作者单位
摘要
近年来,随着弹载电子设备集成度越来越高,内部热耗不断增加,如何实现设备的高效热管理,成为制约弹载电子设备进一步发展的重大难题。该文提出了一种应用于大功率弹载微波组合的相变储热模块,通过仿真分析手段研究了储热模块主体结构对储热模块整体储热性能的影响。综合考虑可制造性、质量、储热能力等多方面因素后,确认了储热模块的结构形式和最终选用的相变介质材料。利用增材制造技术加工出储热模块样品,并搭建热测试平台完成了该样品的散热效果评估。实验表明,在60 ℃环境下,模块总热耗为211 W,工作10 min后,模块表面最高温度为104.1 ℃,满足组合使用要求。该储热设计技术有效地解决了模块短时大功率下温升过高的问题,在弹载电子设备热管理领域有着广阔的应用前景。
相变材料 储热模块 弹载 散热能力 phase change materials heat storage module missile-borne meat dissipation capacity 
压电与声光
2023, 45(5): 780
作者单位
摘要
国防科技大学 理学院,湖南 长沙 410073
随着红外探测技术手段的多样化发展,红外隐身技术的需求日益迫切。由于传统的红外隐身技术面临着多途径目标探测和多功能兼容的严峻挑战,因此研究光学微纳结构红外隐身技术有着十分重要的意义。基于局域共振机制的亚波长尺度的光学微纳结构,极大地丰富了人们对光的传输行为的调控。在红外隐身技术领域,光学微纳结构可以针对红外辐射特性进行材料和结构的精细化设计,从而满足理想红外隐身发射光谱的需求,为发展更加多光谱、多功能、自适应的红外隐身技术提供全新的解决方案。文中围绕红外隐身技术的相关研究,首先介绍了多层薄膜吸收体、金属表面等离子激元、基于相变材料薄膜可调吸收体、智能化设计光学微纳结构实现光谱响应的基本原理,在此基础上,重点回顾了近年来基于光学微纳结构的红外隐身技术新特点,包括多光谱红外隐身技术、多功能红外隐身技术、自适应红外隐身技术的发展现状。最后,梳理了光学微纳结构红外隐身技术所存在的不足及面临的困难并对未来的研究方向和发展趋势进行了展望。
红外隐身 热管理 超材料 选择性发射体 相变材料 infrared stealth thermal management metamaterials selective emitter phase change materials 
红外与激光工程
2023, 52(6): 20230197
Author Affiliations
Abstract
1 Zhengzhou University of Aeronautics, School of Materials Science and Engineering, Zhengzhou, China
2 Nanjing University, College of Engineering and Applied Sciences, National Laboratory of Solid State Microstructures, Nanjing, China
3 South China University of Technology, College of Physics and Optoelectronics, Guangzhou, China
Metasurfaces have emerged as a flexible platform for shaping the electromagnetic field via the tailoring phase, amplitude, and polarization at will. However, the chromatic aberration inherited from building blocks’ diffractive nature plagues them when used in many practical applications. Current solutions for eliminating chromatic aberration usually rely on searching through many meta-atoms to seek designs that satisfy both phase and phase dispersion preconditions, inevitably leading to intensive design efforts. Moreover, most schemes are commonly valid for incidence with a specific spin state. Here, inspired by the Rayleigh criterion for spot resolution, we present a design principle for broadband achromatic and polarization-insensitive metalenses using two sets of anisotropic nanofins based on phase change material Ge2Sb2Se4Te1. By limiting the rotation angles of all nanofins to either 0 deg or 90 deg, the metalens with a suitable numerical aperture constructed by this fashion allows for achromatic and polarization-insensitive performance across the wavelength range of 4–5 μm, while maintaining high focusing efficiency and diffraction-limited performance. We also demonstrate the versatility of our approach by successfully implementing the generation of broadband achromatic and polarization-insensitive focusing optical vortex. This work represents a major advance in achromatic metalenses and may find more applications in compact and chip-scale devices.
