人工晶体学报, 2023, 52 (12): 2156, 网络出版: 2024-01-03
Gd3(Al,Ga)5O12∶Ce晶体生长与闪烁性能研究
Growth and Scintillation Properties of Gd3(Al,Ga)5O12∶Ce Crystal
闪烁晶体 高温固相反应法 提拉法 闪烁性能 GAGG∶Ce GAGG∶Ce scintillation crystal high temperature solid state reaction method Czochralski method scintillation property
摘要
掺铈钆铝镓石榴石(Gd3(Al,Ga)5O12∶Ce,简称GAGG∶Ce)闪烁晶体是近年来发现的一种新型稀土闪烁晶体,具有光输出高、能量分辨率高、衰减时间短、无自辐射和不潮解等优点,在核医学成像、安检和环境监测等领域具有广阔的应用前景。本文报道了GAGG∶Ce晶体的提拉法生长与闪烁性能表征。利用高温固相反应法合成GAGG∶Ce原料,采用XRD对合成的原料进行了物相分析,结果表明,在1 500 ℃下煅烧12 h合成的多晶料为纯GAGG相。利用提拉法生长出尺寸50 mm×90 mm的GAGG∶Ce晶体,测试了其透过光谱、X射线激发发射光谱和脉冲高度谱,结果表明,7 mm厚样品550 nm的透过率为81.5%,晶体X射线激发发射峰中心波长位于550 nm,晶体的光输出为59 000 photons/MeV,能量分辨率为6.2%@662 keV,晶体衰减时间快分量为149 ns,慢分量为748 ns。
Abstract
Ce3+ doped gadolinium aluminum gallium garnet (GAGG∶Ce) scintillation crystal has the advantages of high light output, high energy resolution, short decay time, no self radiation and nondeliquescence, which make it has a broad application prospect in nuclear medical imaging, security inspection and environment detection et al. This paper reported the Czochralski growth and scintillation properties of GAGG∶Ce single crystal. GAGG∶Ce raw material was synthesized by high temperature solid state reaction method. By means of XRD analysis, the raw material sintered at 1 500 ℃ for 12 h is verified to be pure GAGG phase. GAGG∶Ce crystal with size of 50 mm×90 mm was successfully grown by Czochralski method. The transmission spectrum, Xray excited emission spectrum and pulse height spectrum of the crystal were tested. Results show that optical transmittance at 550 nm for the sample with thickness of 7 mm reaches as high as 81.5%. The Xray excited emission peak central wavelength of the GAGG∶Ce crystal is located at 550 nm. The light output of the GAGG∶Ce crystal is 59 000 photons/MeV and the energy resolution is 6.2%@662 keV. The decay time is 149 ns and a slow component of 748 ns.
王海丽, 李辉, 周南浩, 石爽爽, 苏健, 张微, 陈建荣, 黄存新. Gd3(Al,Ga)5O12∶Ce晶体生长与闪烁性能研究[J]. 人工晶体学报, 2023, 52(12): 2156. WANG Haili, LI Hui, ZHOU Nanhao, SHI Shuangshuang, SU Jian, ZHANG Wei, CHEN Jianrong, HUANG Cunxin. Growth and Scintillation Properties of Gd3(Al,Ga)5O12∶Ce Crystal[J]. Journal of Synthetic Crystals, 2023, 52(12): 2156.