硅酸盐通报, 2023, 42 (5): 1529, 网络出版: 2023-08-13  

污水管道中混凝土硫酸腐蚀研究进展

Research Progress on Sulfuric Acid Corrosion of Concrete in Sewage Pipes
作者单位
河北工业大学土木与交通学院, 天津 300401
摘要
随着国家对污水系统规划的重视, 混凝土在污水管道中得到了广泛应用。混凝土在污水管道服役期间会受到物理、化学以及生物的协同作用而劣化。在诸多侵蚀介质中, 硫酸对混凝土的性能影响最为突出。为了进一步加深对此研究领域的理解, 本文主要从污水管道中的硫酸来源、混凝土的硫酸腐蚀机理、影响硫酸腐蚀的因素及抗硫酸腐蚀对策等研究进展进行介绍, 寻找有效的污水管道混凝土防腐对策。
Abstract
With the attention paid to the sewage system planning by the country, concrete has been widely used in sewage pipes. During the service period of sewage pipelines, concrete will be subjected to the synergistic effects of physics, chemistry and biology, leading to its deterioration. Among many corrosive media, sulfuric acid has the most prominent impact on the performance of concrete. In order to further deepen the understanding of this research field, this paper mainly introduces the research progress from the sources of sulfuric acid in sewage pipes, the mechanism of sulfuric acid corrosion of concrete, the factors affecting sulfuric acid corrosion, and the countermeasures against sulfuric acid corrosion, and looks for effective anti-corrosion measures for sewage pipe concrete.
参考文献

[1] PARKER C. The corrosion of concrete[J]. Australian Journal of Experimental Biology and Medical Science, 1945, 23(2): 81-90.

[2] VOLLERTSEN J, NIELSEN A H, JENSEN H S, et al. Corrosion of concrete sewers: the kinetics of hydrogen sulfide oxidation[J]. Science of the Total Environment, 2008, 394(1): 162-170.

[3] 胡聿涵, 白玉川, 徐海珏. 近10年中国城市道路塌陷原因及防治对策分析[J]. 公路, 2016, 61(9): 130-135.

[4] 连 峰, 张旭光, 刘 治, 等. 城市道路塌陷分析及防治对策[J]. 城乡建设, 2020(8): 60-62.

[5] 李若晗. 城市污水管道检测、评价与影响因素研究[D]. 北京: 清华大学, 2016.

[6] 罗伟文, 季 韬, 林 魁. 水泥类型对海砂混凝土在生物硫酸腐蚀下劣化影响的研究[J]. 中国腐蚀与防护学报, 2021, 41(5): 691-696.

[7] SCRIVENER K, DE BELIE N. Bacteriogenic sulfuric acid attack of cementitious materials in sewage systems[M]//ALEXANDER M, BERTRON A, DE BELIE N. Performance of Cement-Based Materials in Aggressive Aqueous Environments. Dordrecht: Springer, 2013: 305-318.

[8] O’CONNELL M, MCNALLY C, RICHARDSON M G. Biochemical attack on concrete in wastewater applications: a state of the art review[J]. Cement and Concrete Composites, 2010, 32(7): 479-485.

[9] GUTIRREZ-PADILLA M G D, BIELEFELDT A, OVTCHINNIKOV S, et al. Biogenic sulfuric acid attack on different types of commercially produced concrete sewer pipes[J]. Cement and Concrete Research, 2010, 40(2): 293-301.

[10] ALEXANDER M G, FOURIE C. Performance of sewer pipe concrete mixtures with Portland and calcium aluminate cements subject to mineral and biogenic acid attack[J]. Materials and Structures, 2011, 44(1): 313-330.

[11] 柯 伟. 中国工业与自然环境腐蚀调查[J]. 全面腐蚀控制, 2003, 17(1): 1-10.

[12] GRENGG C, MITTERMAYR F, BALDERMANN A, et al. Microbiologically induced concrete corrosion: a case study from a combined sewer network[J]. Cement and Concrete Research, 2015, 77: 16-25.

[13] JENSEN H S. Hydrogen sulfide induced concrete corrosion of sewer networks[D]. South Yorkshire: The University of Sheffield, 2009.

[14] 佚 名. 两部委发布“十四五”城镇污水处理及资源化利用发展规划到2025年县城污水处理率达到95%以上[J]. 城市道桥与防洪, 2021(8): 351.

[15] 2部门联合印发《“十四五”城镇污水处理及资源化利用发展规划》[J]. 招标采购管理, 2021(6): 8.

