发光学报, 2022, 43 (7): 1052, 网络出版: 2022-08-08
多激发光窗口下银纳米颗粒表面等离激元增强多光子量子剪裁发光
Multi-photon Near-infrared Quantum Cutting Enhancement By Surface Plasmon of Ag Nanoparticles Under Multi-excitation
多光子量子剪裁 表面等离激元 Er3+掺杂 Ag纳米颗粒 多激发光 multi-photon quantum cutting surface plasmons Er3+ doping Ag nanoparticles multi-excitation
摘要
通过高温固相法制备了NaBaPO4∶Er3+荧光材料。采用化学还原法制备银纳米颗粒(银球与银立方),并修饰到NaBaPO4∶Er3+荧光材料中形成复合材料。利用银纳米颗粒表面等离激元特性实现了多激发光窗口激发下NaBaPO4∶Er3+多光子近红外量子剪裁发光增强。实现了在377 nm与485 nm光激发下,银球纳米颗粒表面等离激元增强NaBaPO4∶Er3+四光子与三光子近红外发光;在519 nm光激发下,银立方纳米颗粒表面等离激元增强NaBaPO4∶Er3+三光子近红外发光。
Abstract
NaBaPO4∶Er3+ was synthesized by solid-state reaction. Ag nanoparticles(NPs)(including Ag ball and Ag cube) were synthesized by chemical reduction method. The surface plasmon resonance of Ag NPs was utilized to enhance the multi-photon near infrared(NIR) quantum cutting emission intensity under multi-excitation. The surface plasmon resonance of Ag ball NPs was utilized to enhance the NIR emission intensity of four-photon and three-photon under the excitation of 377 nm and 485 nm, respectively. The surface plasmon resonance of Ag cube NPs was utilized to enhance three-photon NIR emission intensity under the excitation of 377 nm.
洪锦泉, 郑标, 曾睿灵, 修亦心, 曾瑞雅, 林可鑫, 陈大钦. 多激发光窗口下银纳米颗粒表面等离激元增强多光子量子剪裁发光[J]. 发光学报, 2022, 43(7): 1052. Jin-quan HONG, Biao ZHENG, Rui-ling ZENG, Yi-xin XIU, Rui-ya ZENG, Ke-xin LIN, Da-qin CHEN. Multi-photon Near-infrared Quantum Cutting Enhancement By Surface Plasmon of Ag Nanoparticles Under Multi-excitation[J]. Chinese Journal of Luminescence, 2022, 43(7): 1052.