metasurfaces broadband achromatic metalenses polarization insensitivity phase change materials of Ge2Sb2Se4Te1 
Advanced Photonics Nexus
2023, 2(5): 056002
Author Affiliations
Abstract
1 Zhejiang University, College of Information Science and Electronic Engineering, State Key Laboratory of Modern Optical Instrumentation, Key Laboratory of Micro-Nano Electronics and Smart System of Zhejiang Province, Hangzhou, China
2 Westlake University, School of Engineering, Key Laboratory of 3D Micro/Nano Fabrication and Characterization of Zhejiang Province, Hangzhou, China
3 Institute of Advanced Technology, Westlake Institute for Advanced Study, Hangzhou, China
4 Institute of Microelectronics of the Chinese Academy of Sciences, Beijing, China
5 Peking University, School of Physics, Frontiers Science Center for Nano-optoelectronics, State Key Laboratory for Mesoscopic Physics, Beijing, China
Optical neural networks (ONNs), enabling low latency and high parallel data processing without electromagnetic interference, have become a viable player for fast and energy-efficient processing and calculation to meet the increasing demand for hash rate. Photonic memories employing nonvolatile phase-change materials could achieve zero static power consumption, low thermal cross talk, large-scale, and high-energy-efficient photonic neural networks. Nevertheless, the switching speed and dynamic energy consumption of phase-change material-based photonic memories make them inapplicable for in situ training. Here, by integrating a patch of phase change thin film with a PIN-diode-embedded microring resonator, a bifunctional photonic memory enabling both 5-bit storage and nanoseconds volatile modulation was demonstrated. For the first time, a concept is presented for electrically programmable phase-change material-driven photonic memory integrated with nanosecond modulation to allow fast in situ training and zero static power consumption data processing in ONNs. ONNs with an optical convolution kernel constructed by our photonic memory theoretically achieved an accuracy of predictions higher than 95% when tested by the MNIST handwritten digit database. This provides a feasible solution to constructing large-scale nonvolatile ONNs with high-speed in situ training capability.
phase-change materials optical neural networks photonic memory silicon photonics reconfigurable photonics 
Advanced Photonics
2023, 5(4): 046004
作者单位
摘要
郑州航空工业管理学院 材料学院,河南 郑州 450046
超表面是一种基于亚波长各向异性单元结构的超薄平面光学器件,能够在微观尺度下调制电磁波相位、偏振和振幅等,从而实现波前的任意调控。超构透镜作为超表面走向实用化的重要代表,凭借其超强的光波操控能力、超紧凑结构、多功能性及与半导体工艺兼容等突出优点,引起了研究学者的极大兴趣。然而,已报道的超构透镜受限于相位分布设计,难以同时实现偏振复用及强度可调谐聚焦功能;且结构一旦确定,其电磁性能就被锁定,在灵活调制电磁波方面受到很大限制。为此,文中从各向异性单元结构的设计和优化入手,协同PB相位和传输相位,设计了两种能够在不同空间取向(横向和纵向)上实现自旋分裂的Ge2Sb2Se4Te1 (GSST) 相变超构透镜。通过改变入射圆偏振光的椭偏度,两超构透镜均可实现强度可调谐聚焦性能;通过调控相变材料Ge2Sb2Se4Te1从非晶态逐渐转变为结晶态,两超构透镜均可实现聚焦性能的连续调谐并最终达到“ON”和“OFF”的动态切换。所设计的自旋依赖强度可调谐相变超构透镜有望在多成像系统、机器视觉和显微成像等领域发挥重要作用。
