To reduce the seed length while maintaining the advantages of the cuboid KDP-type crystal, a long-seed KDP crystal with size $471~\text{mm}\times 480~\text{mm}\times 400~\text{mm}$ is rapidly grown. With almost the same high cutting efficiency to obtain third harmonic generation oriented samples, this long-seed KDP-type crystal can be grown with a shorter seed than that of the cuboid KDP-type crystal. The full width at half maximum of the high-resolution X-ray diffraction of the (200) crystalline face is 28.8 arc seconds, indicating that the long-seed KDP crystal has good crystalline quality. In the wavelength range of 377–1022 nm, the transmittance of the long-seed KDP crystal is higher than 90%. The fluence for the 50% probability of laser-induced damage (LID) is $18.5~\text{J}/\text{cm}^{2}$ (3 ns, 355 nm). Several test points survive when the laser fluence exceeds $30~\text{J}/\text{cm}^{2}$ (3 ns, 355 nm), indicating the good LID performance of the long-seed KDP crystal. At present, the growth of a long-seed DKDP crystal is under way.

In this paper, a highly deuterated potassium dihydrogen phosphate (DKDP) crystal with sizes up to $318~\text{mm}\times 312~\text{mm}\times 265~\text{mm}$ was grown by the rapid-growth method. The synthesis tank device was specially designed to synthesize a higher deuterium concentration and high-purity DKDP solution. The deuterium content of the as-grown crystal, which was 97.9%, was determined by two methods, including infrared (IR) spectroscopy and thermo-gravimetric analysis (TGA) measurements. The performances of the 97.9% DKDP crystal, including transmission, absorption coefficient, and laser-induced damage threshold (LIDT) were measured. The results indicate that, in the near-infrared band, the transmission of the 97.9% DKDP crystal is higher than that of KDP and 70% DKDP crystals, and the absorption coefficient is lower. The LIDT of the crystal reached $23.2~\text{J}\cdot \text{cm}^{-2}$ (R-on-1, 1064 nm, 3 ns), which meets the engineering requirements for use in optical applications.

Potassium dihydrogen phosphate (KDP) single crystals are the only nonlinear crystals currently used for electro-optic switches and frequency converters in inertial confinement fusion research, due to their large dimension and exclusive physical properties. Based on the traditional solution-growth process, large bulk KDP crystals, usually with sizes up to 600×600 mm2 so as to make a frequency doubler for the facility requirement loading highly flux of power laser, can be grown in standard Holden-type crystallizers, without spontaneous nucleation and visible defects, one to two orders of magnitude faster than by conventional methods. Pure water and KDP raw material with a few ion impurities such as Fe, Cr, and Al (less than 0.1 ppm) were used. The rapid-growth method includes extreme conditions such as temperature range from 60 to 35 ℃, overcooling up to 5C, growth rates exceeding 10 mm/day, and crystal size up to 600 mm. The optical parameters of KDP crystals were determined. The optical properties of crystals determined indicate that they are of favorable quality for application in the facility.