人工晶体学报, 2023, 52 (12): 2156, 网络出版: 2024-01-03  

Gd3(Al,Ga)5O12∶Ce晶体生长与闪烁性能研究

Growth and Scintillation Properties of Gd3(Al,Ga)5O12∶Ce Crystal
作者单位
1 北京中材人工晶体研究院有限公司,北京100018
2 中材人工晶体研究院有限公司,北京100018
摘要
掺铈钆铝镓石榴石(Gd3(Al,Ga)5O12∶Ce,简称GAGG∶Ce)闪烁晶体是近年来发现的一种新型稀土闪烁晶体,具有光输出高、能量分辨率高、衰减时间短、无自辐射和不潮解等优点,在核医学成像、安检和环境监测等领域具有广阔的应用前景。本文报道了GAGG∶Ce晶体的提拉法生长与闪烁性能表征。利用高温固相反应法合成GAGG∶Ce原料,采用XRD对合成的原料进行了物相分析,结果表明,在1 500 ℃下煅烧12 h合成的多晶料为纯GAGG相。利用提拉法生长出尺寸50 mm×90 mm的GAGG∶Ce晶体,测试了其透过光谱、X射线激发发射光谱和脉冲高度谱,结果表明,7 mm厚样品550 nm的透过率为81.5%,晶体X射线激发发射峰中心波长位于550 nm,晶体的光输出为59 000 photons/MeV,能量分辨率为6.2%@662 keV,晶体衰减时间快分量为149 ns,慢分量为748 ns。
Abstract
Ce3+ doped gadolinium aluminum gallium garnet (GAGG∶Ce) scintillation crystal has the advantages of high light output, high energy resolution, short decay time, no self radiation and nondeliquescence, which make it has a broad application prospect in nuclear medical imaging, security inspection and environment detection et al. This paper reported the Czochralski growth and scintillation properties of GAGG∶Ce single crystal. GAGG∶Ce raw material was synthesized by high temperature solid state reaction method. By means of XRD analysis, the raw material sintered at 1 500 ℃ for 12 h is verified to be pure GAGG phase. GAGG∶Ce crystal with size of 50 mm×90 mm was successfully grown by Czochralski method. The transmission spectrum, Xray excited emission spectrum and pulse height spectrum of the crystal were tested. Results show that optical transmittance at 550 nm for the sample with thickness of 7 mm reaches as high as 81.5%. The Xray excited emission peak central wavelength of the GAGG∶Ce crystal is located at 550 nm. The light output of the GAGG∶Ce crystal is 59 000 photons/MeV and the energy resolution is 6.2%@662 keV. The decay time is 149 ns and a slow component of 748 ns.

王海丽, 李辉, 周南浩, 石爽爽, 苏健, 张微, 陈建荣, 黄存新. Gd3(Al,Ga)5O12∶Ce晶体生长与闪烁性能研究[J]. 人工晶体学报, 2023, 52(12): 2156. WANG Haili, LI Hui, ZHOU Nanhao, SHI Shuangshuang, SU Jian, ZHANG Wei, CHEN Jianrong, HUANG Cunxin. Growth and Scintillation Properties of Gd3(Al,Ga)5O12∶Ce Crystal[J]. Journal of Synthetic Crystals, 2023, 52(12): 2156.

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