[16] MIN H G, SONG Z G. Investigation on the sulfuric acid corrosion mechanism for concrete in soaking environment[J]. Advances in Materials Science and Engineering, 2018, 2018: 1-10.

[17] 韩菊红, 李登华, 张雷顺. 改性混凝土耐腐蚀性能试验研究[J]. 人民黄河, 2007, 29(2): 67-69.

[18] 韩静云, 张小伟, 田永静, 等. 污水处理系统中混凝土结构的腐蚀现状调查及分析[J]. 混凝土, 2000(11): 52-54+63.

[19] 闻宝联. 城市污水环境下混凝土腐蚀及耐久性研究[D]. 天津: 天津大学, 2005.

[20] 孔丽娟, 包 昕, 曹梦凡. 生物膜对污水环境下混凝土腐蚀的影响[J]. 硅酸盐学报, 2016, 44(2): 279-285.

[21] 孔丽娟, 张 蓓, 魏 薇, 等. 污水环境下水泥净浆、砂浆、混凝土腐蚀相关性[J]. 混凝土, 2022(1): 51-56.

[22] YUAN H F, DANGLA P, CHATELLIER P, et al. Degradation modelling of concrete submitted to sulfuric acid attack[J]. Cement and Concrete Research, 2013, 53: 267-277.

[23] MAHDIKHANI M, BAMSHAD O, FALLAH SHIRVANI M. Mechanical properties and durability of concrete specimens containing nano silica in sulfuric acid rain condition[J]. Construction and Building Materials, 2018, 167: 929-935.

[24] 曹 琛, 郑山锁, 胡卫兵. 酸雨环境下混凝土结构性能研究综述[J]. 材料导报, 2019, 33(11): 1869-1874.

[25] 谢 顺. 酸雨对建筑砂浆性能的影响研究[D]. 沈阳: 沈阳建筑大学, 2016.

[26] HUANG S, ZHAO X, SUN Y Q, et al. Pollution of hazardous substances in industrial construction and demolition wastes and their multi-path risk within an abandoned pesticide manufacturing plant[J]. Frontiers of Environmental Science & Engineering, 2017, 11(1): 12.

[27] PARKER C D. The corrosion of concrete[J]. Australian Journal of Experimental Biology and Medical Science, 1945, 23(2): 91-98.

[28] HOUSE M, WEISS W J. Review of microbially induced corrosion and comments on needs related to testing procedures[C]//Proceedings of the 4th International Conference on the Durability of Concrete Structures. Purdue University Libraries Scholarly Publishing Services, 2014.

[29] HOUSE M. Using biological and physico-chemical test methods to assess the role of concrete mixture design in resistance to microbially induced corrosion[J]. Dissertations and Theses-Gradworks, 2013.

[30] MAHAPATRA S, BANERJEE D. Fungal exopolysaccharide: production, composition and applications[J]. Microbiology Insights, 2013, 6: 1-16.

[31] 谢世华. 腐蚀产物附面层对硫酸侵蚀混凝土速度的影响[D]. 昆明: 昆明理工大学, 2020.

[32] VINCKE E, BOON N, VERSTRAETE W. Analysis of the microbial communities on corroded concrete sewer pipes-a case study[J]. Applied Microbiology and Biotechnology, 2001, 57(5): 776-785.

[33] STANASZEK-TOMAL E, FIERTAK M. Biological corrosion in the sewage system and the sewage treatment plant[J]. Procedia Engineering, 2016, 161: 116-120.

[34] 李铁锋. 环境地学概论[M]. 北京: 中国环境科学出版社, 1996.

[35] 余 倩, 段 雷, 郝吉明. 中国酸沉降: 来源、影响与控制[J]. 环境科学学报, 2021, 41(3): 731-746.

[36] 杨 晗, 耿 欧, 冯磊磊. 再生骨料透水混凝土抗酸雨侵蚀性能研究[J]. 混凝土, 2021(11): 24-28.

[37] 凌 琪. 酸雨的形成机制研究进展[J]. 安徽建筑工业学院学报(自然科学版), 1995, 3(1): 55-58.

[38] 钟 磊. 局部腐蚀方钢管混凝土轴压短柱力学性能[D]. 哈尔滨: 哈尔滨工业大学, 2021.

[39] 陈梦成, 方 苇, 黄 宏. 模拟酸雨腐蚀钢管混凝土构件静力性能研究[J]. 工程力学, 2020, 37(2): 34-43.

[40] DUAN L, MA X X, LARSSEN T, et al. Response of surface water acidification in Upper Yangtze River to SO2 emissions abatement in China[J]. Environmental Science & Technology, 2011, 45(8): 3275-3281.

