Mingyuan Ye 1†Xiaorui Hao 2†Jinfeng Zeng 3Lin Li 4,*[ ... ]Yuhan Wu 1,6,****
Author Affiliations
Abstract
1 School of Environmental and Chemical Engineering, Shenyang University of Technology, Shenyang 110870, China
2 College of Materials Science and Engineering, Nanjing Tech University, Nanjing 211816, China
3 College of Pharmacy, Xinjiang Medical University, Engineering Research Center of Xinjiang and Central Asian Medicine Resources (Ministry of Education), Urumqi 830000, China
4 Institute for Carbon Neutralization, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China
5 School of Physics and Electronic Engineering, Jiangsu University, Zhenjiang 212013, China
6 Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
Anode materials are an essential part of lithium-ion batteries (LIBs), which determine the performance and safety of LIBs. Currently, graphite, as the anode material of commercial LIBs, is limited by its low theoretical capacity of 372 mA·h·g?1, thus hindering further development toward high-capacity and large-scale applications. Alkaline earth metal iron-based oxides are considered a promising candidate to replace graphite because of their low preparation cost, good thermal stability, superior stability, and high electrochemical performance. Nonetheless, many issues and challenges remain to be addressed. Herein, we systematically summarize the research progress of alkaline earth metal iron-based oxides as LIB anodes. Meanwhile, the material and structural properties, synthesis methods, electrochemical reaction mechanisms, and improvement strategies are introduced. Finally, existing challenges and future research directions are discussed to accelerate their practical application in commercial LIBs.
alkali-earth metal iron-based oxides anodes lithium-ion batteries electrochemical energy storage 
Journal of Semiconductors
2024, 45(2): 021801
作者单位
摘要
1 天津工业大学纺织科学与工程学院 天津 300387
2 天津金发新材料有限公司 天津 300000
通过γ射线辐照技术引入“自掺杂”缺陷,优化硬碳层间尺寸和孔结构。通过扫描电镜、X射线衍射、拉曼光谱、等温氮气吸脱附等方法探究了吸收剂量对硬碳层间距与内部缺陷、无序结构的影响;通过恒电流充/放电研究了材料的电化学性能。结果表明:较低剂量辐照会提升硬碳表面结晶度,而随着吸收剂量的增加,硬碳无序结构增多,辐照后硬碳电化学性能得到明显改善。在140 kGy剂量辐照下,硬碳呈现出425.343 m2/g的高比表面积,硬碳在30 mA/g能够提供300 mAh/g的储钠容量,在1 A/g大电流密度容量仍然保持在195 mAh/g,对比未辐照处理的硬碳,电极容量提高了3倍,并且在大倍率充/放电过程中保持优良的稳定性能。这项工作为设计先进的纳米材料及缺陷工程在储能领域的应用提供了新的途径和思路。
γ射线 辐照 硬碳 缺陷 层间尺寸 储钠性能 γ-Ray Irradiation Hard carbon Defects Interlayer spacing Sodium storage properties 
辐射研究与辐射工艺学报
2024, 42(1): 010202
Author Affiliations
Abstract
1 Research Institute of Physics, Southern Federal University, Rostov-on-Don, 344090, Russia
2 Faculty of Physics, Southern Federal University, Rostov-on-Don, 344090, Russia
3 Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, 344006, Russia
The solid solutions of the (1-x)Na0.5Bi0.5TiO3-xNa0.5K0.5NbO3 system were produced by the conventional ceramic technology using mechanical activation of the synthesized product. It was found that in the (1-x)Na0.5Bi0.5TiO3-xNa0.5K0.5NbO3 system at room temperature, a number of morphotropic phase transitions occur: rhombohedral → cubic → tetragonal → monoclinic phases. The introduction of a small amount of Na0.5K0.5NbO3 leads to an increase in the temperature stability of the dielectric properties of ceramics. A change in the relaxor properties of the solid solutions of the (1-x)Na0.5Bi0.5TiO3-xNa0.5K0.5NbO3 system was shown. The increase in energy density and energy efficiency was found at additive 10mol.% of Na0.5K0.5NbO3.
