硅酸盐通报, 2023, 42 (11): 3836, 网络出版: 2023-12-11
SAP对高性能工程水泥基复合材料性能的影响
Effect of SAP on Properties of High Performance Engineered Cementitious Composites
超吸水性聚合物 高性能工程水泥基复合材料 收缩性能 抗压强度 抗折强度 拉伸性能 superabsorbent polymer high performance engineered cementitious composite shrinkage property compressive strength flexural strength tensile property
摘要
高收缩率是限制高性能工程水泥基复合材料(HP-ECC)大规模工程应用的瓶颈之一。本文通过引入超吸水性聚合物(SAP)来缓解HP-ECC的收缩, 研究了不同掺量的SAP对HP-ECC抗压强度、抗折强度、拉伸性能、自收缩和干燥收缩性能的影响, 并采用扫描电子显微镜(SEM)研究了SAP对HP-ECC拉伸后纤维表面形貌变化的影响。结果表明, HP-ECC中掺入SAP后的抗压强度和抗折强度降低, 自收缩和干燥收缩得到缓解, 且自收缩和干燥收缩随SAP掺量的增加而降低。此外, HP-ECC的拉伸强度降低, 拉伸延伸率提高。SAP的引入降低了基体的断裂韧度, 使基体更容易形成微裂缝, 从而改善了HP-ECC的应变硬化行为和多缝开裂现象。随着SAP掺量的增加, 纤维从基体中拔出时的表面形貌越来越光滑, 纤维-基体界面黏结性能降低。
Abstract
High shrinkage is one of the bottlenecks limiting the large-scale engineering application of high performance engineered cementitious composites (HP-ECC). This work alleviated the shrinkage of HP-ECC by introducing superabsorbent polymers (SAP). The effects of different amounts of SAP on the compressive strengthflexural strengthtensile propertiesautogenous shrinkage and dry shrinkage properties of HP-ECC were investigated. Scanning electron microscopy (SEM) was used to observe the changes in fiber surface morphology after stretching of HP-ECC caused by SAP. The results show that the addition of SAP reduces the compressive strength and flexural strength of HP-ECC and alleviates autogenous shrinkage and dry shrinkageand the autogenous shrinkage and dry shrinkage decreases with the increase of SAP content. MoreoverSAP reduces the tensile strength of HP-ECC and increases the tensile strain of HP-ECC. The incorporation of SAP reduces the fracture toughness of the matrixmaking it more prone to microcracksthereby improving the strain hardening behavior and multiple cracking of HP-ECC. It is observed that with the increase of SAP contentthe surface morphology of the fibers as they are pulled out of the matrix becomes smootherindicating a decreasing in fiber matrix interface adhesion.
姜爱国, 杨维斌, 蔡杰. SAP对高性能工程水泥基复合材料性能的影响[J]. 硅酸盐通报, 2023, 42(11): 3836. JIANG Aiguo, YANG Weibin, CAI Jie. Effect of SAP on Properties of High Performance Engineered Cementitious Composites[J]. Bulletin of the Chinese Ceramic Society, 2023, 42(11): 3836.