光散射学报, 2015, 27 (4): 0364, 网络出版: 2016-01-20  

基于振动光谱成像技术的聚合物共混体系研究进展

Research Progress and Application of Polymer Blend Based on Vibrational Spectroscopy Imaging Techniques
作者单位
1 西南大学化学化工学院,重庆 400715
2 中山大学化学与化学工程学院,广州 510275
3 中山大学测试中心
摘要
振动光谱可以提供分子的振动信息,对于聚合物分子链的构象和链间的相互作用非常敏感。分子振动光谱成像作为一种原位无损检测技术,广泛应用于聚合物共混体系结晶、相态分布、界面扩散等性质的研究。本文综述了拉曼(Raman)光谱和红外(IR)光谱成像技术以及其衍生的具有高空间分辨率的红外-原子力联用技术(IR-AFM)、拉曼-原子力联用技术(Raman-AFM)以及针尖增强拉曼光谱技术(TERS)在聚合物共混体系研究中的最新应用进展,以探索并扩展振动光谱成像技术在高分子领域中的应用。
Abstract
Vibrational Spectroscopy can provide molecular vibrational information and can be very sensitive to the conformation of polymer molecular chains and interaction between chains.Vibrational Spectroscopy Imaging as an in situ non-damage detection is widely applied to the study of polymer blend’s properties such as crystallization,distribution of phase state and interface diffusion.The present paper emphasized to summarize the headway of application research of polymer blend by imaging techniques of Raman Spectroscopy and Infrared Spectroscopy and their derivative techniques with high-space resolution ratio,such as the combination of Infrared Spectroscopy and Atomic Force Microscope(IR-AFM),the combination of Raman Spectroscopy and Atomic Force Microscope(Raman-AFM)and Tip-Enhanced Raman Spectroscopy(TERS),aiming to explore and expand the application of vibrational Spectroscopy imaging techniques in the polymer field.
参考文献

[1] Baer M.Studies on heterogeneous polymeric systems I:Influence of morphology on mechanical properties[J].J Appl Polym Sci,1972,16:1109-1123.

[2] Dickie R D,Newman P S.Polymer Blends:Chap.8:Mechanical Properties(Small Deformations)of Multiphase Polymer Blends [M].Academic Press,New York,1978,1:353.

[3] Manson J,Sperling L.Polymer Blends and Composites [M].Plenum Press,New York,1976.

[4] Markwort L.Micro-Raman Imaging of Heterogeneous Polymer Systems:General Applications and Limitations[J].J Appl Polym Sci,1996,61:231-254.

[5] 左敏.LCST型高分子共混体系相分离行为与粘弹弛豫的研究 [D].浙江大学博士学位论文.2007:13-21.

    Zuo Min.Study on the behavior and viscoelastic relaxation phase separation of LCST type polymer blends [D].Doctoral Dissertation of Zhejiang University,2007:13-21

[6] 胡成龙.拉曼光谱法研究聚合物分子链的动态运动过程.中山大学博士论文.2011:1-21.

    Hu Chenglong.Dynamic movement process of Raman study of polymer molecular spectroscopy chain [D].Doctoral Dissertation of Sun Yat-sen University,2011:1-21

[7] Vogel C,Wessel E,Siesler H W.FT-IR Spectroscopic Imaging of Anisotropic Poly(3-hydroxybutyrate)/Poly(lactic acid)Blends with Polarized Radiation[J].Macromolecules 2008,41:2975.

[8] Rhuday K L,Su S,Howell H R,et al.Stimuli-Responsive Surface Crystallization of Phospholipids from Bimodal Colloidal Particles[J].Langmuir,2008,24:1808.

[9] Shin E,Riber T,Koenig J L,et al.Analysis of Binary Solvent Diffusion into Cross-Linked Poly(butadiene)Using Fast Scan Fourier Transform Infrared Imaging Spectroscopy[J].Appl Spectrosc,2001,55:1573.

[10] Gupper A,Wilhelm P,Schmied M,et al,Combined Application of Imaging Methods for the Characterization of a Polymer Blend[J].J Appl Spectrosc,2002,56:1515.