[41] QIAO Y H, FENG J F, LIU X, et al. Surface water pH variations and trends in China from 2004 to 2014[J]. Environmental Monitoring and Assessment, 2016, 188(7): 443.

[42] 李 崇, 周 俊, 刘 瑶, 等. 我国废硫酸产生及综合利用现状[J]. 过程工程学报, 2018, 18(s1): 24-34.

[43] 李白冰. 如何用萃取法拯救工业废水中的硫酸[J]. 金属世界, 2022(2): 65-67.

[44] 纪罗军, 赵红林, 靳志超. 从循环经济角度看工业废硫酸的资源化利用[J]. 硫酸工业, 2021(10): 1-6.

[45] 全国硫与硫酸工业信息总站. 我国硫酸工业酸性污水减排技术进展[C]//第五届全国烟气脱硫脱硝及污酸污水技术年会(2017)论文集. 西安, 2017: 125-128.

[46] PEYRONNARD O, BLANC D, BENZAAZOUA M, et al. Study of mineralogy and leaching behavior of stabilized/solidified sludge using differential acid neutralization analysis[J]. Cement and Concrete Research, 2009, 39(6): 501-509.

[47] CRAMMOND N. The occurrence of thaumasite in modern construction: a review[J]. Cement and Concrete Composites, 2002, 24(3/4): 393-402.

[48] HAGELIA P, SIBBICK R G, CRAMMOND N J, et al. Thaumasite and secondary calcite in some Norwegian concretes[J]. Cement and Concrete Composites, 2003, 25(8): 1131-1140.

[49] 王 凯, 马保国, 龙世宗, 等. 不同品种水泥混凝土的抗酸雨侵蚀性能[J]. 武汉理工大学学报, 2009, 31(2): 1-4.

[50] MONTENY J, VINCKE E, BEELDENS A, et al. Chemical, microbiological, and in situ test methods for biogenic sulfuric acid corrosion of concrete[J]. Cement and Concrete Research, 2000, 30(4): 623-634.

[51] MEHTA P K, MONTEIRO P J M. Concrete: microstructure, properties, and materials[M]. 3rd ed. New York: McGraw-Hill, 2006.

[52] JOSEPH A P, KELLER J, BUSTAMANTE H, et al. Surface neutralization and H2S oxidation at early stages of sewer corrosion: influence of temperature, relative humidity and H2S concentration[J]. Water Research, 2012, 46(13): 4235-4245.

[53] 杨 凯. 酸性水腐蚀下混凝土性能的劣化与防腐技术研究[D]. 武汉: 武汉理工大学, 2011.

[54] 战 越. 硫酸侵蚀混凝土及胶砂试件的附面层效应研究[D]. 昆明: 昆明理工大学, 2017.

[55] 张彩虹. 硫酸腐蚀混凝土材料试验研究及数值模拟[D]. 昆明: 昆明理工大学, 2021.

[56] 林 魁. 生物硫酸对SAC海砂混凝土劣化及氯离子固化影响[D]. 福州: 福州大学, 2016.

[57] 韩静云, 郜志海, 张小伟. 城市污水对初沉池混凝土不均衡损伤特性研究[J]. 土木工程学报, 2005, 38(7): 45-49.

[58] 张伟航. 冲刷与稀硫酸联合腐蚀作用下砂浆耐久性研究[D]. 昆明: 昆明理工大学, 2014.

[59] 路浩然. 水流冲刷对污水管内混凝土腐蚀的作用机制研究[D]. 石家庄: 石家庄铁道大学, 2019.

[60] 李北星, 周长泉, 蔡老虎, 等. 硫酸环境作用下粉煤灰混凝土性能劣化时变规律[J]. 材料科学与工程学报, 2014, 32(6): 809-815.

[61] 陈 铮. 多掺复合料对水泥基材料抗酸腐蚀性能影响的研究[D]. 抚州: 东华理工大学, 2019.

[62] 钱文勋, 贺传卿, 何 旸, 等. 提升水泥砂浆耐酸性能的防护技术研究[J]. 混凝土与水泥制品, 2020(3): 10-14.

[63] DE BELIE N, MONTENY J, BEELDENS A, et al. Experimental research and prediction of the effect of chemical and biogenic sulfuric acid on different types of commercially produced concrete sewer pipes[J]. Cement and Concrete Research, 2004, 34(12): 2223-2236.

[64] 肖 杰, 屈文俊, 朱 鹏. 不同粗细骨料组合下的混凝土耐硫酸腐蚀研究[J]. 建筑科学与工程学报, 2016, 33(6): 81-87.