光学超表面 超构透镜 相变材料Ge2Sb2Se4Te1 自旋依赖 强度可调谐 optical metasurface metalenses phase-change materials Ge2Sb2Se4Te1 spin-dependent intensity-adjustable 
红外与激光工程
2022, 51(11): 20220398
作者单位
摘要
1 东华大学环境学院,空气环境与建筑节能研究所,上海 201620
2 上海污染控制与生态安全研究院,上海 200092
3 上海市安装工程集团有限公司,上海 200080
脂肪酸类相变材料(PCMs)在缓解建筑用能源危机上有着巨大的应用前景。本工作制备了月桂酸-肉豆蔻酸-硬脂酸(LA-MA-SA)的相变材料。以多孔网状膨胀石墨(EG)为热导率增强材料、硅藻土(DE)为定型材料,通过熔融浸渍法分别制备了含质量分数为2% EG、4% EG、6% EG、8% EG、10% EG的高热导率的LA-MA-SA/EG/DE定型复合相变材料,对定型复合相变材料进行微观结构分析和热物性测量。结果表明:LA-MA-SA与EG和DE为物理吸附过程且吸附效果良好。稳态法热导率测试发现,EG可以有效提高PCM的热导率,添加2%~10%的EG,热导率增强了29.7%~708.2%。通过泄漏测试发现,添加DE能够对复合物起到一定的定型作用,防止PCM的泄漏。对复合物进行100次DSC循环后,材料的相变温度和相变潜热均无明显变化。通过蓄/放热试验发现,LA-MA-SA/10% EG/10/% DE的石膏板在加热冷却过程中分别表现出良好的储、放热性能和较长的相对热舒适时间,较纯石膏板延长0.82 h。
脂肪酸 硅藻土 定型相变材料 热物性 fatty acid diatomite stabilized phase change materials thermal physical properties 
硅酸盐学报
2022, 50(6): 1652
作者单位
摘要
1 青海大学,新能源光伏产业研究中心,西宁 810016
2 清华大学材料学院,北京 100084
针对芒硝相变材料因过冷度大、相分层严重导致相变潜热存储循环寿命缩短的问题,以Na2SO4·10H2O- Na2CO3·10H2O-NaCl相变材料体系为基体、改进的Hummers法结合冷冻干燥和球磨工艺改性制备的亲水性纳米氧化石墨烯(Nano-GO)为添加剂,制得纳米氧化石墨烯/芒硝基复合相变材料(GO-MCPCMs)。结果表明:氧化处理过的纳米氧化石墨烯中O/C比例增加了65.75%,结构缺陷水平由0.224增至1.088,无团聚现象;纳米氧化石墨烯/芒硝基复合相变材料的结晶相变温度增至约23 ℃、过冷度减小至0 ℃、相分层消除,该复合相变体系中Na2SO4结晶体全部结晶为晶粒长度尺寸近于2 cm的Na2SO4·10H2O;500次固?液循环前后含氧化石墨烯质量分数为0.075%的GO-MCPCMs结晶潜热值分别为156.7 J/g和149.9 J/g,衰减率为4.3%,Nano-GO的加入明显改善了芒硝基复合相变体系的热稳定性。纳米氧化石墨烯/芒硝基复合相变材料具有良好的热循环稳定性和较长的使用寿命。
改性纳米石墨烯 改进Hummers法 芒硝基复合相变材料 结构与热性能 循环稳定性 modified nano graphene improved Hummers method mirabilite composite phase change materials structure and thermal property cycle stability 
硅酸盐学报
2022, 50(6): 1642
Tun Cao 1,*†Meng Lian 1†Xieyu Chen 2†Libang Mao 1†[ ... ]Dongming Guo 3,*
Author Affiliations
Abstract
1 School of Optoelectronic Engineering and Instrumentation Science, Dalian University of Technology, Dalian 116024, China
2 Center for Terahertz Waves and College of Precision Instrument and Optoelectronics Engineering, Tianjin University, Tianjin 300072, China
3 School of Mechanical Engineering, Dalian University of Technology, Dalian 116024, China
Metamaterials composed of metallic antennae arrays are used as they possess extraordinary optical transmission (EOT) in the terahertz (THz) region, whereby a giant forward light propagation can be created using constructive interference of tunneling surface plasmonic waves. However, numerous applications of THz meta-devices demand an active manipulation of the THz beam in free space. Although some studies have been carried out to control the EOT for the THz region, few of these are based upon electrical modulation of the EOT phenomenon, and novel strategies are required for actively and dynamically reconfigurable EOT meta-devices. In this work, we experimentally present that the EOT resonance can be coupled to optically reconfigurable chalcogenide metamaterials which offers a reversible all-optical control of the THz light. A modulation efficiency of 88% in transmission at 0.85 THz is experimentally observed using the EOT metamaterials, which