characteristics. Thus, outlining current research on the extinction characteristics of biomaterials becomes essential, paving the way for future developments in safer and more eco-friendly broadband smoke screen materials.

Progress

First, the extinction characteristics of biomaterials are introduced, with absorption and scattering attributes based on the characteristics of complex refractive index. The calculation flowchart for the extinction characteristics of biomaterials is presented (Fig. 5), and characterization methods for different biomaterial structures are summarized. These structures include spherical single particles, typical non-spherical single particles, monodisperse aggregated particles, and polydisperse aggregated particles. Although the extinction properties are primarily determined by the composition and structural parameters of biomaterials (as shown in Fig. 6 and Fig. 9), other influential factors are examined. These factors are represented by biomaterial activity (Fig. 10), wind speed (Fig. 12), ground roughness (Fig. 13), and relative humidity (Fig. 14). Subsequently, static and dynamic testing methods for biomaterials are listed. In the static methods, the scanning electron microscope (SEM) test (Fig. 15) and infrared spectroscopy test (Fig. 16) are featured, while in the dynamic methods, the smoke box test (Fig. 17) and field test (Fig. 19) are included. In conclusion, emerging trends such as precise simulations of intricate spatial structures, analyses of factors influencing extinction characteristics, and standardization of extinction characteristics testing are emphasized.

Conclusions and Prospects

In recent years, significant advancements have been observed in the study of extinction characteristics and test techniques of biomaterials. However, certain challenges persist that require attention in the forthcoming research, including the simulation of randomly oriented aggregation for biological particles, the multivariate analysis of dynamic extinction properties of biomaterials, and the standardization of extinction performance testing. Initially, given that biological particles generally possess irregular shapes and biological particle aggregations exhibit complex and variable structures, only a model accounting for the randomly oriented aggregation of these irregular particles can accurately represent the spatial structure of aggregated biological particles, ensuring precise calculations of the biomaterials' extinction properties. At this juncture, due to the absence of an established model for randomly oriented aggregation of irregular particles, simulations are restricted to particles with regular shapes. Furthermore, a comprehensive consideration of factors, such as wind speed, temperature, and atmospheric stability, becomes imperative, surpassing the simplicity of previous analyses affecting the extinction properties of biomaterials. Additionally, addressing issues of a low effectiveness-cost ratio and limited repeatability by standardizing the collection and analysis of experimental data emerges as a crucial research direction. Anticipated improvements for the near future include the development of a randomly oriented aggregation model for diverse irregular biological particles, enabling the study of extinction characteristics for non-spherical biological materials. There is also the need for accurate simulations and predictions of sedimentation diffusion of aggregated particles under varied meteorological conditions. This would involve the consideration of multiple influencing factors, the enhancement of specific organic groups performance and the integration of other material components to bolster biomaterial performance. Lastly, the establishment of clear evaluation tests and criteria for the extinction performance of biomaterials is crucial, ensuring experimental data are gathered and analyzed following a relatively consistent standard.

顾有林, 张熙, 胡以华, 孟凡昊, 陈国龙, 丁婉莹, 王思雨. 生物材料消光特性研究进展[J]. 中国激光, 2024, 51(3): 0307302. Youlin Gu, Xi Zhang, Yihua Hu, Fanhao Meng, Guolong Chen, Wanying Ding, Siyu Wang. Progress on Extinction Properties of Biomaterials[J]. Chinese Journal of Lasers, 2024, 51(3): 0307302.

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