光学学报, 2007, 27 (3): 494, 网络出版: 2007-03-15  

刻蚀改变InGaN/AlGaN应变多量子阱发光特性

Photoluminescence of InGaN/AlGaN Strained Multiple Quantum Wells Influenced by Dry Etching
作者单位
1 中国科学院上海微系统与信息技术研究所信息功能材料国家重点实验室, 上海 200050
2 中国科学院研究生院, 北京 100039
摘要
为了分析干法刻蚀对应变多量子阱(SMQWs)发光特性的影响, 采用感应耦合等离子体(ICP)刻蚀技术对金属有机物化学气相沉积(MOCVD)生长的InGaN/AlGaN应变多量子阱覆盖层表面刻蚀了约95 nm。通过光致发光(PL)特性表征发现,干法刻蚀后量子阱光致发光强度较未刻蚀量子阱光致发光强度提高了近3倍。干法刻蚀后, 量子阱表面呈现高低起伏状形貌, 粗糙度提高, 出射光在起伏状粗糙形貌表面反复散射, 从而逃逸概率增大, 有助于光致发光强度增强。理论计算结果得出表面形貌变化引起的量子阱光致发光强度增强因子约为1.3倍。另外, 由于所采用的感应耦合等离子体功率较小, 刻蚀损伤深度几乎不会达到量子阱阱层, 然而干法刻蚀过程中Ar离子隧穿到量子阱阱层内部可能形成新的发光中心, 从而使量子阱的发光强度得到提高。
Abstract
To investigate the influence of dry etching on strained multiple quantum wells (SMQWs), we etch the cap layer of metalorganic chemical vapor phase deposition (MOCVD) grown InGaN/AlGaN SMQWs about 95 nm by inductively coupled plasma (ICP). Photoluminescence (PL) measurements show that, the photoluminescence intensity of the quantum wells is enhanced about 3 times after dry etching. The surface of the quantum well becomes fluctuant, the degree of roughness becomes larger, and it allows the photons generated within the quantum wells to escape surface more easily by multiple scattering at the rough surface. The theoretic calculation result shows that the pattern change of the quantum well surface causes the enhancement of the photoluminescence intensity about 1.3 times. On the other side, because the inductively coupled plasma power is small, the damage depth almost cannot reach the well layer, but the tunneling of Ar+ inside the quantum well structure may bring new luminescence centers, and enhances the photoluminescence intensity.
参考文献

[1] Lai Tianshu, Wang Jiahui, Zhang Lili et al.. Mechanisms of blue and red luminescence of GaN film[J]. Acta Optica Sinica, 2003, 23(12): 1493~1496 (in Chinese)
赖天树,王嘉辉,张莉莉 等. GaN薄膜的蓝光和红光发射机理研究[J]. 光学学报, 2003, 23(12): 1493~1496

[2] Mo Chunlan, Li Peng, Wang Li et al.. Properties dependence of GaN∶Si Films on gas flow mixture[J]. Acta Optica Sinica, 2002, 22(2): 181~185 (in Chinese)
莫春兰,李鹏,王立 等. 气流混合对生长GaN∶Si 膜性能影响的研究[J]. 光学学报, 2002, 22(2): 181~185

[3] Xu Ke, Xu Jun, Zhou Guoqing et al.. Growth and defects of LiGaO2 crystal used for GaN epitaxy[J]. Acta Optica Sinica, 1998, 18(4): 499~502 (in Chinese)
徐科,徐军,周国清 等. GaN 外延衬底LiGaO2晶体的生长和缺陷[J]. 光学学报, 1998, 18(4): 499~502

[4] . Fujii, Y. Gao, R. Sharma et al.. Increase in the extraction efficiency of GaN-based light-emitting diodes via surface roughening[J]. Appl. Phys. Lett., 2004, 84(6): 855-857.

[5] . . Enhanced light output in nitride-based light-emitting diodes by roughening the mesa sidewall[J]. IEEE Photon Technol. Lett., 2005, 17(10): 2038-2040.

[6] . W. Chow, A. F. Wright, A. Girndt et al.. Microscopic theory of gain for an InGaN/AlGaN quantum well laser[J]. Appl. Phys. Lett., 1997, 71(18): 2608-2610.

[7] . T. Chu, C. C. Kao et al.. Enhanced light output of an InGaN/GaN light emitting diode with a nano-roughened p-GaN surface[J]. Nanotechnology, 2005, 16: 1844-1848.

[8] . W. Kin, H. Y. Lee, M. C. Yoo et al.. Highly efficient vertical laser-liftoff GaN-based light-emitting diodes formed by optimization of the cathode structure[J]. Appl. Phys. Lett., 2005, 86: 052108-1.

[9] . Statistical ray optics[J]. J. Opt. Soc. Am., 1982, 72(7): 899-907.

[10] . . Passivation of InGaAs/InP surface quantum wells by ion-gun hydrogen[J]. Appl. Phys. Lett., 1994, 64(16): 2658-2660.

[11] M. Rahman. Channeling and diffusion in dry-etched damage[J]. J. Appl. Phys., 82(5): 2215~2224

[12] . Habere, Monica Hansen, Steve Denbaars. Channeling as a mechanism for dry etch damage in GaN[J]. Appl. Phys. Lett., 2000, 76(26): 3941-3943.

[13] . Boguslawski, E. L. Briggs, J. Bernholc. Native defects in gallium nitride[J]. Phys. Rev. B, 1995, 51: 17255-17259.

[14] Xu Xurong, Su Mianzeng. Luminescent Science and Luminescent Material[M]. Beijing: Publishing Company of Chemical Industry, 2004. 74~82 (in Chinese)
徐叙瑢, 苏勉曾. 发光学与发光材料[M]. 北京: 化学工业出版社, 2004. 74~82

[15] . S. Djie, T. Mei, J. Arokiaraj. Photoluminescence enhancement by inductively coupled argon plasma exposure for quantum well intermixing[J]. Appl. Phys. Lett., 2003, 83(1): 60-62.

[16] Takashi Mukai, Daisuke Morita, Shuji Nakamura. High-power UV InGaN/AlGaN double-heterostructure LEDs[J]. J. Cryst. Growth., 1998, 189/190: 778~781

曹萌, 吴惠桢, 劳燕锋, 刘成, 谢正生. 刻蚀改变InGaN/AlGaN应变多量子阱发光特性[J]. 光学学报, 2007, 27(3): 494. 曹萌, 吴惠桢, 劳燕锋, 刘成, 谢正生. Photoluminescence of InGaN/AlGaN Strained Multiple Quantum Wells Influenced by Dry Etching[J]. Acta Optica Sinica, 2007, 27(3): 494.

关于本站 Cookie 的使用提示

中国光学期刊网使用基于 cookie 的技术来更好地为您提供各项服务,点击此处了解我们的隐私策略。 如您需继续使用本网站,请您授权我们使用本地 cookie 来保存部分信息。
全站搜索
您最值得信赖的光电行业旗舰网络服务平台!