[11] Rafferty D W,Koenig J L,Maagyar G.,et al.FT-IR Imaging of Patterned Photocrosslinkable Poly(vinyl cinnamate)[J].Appl Spectrosc,2002,56:1549.

[12] Hikima Y,Morikawa J,Hashimoto T.Imaging of Two-Dimensional Distribution of Molecular Orientation in Poly(ethylene oxide)Spherulite Using IR Spectrum and Birefringence[J].Macromolecules,2012,45:8356-8362.

[13] Hikima Y,Morikawa J,Hashimoto T.Wavenumber Dependence of FT-IR Image of Molecular Orientation in Banded Spherulites of Poly(3-hydroxybutyrate)and Poly(Lactic acid)[J].Macromolecules 2013,46:1582-1590.

[14] Unger M,Sedlmair J,Siesler H,et al.3D FT-IR imaging spectroscopy of phase-separation in a poly(3-hydroxybutyrate)/poly(l-lactic acid)blend[J].Vibrational Spectroscopy,2014,75:169-172.

[15] Mu T,Cong Y,Zhang B.High Flux and Rejection with Chiral Chitosan Composite Nanofiltration Membranes:Preparation and Characterization[J].J Appl Polym Sci,2013:3582

[16] Sato H,Sasao S,Matsukawa K,et al. Raman Mapping Study of Compatibilized and Uncompatibilized Polymer Blends of Nylon 12 and Polyethylene[J].Applied Spectroscopy,2002,56(8):1038-1043.

[17] Morgana R L,Hilla M J,Barhama P J,et al.A study of the phase behaviour of polyethylene blends using micro-Raman imaging[J].Polymer,2001,42:2121-2135.

[18] Huan S Y,Lin W Q,Sato H M,et al.Direct characterization of phase behavior and compatibility in PET/HDPE polymer blends by confocal Raman mapping[J].J Raman Spectrosc,2007,38:260-270.

[19] Kotzianova A,Rebicek J,Mojzes P,et al.Analysis of composite nano brous layers by confocal Raman microscopy[J].Polymer 2014,55:5036-5042.

[20] Grimm S B,Jakubka F,Schieβl S P,et al. Mapping Charge-Carrier Density Across the p-π Junction in Ambipolar Carbon-Nanotube Networks by Raman Microscopy[J].Adv Mater,2014,26:7986-7992.

[21] Schmidt U,Hild S,Ibach W,et al.Characterization of Thin Polymer Films on the Nanometer Scale with Confocal Raman AFM[J].Macromol Symp,2005,230:133-143.

[22] Lua Y Y,Cao X P,Rohrs B R,et al.Surface Characterizations of Spin-Coated Films of Ethylcellulose and Hydroxypropyl Methylcellulose Blends[J].Langmuir,2007,23:4286 4292.

[23] Wang D.True surface topography and nanomechanical mapping measurements on block copolymers with atomic force microscopy[J].Macromolecules,2010,43:3169-3172.

[24] Dazzi A,Prazeres R,Glotin F,et al.Analysis of nano-chemical mapping performed by an AFM-based(AFM-IR)acousto-optic technique[J].Ultramicroscopy,2007,107(12):1194-1200.

[25] Dazzi A,Prazeres R,Glotin F,et al.Chemical mapping of the distribution of viruses into infected bacteria with a photothermal method[J].Ultramicroscopy,2008,108(7):635-641.

[26] Dazzi A,France O,Prater C B,et al.AFM-IR:combining atomic force microscopy and infrared spectroscopy for nanoscale chemical characterization[J].Applied Spectroscopy OA,2012,66(12):1365-1384.

[27] Marcott C,Lo M,Kjoller K,et al.Spatial differentiation of sub-micrometer domains in a poly(hydroxyalkanoate)copolymer using instrumentation that combines atomic force microscopy(AFM)and infrared(IR)spectroscopy[J].Applied Spectroscopy,2011,65(10):1145-1150.