Ceramics lead-free materials mechanical activation dielectric properties energy storage 
Journal of Advanced Dielectrics
2024, 14(1): 2350023
Author Affiliations
Abstract
Department of Materials Science and Engineering, Iowa State University, Ames, IA 50011, USA
PbZrO3-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb0.93xLa0.02(Li12Bi12)xSr0.04][Zr0.57Sn0.34Ti0.09]O3, with Li+ and Bi3+ substitution of Pb2+ at x=0, 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li+ and Bi3+ substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22J/cm3) are achieved in the composition of x=0.12 with a low sintering temperature (1075C).
PbZrO3-based antiferroelectrics Li+Bi substitution energy storage energy efficiency 
Journal of Advanced Dielectrics
2024, 14(1): 2350022
Author Affiliations
Abstract
1 School of Electronic and Information Engineering, Foshan University, Foshan 528000, P. R. China
2 School of Mechatronic Engineering and Automation, Foshan University, Foshan 528000, P. R. China
3 China-Australia Institute for Advanced Materials and Manufacturing, Jiaxing University, Jiaxing 314001, P. R. China
4 School of Materials Science and Hydrogen Energy, Foshan University, Foshan 528000, P. R. China
5 School of Physics and Optoelectronic Engineering, Foshan University, Foshan 528000, P. R. China
Ferroelectric ceramics have the potential to be widely applied in the modern industry and military power systems due to their ultrafast charging/discharging speed and high energy density. Considering the structural design and electrical properties of ferroelectric capacitor, it is still a challenge to find out the optimal energy storage of ferroelectric ceramics during the phase-transition process of amorphous/nanocrystalline and polycrystalline. In this work, a finite element model suitable for the multiphase ceramic system is constructed based on the phase field breakdown theory. The nonlinear coupling relationship of multiple physical fields between multiphase ceramics was taken into account in this model. The basic structures of multiphase ceramics are generated by using the Voronoi diagram construction method. The specified structure of multiphase ceramics in the phase-transition process of amorphous/nanocrystalline and polycrystalline was further obtained through the grain boundary diffusion equation. The simulation results show that the multiphase ceramics have an optimal energy storage in the process of amorphous polycrystalline transformation, and the energy storage density reaches the maximum when the crystallinity is 13.96% and the volume fraction of grain is 2.08%. It provides a research plan and idea for revealing the correlation between microstructure and breakdown characteristics of multiphase ceramics. This simulation model realizes the nonlinear coupling of the multiphase ceramic mesoscopic structure and the phase field breakdown. It provides a reference scheme for the structural design and performance optimization of ferroelectric ceramics.
Ferroelectric ceramics phase transition phase-field model dielectric breakdown energy storage 
Journal of Advanced Dielectrics
2024, 14(1): 2245001
作者单位
摘要
上海理工大学 光电信息与计算机工程学院,上海 200093
