半导体光电, 2019, 40 (6): 830, 网络出版: 2019-12-17   

N/Al共掺ZnO透明导电薄膜的制备及光电性能研究

Preparation and Photoelectric Properties of N/Al Co-doped ZnO Transparent Conducting Thin Films
高松华 1,2,*高立华 1,2陈礼炜 1,2
作者单位
1 装备智能控制福建省高校重点实验室, 福建 三明 365004
2 三明学院 机电工程学院, 福建 三明 365004
摘要
采用射频磁控溅射和退火处理方法在普通玻璃基底上制备了N、Al共掺的ZnO薄膜。利用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、四探针电阻测试仪和紫外-可见光光谱及X射线光电子能谱(XPS)等测试手段, 分析了溅射功率对薄膜表面形貌结构及光电性能的影响。研究结果表明: 不同溅射功率下所制备的薄膜均为具有c轴择优取向的六角纤锌矿结构, 在可见光范围内, 平均透过率都超过了85%; 在溅射功率为140W条件下, N、Al共掺的ZnO薄膜显示出p型导电特性。
Abstract
N/Al co-doped ZnO films were deposited on glass substrate by radio frequency(RF) magnetron sputtering and annealing process. The influence of sputtering power on the surface morphology and photoelectric properties of the films was studied by means of scanning electron microscope(SEM), X-ray diffraction (XRD), four-probe resistance tester, UV-visible spectrum and X-ray photoelectron spectroscopy(XPS). The results show that the films prepared under different sputtering powers are hexagonal wurtzite structures with preferred orientation of c-axis, and the average transmittance exceeds 85% in visible light range. N/Al co-doped ZnO films perpared with the sputtering power of 140W show p-type conductivity.
参考文献

[1] Krunks M, Katerski A, Dedova T, et al. Nanostructured solar cell based on spray pyrolysis deposited ZnO nanorod array[J]. Solar Energy Materials and Solar Cells, 2008, 92(9): 1016-1019.

[2] Ryu Y R, Kim W J, White H W. Fabrication of homostructural ZnO p-n junctions[J]. J. of Crystal Growth, 2000, 219(4): 419-422.

[3] He G H, Zhou H, Shen H, et al. Photodetectors for weak-signal detection fabricated from ZnO∶(Li,N) films[J]. Appl. Surface Science, 2017, 412: 554-558.

[4] Ma Q B, Ye Z Z, He H P, et al. Structural, electrical and optical properties of transparent conductive ZnO∶Ga films prepared by DC reactive magnetron sputtering[J]. J. of Crystal Growth, 2007, 304(1): 64-68.

[5] 王 航, 师清奎, 李 谦, 等. Al掺杂对ZnO薄膜形貌和光学性能的影响[J]. 半导体光电, 2019, 40(2): 234-238.

    Wang Hang, Shi Qingkui, Li Qian, et al. Effect of Al doping on morphology and optical properties of ZnO films[J]. Semiconductor Optoelectronics, 2019, 40(2): 234-238.

[6] Zhu B L, Zeng D W, Wu J, et al. Synthesis and gas sensitivity of In-doped ZnO nanoparticles[J]. J. of Materials Science: Materials in Electronics, 2003, 14(8): 521-526.

[7] Suja M, Bashar S B, Morshed M M, et al. Realization of Cudoped p-type ZnO thin films by molecular beam epitaxy[J].ACS Appl. Mater. & Interfaces, 2015, 7(16): 8894-8899.

[8] Mannam R, Eswaran S K, Dasgupta N, et al. Zn-vacancy induced violet emission in p-type phosphorus and nitrogen codoped ZnO thin films grown by pulsed laser deposition[J].Appl. Surface Science, 2015, 3479(30): 96-100.

[9] Bu I Y Y, Hu T H. P-type ZnO films deposited by DC reactive magnetron sputtering using codoping process[J]. J.of Mater. Science: Materials in Electron., 2017, 28(3):2852-2858.

[10] 赵鹏程, 张振中, 姚 斌, 等. 硼对氮掺杂的p型ZnO 薄膜的影响[J]. 发光学报, 2014, 35(7): 795-799.

    Zhao Pengcheng, Zhang Zhenzhong, Yao Bin, et al. Effect of boron on nitrogen doped p-type ZnO thin films[J]. Chinese J. of Luminescence, 2014, 35(7): 795-799.

[11] Li W J, Kong C Y, Ruan H B, et al. Investigation on the formation mechanism of In-N codoped p-type ZnCdO thin films: Experiment and theory[J]. The J. of Physical Chemistry C, 2014, 118(39): 22799-22806.

[12] 赵永红, 孔春阳, 秦国平, 等. N-In共掺p型ZnO 薄膜的结构和电学特性研究[J]. 重庆师范大学学报(自然科学版),2013, 30(3): 115-120.

    Zhao Yonghong, Kong Chunyang, Qin Guoping, et al. The investigation on the microstructure and electrical properties of p-type ZnO ∶ In-N films[J]. J. of Chongqing Normal University(Natural Science Edi.), 2013, 30(3): 115-120.

[13] 高松华, 高立华, 陈礼炜. 退火处理对N掺杂Al∶ZnO薄膜结构及性能的影响[J]. 真空科学与技术学报, 2018, 38(2):117-120.

    Gao Songhua, Gao Lihua, Chen Liwei. Effect of annealing on microstructures and properties of N-doped Al∶ZnO thin films[J]. Chinese J.of Vacuum Science and Technol., 2018, 38(2):117-120.

高松华, 高立华, 陈礼炜. N/Al共掺ZnO透明导电薄膜的制备及光电性能研究[J]. 半导体光电, 2019, 40(6): 830. GAO Songhua, GAO Lihua, CHEN Liwei. Preparation and Photoelectric Properties of N/Al Co-doped ZnO Transparent Conducting Thin Films[J]. Semiconductor Optoelectronics, 2019, 40(6): 830.

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