is composed of a gold (Au) circular aperture array sitting on a non-volatile chalcogenide phase change material (Ge2Sb2Te5) film. This comes up with a robust and ultrafast reconfigurable EOT over 20 times of switching, excited by a nanosecond pulsed laser. The measured data have a good agreement with finite-element-method numerical simulation. This work promises THz modulators with significant on/off ratios and fast speeds.Metamaterials composed of metallic antennae arrays are used as they possess extraordinary optical transmission (EOT) in the terahertz (THz) region, whereby a giant forward light propagation can be created using constructive interference of tunneling surface plasmonic waves. However, numerous applications of THz meta-devices demand an active manipulation of the THz beam in free space. Although some studies have been carried out to control the EOT for the THz region, few of these are based upon electrical modulation of the EOT phenomenon, and novel strategies are required for actively and dynamically reconfigurable EOT meta-devices. In this work, we experimentally present that the EOT resonance can be coupled to optically reconfigurable chalcogenide metamaterials which offers a reversible all-optical control of the THz light. A modulation efficiency of 88% in transmission at 0.85 THz is experimentally observed using the EOT metamaterials, which is composed of a gold (Au) circular aperture array sitting on a non-volatile chalcogenide phase change material (Ge2Sb2Te5) film. This comes up with a robust and ultrafast reconfigurable EOT over 20 times of switching, excited by a nanosecond pulsed laser. The measured data have a good agreement with finite-element-method numerical simulation. This work promises THz modulators with significant on/off ratios and fast speeds.
metamaterials extraordinary optical transmission surface plasmon resonance reconfigurable phase change materials 
Opto-Electronic Science
2022, 1(1): 210010
作者单位
摘要
宁波大学 信息科学与工程学院 浙江省光电探测材料及器件重点实验室,浙江 宁波 315211
硫系玻璃具有超宽的红外透过光谱范围、较高的线性折射率、极高的光学非线性和超快的非线性响应,近年来在集成光子器件研究领域备受关注。首先回顾了硫系玻璃集成光波导的制备,综述了硫系集成光子器件在红外传感和高性能非线性应用方面取得的进展,然后介绍了硫系相变光子器件在光开关、光存储和光计算等方面的前沿进展,最后对目前硫系玻璃光子器件研究存在的问题进行了归纳,并对未来的研究方向进行了展望。
硫系玻璃 集成光子器件 红外传感 非线性效应 相变材料 chalcogenide glass integrated photonic devices infrared sensing nonlinear effect phase change materials 
红外与激光工程
2022, 51(3): 20220152
菅佳玲 1,2叶羽婷 1,2李钧颖 3施依琳 1,2[ ... ]李兰 1,2,*
作者单位
摘要
1 西湖大学工学院,浙江省3D微纳加工和表征研究重点实验室,杭州 310024
2 浙江西湖高等研究院前沿技术研究所,杭州 310024
3 浙江大学信息与电子工程学院,杭州 310027
硫系玻璃由于具有较高的折射率、宽的红外波段透明窗口、较低的非线性损耗和较快的非线性响应,在光学器件领域具有巨大的应用潜力。随着近年来微纳器件加工技术的进步,基于硫系玻璃制备的新型微纳光子器件,在通信、安全、医疗、环境等领域得到了广泛的应用。本工作从硫系玻璃的物理光学性质出发,就硫系玻璃的薄膜制备工艺、微纳器件加工方法、光学器件应用及发展前景分别展开论述。
硫系玻璃 微纳光子器件 集成光学 中红外传感 相变材料 柔性光子 chalcogenide glasses micro/nano photonic devices integrated photonics mid-infrared sensing phase change materials flexible photonics 
硅酸盐学报
2021, 49(12): 2676

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