采用坩埚下降法生长了NaI∶Zn（0，0.05%，0.08%，0.4%），Tl（0.18%）晶体。对晶体样品进行了X射线粉末衍射、电感耦合等离子体发射光谱以及紫外可见近红外透射光谱测试。结果表明，生长的晶体具有单一的物相，Zn和Tl离子掺杂并没有改变NaI的晶体结构；随着Zn掺杂浓度的增加，晶体内的Zn²⁺离子浓度增加、Tl⁺离子浓度下降；晶体透过率随Zn掺杂浓度的增加呈现先增大后减小的趋势，Zn掺杂浓度为0.08%时，样品的透过率最高，且所有样品在350~700 nm波段的透过率均高于70%。经过切割、打磨、抛光、封装等工序将NaI∶Zn，Tl晶体封装成辐射探测元件。闪烁性能测试结果表明，在¹³⁷Cs放射源激发下，Zn掺量为0.05%、0.08%时的NaI∶Zn，Tl晶体的能量分辨率≤6.80%，光输出相对于NaI∶Tl晶体增加6%~10%，这有利于NaI晶体在高能粒子探测领域的进一步应用。

NaI∶Zn(0, 0.05%, 0.08%, 0.4%),Tl(0.18%) crystals were grown using Bridgman method respectively. The crystal samples were tested by X-ray powder diffraction, inductively coupled plasma emission spectra, and ultraviolet-visible near-infrared transmission spectra. The results show that the grown crystals have a single phase, and the crystal structure of NaI does not change with Zn and Tl ions doping. As the doping concentration of Zn increases, the concentration of Zn²⁺ ions in the crystal increases, while the concentration of Tl⁺ ions decreases. The transmittance shows a trend of firstly increasing and then decreasing with the increase of Zn doping concentration. When the doping concentration of Zn is 0.08%, the transmittance of the sample is the highest. The transmittance of all the NaI∶Zn,Tl crystals is higher than 70% in the 350-700 nm wavelength range. After cutting, polishing, and packaging processes, NaI∶Zn,Tl crystals were enveloped into radiation detection components. The scintillation performance test results showed that under the excitation of a ¹³⁷Cs radiation source, the energy resolution of NaI∶Zn,Tl crystals with Zn doping of 0.05% and 0.08% were less than 6.80%, and the light output increased 6%-10% compared with that of NaI∶Tl crystal. This is conducive to the further application of NaI crystals in the field of high-energy particle detection.