光学学报, 2006, 26 (2): 275, 网络出版: 2006-04-20   

新型高色纯度弱电流猝灭性蓝色有机发光器件

Novel Blue Organic Light Emitting Diode with Highly Saturated Color and Weak Current-Induced Quenching
作者单位
上海大学材料科学与工程学院, 上海 201800
摘要
以ADN为基质,分别以不同掺杂剂制备了四种蓝色有机发光器件,器件结构为:CuPc(12 nm)/NPB(40 nm)/AND∶Dopant(50 nm)/Alq(12 nm)/LiF(4 nm)/Al。掺杂剂有:BCzVB(amino-substituted distyrylarylene derivatives)、TBPe、BCzVBi和DSA-ph四种。研究了最佳掺杂浓度以及器件的亮度、电流密度、效率和色坐标等电学特性和光学特性。其中掺杂BCzVB制备了色纯度高、低电流猝灭性的蓝色有机发光器件,色坐标达到x=0.146,y=0.162,最大亮度为11600 cd/m2(15 V),电流效率为2.8 cd/A,流明效率为1.79 lm/W;以ADN为基质,分别以TBPe、BCzVBi和DSA-ph为掺杂剂,制备了另外三种对比器件。器件ADN∶TBPe色坐标为x=0.162,y=0.222(蓝绿光),效率随电流的增加而降低很快;器件ADN∶BczVBi有较好的色纯度(色坐标:x=0.164,y=0.146),但电流效率较低:2.03 cd/A,效率随电流的增加降低幅度也较快。器件ADN∶DSA-ph效率较高为8 cd/A,效率随电流增加变化幅度不大,但色纯度比较差(x=0.153,y=0.306),适合于做白色有机发光器件。
Abstract
Four blue organic light emitting diodes (OLED) based on anthracene derivatives( ADN) doped with different dopants have been prepared. The device structure is CuPc(12 nm)/NPB(40 nm)/ADN∶Dopant(50 nm)/Alq(12 nm)/LiF(4 nm)/Al. The four dopants are amino-substituted distyrylarylene derivatives(BCzVB), tetra-butylperylene (TBPe), BCzVBi and DSA-ph. The optium concentration of dopants, the luminescence, current density, efficiency and color coordinates of these devices are explored. The device based on ADN doped with BCzVB shows high color purity and a weak current-induced fluorescence quenching. With CIE coordinates x=0.146,y=0.162, maximum luminance 11600 cd/m2 (15 V), current efficiency 2.8 cd/A, and luminous efficiency 1.79 lm/W. For comparison, the blue OLEDs based on ADN doped with TBPe BCzVBi and DSA-ph are also made. The first exhibits CIE coordinates x=0.162, y=0.222 (greenish blue) and a steep decline of efficiency with the increase of the current. The second gives a better purity (x=0.164,y=0.146) but lower current steeply declining with increase of current efficiency 2.03 cd/A. The last has high efficiency 8 cd/A and a weak current-induced fluorescence quenching, but poor CIE coordinates x=0.153,y=0.306, and it is suitable for white OLED.
参考文献

[1] . . Efficient electroluminescence of distyrylarylene with hole transporting ability[J]. J. Appl. Phys., 1995, 78(9): 5831-5833.

[2] . . Highly efficient blue electroluminescence from a distyrylarylene emittinglayer with a new dopant[J]. Appl. Phys. Lett., 1995, 67(26): 3853-3856.

[3] . Tang. Anthracene derivatives for stable blue-emitting organic electroluminescence devices[J]. Appl. Phys. Lett., 2002, 80(17): 3201-3203.

[4] Wu Youzhi, Zheng Xinyou, Jiang Xueyin. Highly efficient distyry1 arylene (DSA) derivative blue orginic electroluminescent device with improved color purity[J]. Acta Optica Sinica, 2004, 24(8): 1120~1124 (in Chinese)
吴有智,郑新友,蒋雪茵 等. 色纯度改进的苯乙烯衍生物高效蓝色有机电致发光器件[J]. 光学学报, 2004, 24(8): 1120~1124

[5] Zhu Wenqing, Zheng Xinyou, Jiang Xueyin. Study on the luminous of blue organic electroluminescent diodes with distyrylarylenes derivative[J]. Acta Optica Sinica, 2003, 23(3): 361~365 (in Chinese)
朱文清,郑新友,蒋雪茵 等. 以联苯乙烯衍生物为发光层的蓝色有机发光二极管特性的研究[J]. 光学学报, 2003, 23(3): 361~365

[6] Zhu Wenqing, Zhang Buxin, Zheng Xinyou et al.. Two types of blue organic thin film light emitting diodes with different structure[J]. Acta Optica Sinica, 2001, 21(7): 882~885 (in Chinese)
朱文清,张频新,郑新友 等. 两种不同结构的蓝色有机发光二极管[J]. 光学学报, 2001, 21(7): 882~885

[7] Chihaya Adachi, Mark E. Thompson, Stephen R. Forrest. IEEE J. Sel. Top. Quant. Electron., 2002, 8(2): 372~374

曹进, 张晓波, 委福祥, 蒋雪茵, 张志林, 朱文清, 许少鸿. 新型高色纯度弱电流猝灭性蓝色有机发光器件[J]. 光学学报, 2006, 26(2): 275. 曹进, 张晓波, 委福祥, 蒋雪茵, 张志林, 朱文清, 许少鸿. Novel Blue Organic Light Emitting Diode with Highly Saturated Color and Weak Current-Induced Quenching[J]. Acta Optica Sinica, 2006, 26(2): 275.

本文已被 8 篇论文引用
被引统计数据来源于中国光学期刊网
引用该论文: TXT   |   EndNote

相关论文

加载中...

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!