研究了富勒烯对六官能团脂肪族聚氨酯丙烯酸酯/环氧树脂(RJ423/ EPIKOTE 828)体系光致聚合物的全息性能的影响,分析了富勒烯(C60)材料以及曝光光强对光致聚合物衍射效率的影响。通过吸收光谱结合X射线衍射图谱分析,掺杂的富勒烯既没有和聚合物中的其他成分发生化学反应,也不影响材料本身的结构和结晶性能。实验结果表明,富勒烯掺杂提高了单体聚合反应的速率,并且参与活性单体分子之间的扩散。在光强20 mW/cm2、时间40~50 s、厚度200 μm时,光致聚合物的衍射效率提升到86%,感光灵敏度达到1.32 cm2/J,收缩率降低了约80%。由于C60促进聚合,抑制体积收缩,从而增强全息存储的稳定性,经过全息图像存储实验对比,证明该光致聚合物掺杂富勒烯之后具有优秀的全息存储性能,同时也表明富勒烯掺杂的光致聚合物在全息储存领域具有较大的应用前景。
衍射光学 富勒烯 衍射效率 光致聚合物 全息光存储 diffractive optics fullerene diffraction efficiency photopolymer holographic optical storage 
光学仪器
2024, 46(1): 23
作者单位
摘要
吉林大学电子科学与工程学院 集成光电子学国家重点实验室,吉林 长春 130012
超级电容器是良好的储能器件,具有功率密度高、使用寿命长、充电速度快等优点。激光诱导石墨烯(LIG)是一种常见的双电层电容器电极材料,但LIG双电层电容器通常表现出较低的电化学性能,而活性物质的掺入会提高超级电容器性能。针对如何控制活性物质的掺入问题,提出一种基于激光直写表面滴涂硝酸铁[Fe(NO33]的聚酰亚胺(PI)薄膜以制备LIG-Fe3O4复合物电极的微型超级电容器的方法。激光处理过的区域会同时发生PI薄膜烧蚀与Fe(NO33分解,产生Fe3O4与LIG复合的LIG-Fe3O4复合物电极。所制备的LIG-Fe3O4复合物微型超级电容器性能与LIG微型超级电容器相比提高了7.58倍。所提方法为制备高性能LIG微型超级电容器提供了一条新途径。
储能器件 激光直写 激光诱导石墨烯 微型超级电容器 
激光与光电子学进展
2024, 61(3): 0314005
作者单位
摘要
1 昆明理工大学材料科学与工程学院,云南 昆明 650093
2 云南省新材料制备与加工重点实验室,云南 昆明 650093
近红外光写入的光激励发光材料不仅能推进光激励发光材料在信息存储领域的实用化进程,也能在生物成像和编码方面发挥独到的作用。然而,近红外光写入型的高容量光激励发光材料仍旧十分缺乏。首先以具有热辅助紫外光激发增值填充容量的BaSi2O5∶Eu2+,Nd3+材料作为基础,进一步掺杂Yb3+离子实现近红外光的热转化,然后复合含有蓝、紫光发射的NaYF4∶Yb3+,Tm3+上转换发光材料,成功展示了980 nm激光调控的强度复用光存储。本研究不仅提供了一种高效的近红外光写入型的光激励信息存储材料,还表明了基于热辅助光激励发光材料构建高效近红外光写入的高简效性。
光激励发光材料 近红外光写入 热辅助激发 信息存储 
激光与光电子学进展
2024, 61(1): 0116005
作者单位
摘要
量子光学与光量子器件国家重点实验室 山西大学光电研究所 山西 太原 030006
在光学俘获和操控单原子的实验中, 激光的低频强度噪声通常会加热原子, 从而缩短其存储时间并破坏其内态相干性。我们采用了一种基于电光振幅调制器(EOAM)的单级反馈环路来抑制激光低频噪声, 实现了0~1MHz的强度噪声的有效抑制, 100 kHz以下的噪声可降低20 dB, 500 kHz以下的噪声可降低10 dB。噪声抑制的频率范围涵盖了光学偶极阱的典型参量加热频率。将该装置用于单个铯原子实验将单个原子在偶极阱中的存储时间延长两个数量级, 测量的退相干时间也增加了5倍。
光电反馈 强度噪声 光学俘获 原子存储时间 原子退相干时间 optoelectronic feedback laser intensity noise optical trappings atomic storage time atomic decoherence time 
量子光学学报
2023, 29(4): 040601
Author Affiliations
Abstract
1 Grupo de Materiales Ferroicos, Facultad de Física — IMRE, Universidad de la Habana. San Lázaro y L, Vedado. La Habana 10400, Cuba
2 LPMC, Université de Picardie Jules Verne, 33 rue Saint-Leu, 80039 Amiens Cedex, France
(Pb0.8Ba0.2)[(Zn1/3Nb2/3)0.7Ti0.3]O3 relaxor-type ferroelectric ceramics was obtained via classical solid-state reaction. The hysteresis loop results were discussed in the frame of ergodicity criterium around the characteristic ferroelectric relaxor freezing temperature. Slimer hysteresis loops were observed below the freezing temperature reflecting an ergodic relaxor behavior. Above this temperature, estimated around 223K for the studied system, larger and unsaturated like ferroelectric hysteresis loops were observed. This temperature also coincides with the slope change on maximum polarization and inflection point of remnant polarization curves. Energy storage, energy loss and efficiency values were determined in a wide temperature range. While the recoverable energy density shows relatively low values (0.23J/cm3), there are interesting behaviors for this parameter and for the efficiency, since the two physical quantities increase versus temperature and the efficiency even reaches the value of 97%.
Relaxors ferroelectrics energy storage freezing temperature 
Journal of Advanced Dielectrics
2023, 13(6): 2350019

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