[28] Eby T,Gundusharma U,Lo M,et al.Reverse engineering of polymeric multilayers using AFM-based nanoscale IR spectroscopy and thermal analysis[J].Spectroscopy Europe,2012,24(3):18-21.

[29] Ye J P,Midorikawa H,Awatani T,et al.Nanoscale infrared spectroscopy and AFM imaging of a polycarbonate/ acrylonitrile-styrene/butadiene blend[J].Microscopy and Analysis,2012,26(3):24-27.

[30] Felts J R,Kjoller K,Lo M,et al.Nanometer-Scale Infrared Spectroscopy of Heterogeneous Polymer Nanostructures Fabricated by Tip-Based Nanofabrication[J].ACS Nano,2012,6(9):8015-8021.

[31] Eerdenbrugh B.V,Lo M,Kjoller K,et al.Nanoscale mid-infrared imaging of phase separation in a drug-polymer blend[J].Journal of Pharmaceutical Sciences,2012:1-8.

[32] 王瑞,郝凤欢,张明倩,等.针尖增强拉曼光谱术原理与系统设计关键[J].激光与光电子学进展,2010,47:031601.

    Wang Rui,He Fenghuan,Zhang Mingqian,et al.The principles and key system design of tip enhanced Raman spectroscopy[J].Laser & Optoelectronics Progress,2010,47:031601

[33] 魏红,徐红星.单分子表面增强光谱[J].中国科学:物理学力学天文学,2010,40(1):1-15.

    Wei Hong,Xun Hongxing.Surface enhanced spectroscopy of single molecule[J].SCIENCE CHINA:Physics,Mechanics & Astronomy,2010,40(1):1-15

[34] 贺卫东,张伟,栗苹.表面增强光谱和表面等离激元共振传感器[J].科学通报,2011,56(20):1585-1592.

    He Weidong,Zhang Wei,Su ping.Surface enhanced spectroscopy and surface plasmon resonance sensor[J].Chinese Science Bulletin,2011,56(20):1585-1592

[35] 任斌,王喜.针尖增强拉曼光谱:技术、应用和发展[J].光散射学报,2006,18(4):288-296.

    Ren Bin,Wang Xi.Tip enhanced raman spectroscopy:application and development of technology[J].J Light Scatt,2006,18(4):288-296

[36] 任斌,田中群.表面增强拉曼光谱的研究进展[J].现代仪器,2004,5:1-13.

    Ren Bin,Tian Zhongqun.Research progress of surface enhanced Raman spectrum[J].Modern Instrument,2004,5:1-13

[37] Mark S A,Locally enhanced Raman spectroscopy with an atomic force microscope[J].Appl.Phys Lett,2000,76(21):3130-3132.

[38] Yeo B S,Amstad E,Schmid T,et al.Nanoscale probing of a polymer-blend thin film with tip-enhanced Raman spectroscopy[J].Small,2009,5:952-960.

[39] Xue L J,Li W Z,Hoffmann G.G.,et al. High-resolution chemical identification of polymer blend thin films using tip-enhanced Raman mapping[J].Macromolecules,2011,44:2852-2858.

[40] Xue L J,Li W Z,Hoffmann G G,et al. High resolution tip enhanced Raman mapping on polymer thin films[J].Macromol Symp,2011,305:73-80.

[41] Wang X,Zhang D,Braun K,et al. High-Resolution Spectroscopic Mapping of the Chemical Contrast from Nanometer Domains in P3HT:PCBM Organic Blend Films for Solar-Cell Applications[J].Adv Funct Mater,2010,20:492-499.

黎青霞, 袁中柯, 张卫红, 陈建, 陈旭东. 基于振动光谱成像技术的聚合物共混体系研究进展[J]. 光散射学报, 2015, 27(4): 0364. LI Qing-xia, YUAN Zhong-ke, ZHANG Wei-hong, CHEN Jian, CHEN Xu-dong. Research Progress and Application of Polymer Blend Based on Vibrational Spectroscopy Imaging Techniques[J]. The Journal of Light Scattering, 2015, 27(4): 0364.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!