[65] CHANG Z T, SONG X J, MUNN R, et al. Using limestone aggregates and different cements for enhancing resistance of concrete to sulphuric acid attack[J]. Cement and Concrete Research, 2005, 35(8): 1486-1494.

[66] MAKHLOUFI Z, KADRI E H, BOUHICHA M, et al. Resistance of limestone mortars with quaternary binders to sulfuric acid solution[J]. Construction and Building Materials, 2012, 26(1): 497-504.

[67] 屈志中. 混凝土的抗生物侵蚀性[J]. 混凝土, 1997(5): 34-36+39.

[68] UCHIDA H, ENOKIDA T, TANAKA R, et al. Deterioration preventive for concrete or mortar and method for preventing deterioration of concrete or mortar: US6159281[P]. 2000-12-12.

[69] ALUM A, RASHID A, MOBASHER B, et al. Cement-based biocide coatings for controlling algal growth in water distribution canals[J]. Cement and Concrete Composites, 2008, 30(9): 839-847.

[70] 王 萌. 城市生活污水对混凝土的腐蚀及防治研究[D]. 石家庄: 石家庄铁道大学, 2015.

[71] 马 荣. 二氧化氯杀菌技术在油田回注水处理中的应用效果[J]. 油气田地面工程, 2016, 35(6): 88-89.

[72] 乔怡娜. 二氧化氯杀菌机理及其对城市污水杀菌消毒应用研究[D]. 太原: 中北大学, 2008.

[73] YAMANAKA T, ASO I, TOGASHI S, et al. Corrosion by bacteria of concrete in sewerage systems and inhibitory effects of formates on their growth[J]. Water Research, 2002, 36(10): 2636-2642.

[74] 任 晨, 李思哲. 一种抗混凝土微生物腐蚀的混凝土外加剂: CN103755196A[P]. 2016-02-24.

[75] MERACHTSAKI D, FYTIANOS G, PAPASTERGIADIS E, et al. Properties and performance of novel Mg(OH)2-based coatings for corrosion mitigation in concrete sewer pipes[J]. Materials (Basel, Switzerland), 2020, 13(22): 5291.

[76] 贺 奎. 恶劣环境下混凝土用有机功能材料及其防护机理研究[D]. 杭州: 浙江大学, 2014.

[77] ALMUSALLAM A A, KHAN F M, DULAIJAN S U, et al. Effectiveness of surface coatings in improving concrete durability[J]. Cement and Concrete Composites, 2003, 25(4/5): 473-481.

[78] HAILE T, NAKHLA G, ALLOUCHE E, et al. Evaluation of the bactericidal characteristics of nano-copper oxide or functionalized zeolite coating for bio-corrosion control in concrete sewer pipes[J]. Corrosion Science, 2010, 52(1): 45-53.

[79] 李 宾, 李昌兰, 王晓东, 等. 合流污水环境中混凝土管道的涂层保护[J]. 材料保护, 2001, 34(12): 33-34.

[80] 齐秋霖, 周 健, 葛仲熙, 等. 硫铝酸盐水泥抗酸侵蚀性能与机理研究[J]. 硅酸盐通报, 2021, 40(8): 2508-2514+2533.

[81] YANG Y, JI T, LIN X J, et al. Biogenic sulfuric acid corrosion resistance of new artificial reef concrete[J]. Construction and Building Materials, 2018, 158: 33-41.

[82] 刘浩然. 高抗折低热矿渣硫铝酸盐水泥抗化学侵蚀性能及机理[D]. 天津: 河北工业大学, 2019.

[83] 胡 洁, 郑娟荣. 碱激发胶凝材料抗酸侵蚀性的试验研究[J]. 山西建筑, 2011, 37(35): 119-120.

[84] 刘红飞, 蒋元海. 我国碱激发混凝土标准研制与应用[J]. 混凝土世界, 2021(3): 58-62.

[85] GE Z, SUN R J, ZHANG K, et al. Physical and mechanical properties of mortar using waste polyethylene terephthalate bottles[J]. Construction and Building Materials, 2013, 44: 81-86.

周健, 林志超, 徐名凤, 李辉, 聂松. 污水管道中混凝土硫酸腐蚀研究进展[J]. 硅酸盐通报, 2023, 42(5): 1529. ZHOU Jian, LIN Zhichao, XU Mingfeng, LI Hui, NIE Song. Research Progress on Sulfuric Acid Corrosion of Concrete in Sewage Pipes[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(5): 1529.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!